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A novel strategy using biodegradable EDDS for the chemically enhanced phytoextraction of soils contaminated with heavy metals 总被引:1,自引:0,他引:1
Chunling LUO Zhenguo SHEN Alan J.M. Baker Xiangdong LI 《中国地球化学学报》2006,25(B08):115-115
For the sake of cost and potential environmental risk, it is necessary to minimize the amount of chelates used in chemically-enhanced phytoextraction. In the present study, a biodegradable chelating agent, EDDS was added in a hot solution at 90℃ to the soil in which garland chrysanthemum (Chrysanthemum coronarium L.) and beans (Phaseolus vulgaris L., white bean) were growing. The application of hot chelate solutions was much more efficient than the application of normal chelate solutions (25℃) in improving the uptake of heavy metals by plants. When 1 mmol kg1 of EDDS as a hot solution was applied to soil, the concentrations ofCu, Zn and Cd and the total phytoextraction by the shoots of the two plant species exceeded or approximated those in the shoots of plants treated with 5 mmol kg^-1 of normal EDTA solution. The concentrations of metals in the shoots of beans were significantly correlated with the relative electrolyte leakage rate of root cells, indicating that the root damage resulting from the hot solution might play an important role in the process of chelate-enhanced metal uptake. The soil leaching study demonstrated that decreasing the dosage of chelate resulted in decreased concentrations of soluble metals in soils. On the 28th day following the application of chelate, the concentrations of soluble metals in the EDDS treated soil were not significantly different from the concentrations in the control soil to which chelates had not been applied. 相似文献
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锚喷材料经时蠕变损伤本构方程 总被引:1,自引:0,他引:1
从以应力,湿度,温度和损伤诸函数的时间积分表示和自由能涵函出发,根据非平衡热力学定律,同时考虑了喷射混凝土老化效应及骨料因素,给出了锚喷材料损伤蠕变本构方程和损伤演化方程,养护时间及蠕变有效作用应力的定义,并用实验结果验证了该理论。 相似文献
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Ccile Gautheron Laurent Tassan-Got Jocelyn Barbarand Maurice Pagel 《Chemical Geology》2009,266(3-4):157-170
Recent data on He diffusion challenge the temperature sensitivity of apatite (U–Th)/He thermochronology: the damage induced by recoil of U and Th decay series during emission of α particles (α-recoil damage) has been proposed to modify He-diffusion properties through time. However, we propose that annealing of these irradiation defects may be an important phenomenon and may be significant in case of slowly-cooled or reheated basement rocks. To test this hypothesis, we developed a quantitative model including an explicit treatment of α-recoil damage, annealing, and their effect on He-diffusion kinetics, and calibrate it against literature data. Our model is based on two hypotheses: (1) helium is in equilibrium between an apatite crystal and its defects and (2) alpha-recoil damage annealing can be described analogously to fission-track annealing. This model has been embedded into a Monte Carlo simulation of helium production/ejection/diffusion and applied to data from the French Massif Central; a complex slowly-cooled terrain with burial reheating, where the thermal history has been constrained by previous fission-track (FT) data including FT length distributions. (U–Th)/He ages are close to the FT ages from the same samples and are generally reproducible among replicates, but some samples present He-age dispersion that is not correlated with crystal size. Our model reproduces the Massif Central data very well except for three samples where He ages are older than corresponding FT ages. We show that annealing of irradiation damage has an important impact on retentivity of helium and that the He content, [He] is only a rough approximation of the damage level. In particular our results show that independence of He ages on crystal sizes, in case of reheated samples, is a clear indication of the higher He retentivity induced by α-recoil defects and that an explicit treatment of defect annealing is required for a correct interpretation of (U–Th)/He ages in such a case. More generally a correlation with the crystal size can bring information on the thermal path only if the age of defects, well represented by the fission-track age, is available, due to the dependence of the partial retention zone on damages. Conversely, in case of rapid cooling or for samples having low U and Th contents, damage effects can be ignored without significant effects on He ages. 相似文献
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通过干湿循环效应下的数字图像三轴剪切试验、CT扫描试验及扫描电镜SEM(scanning electron microscopy)试验,研究了玄武岩纤维加筋黄土干湿循环过程的三轴剪切力学行为及微细观结构演化机制。结果表明:随干湿循环次数增加,纤维含量较高试样的三轴剪切鼓胀破坏形态转变为剪切带破坏;干湿循环早期阶段,剪切破坏形态随纤维含量增加,由剪切带破坏转变为鼓胀破坏。干湿循环作用和纤维含量对应力-应变曲线的类型及特征无明显影响,均表现为应变硬化型。破坏偏应力随干湿循环次数增加而逐渐减小,但衰减速率逐渐减小;破坏偏应力随纤维含量增大先增加而后减小,呈抛物线变化特征,存在一个最佳纤维含量为0.6%。CT数均值ME值呈现与破坏偏应力相似的变化规律。干湿循环作用下筋-土界面产生一定的开裂和松弛现象,弱化了纤维的加筋效应,但与素黄土相比,纤维加筋黄土的微观结构表现出显著的整体稳定性。构建了干湿循环效应下玄武岩纤维加筋黄土的宏细观损伤变量,其表现出一致的变化规律。 相似文献