含粉煤灰与伊利石的高吸水复合材料性能测试

粉煤灰具有一定的吸水能力,且含多种营养元素,对土壤有很好的改良效果;伊利石也具有吸水性,且含钾量高。采用溶液聚合法首次合成的粉煤灰-伊利石/丙烯酸-丙烯酰胺高吸水复合材料,其吸蒸馏水、自来水、生理盐水倍率分别为1 782,450,117,而国家“863计划”关于高吸水材料的技术指标分别为300,150,50;同时对复合材料的保水性、热稳定性、耐寒性及其二次吸液性能进行测试,结果表明:复合材料具有优越的保水性,25℃条件下干燥8 d,吸水凝胶还可以保持50%的吸水量;在0～120℃范围性能稳定;具有较高的二次吸液能力,可以多次使用。     

Advective heat transfer and fabric development in a shallow crustal intrusive granite — the case of Proterozoic Vellaturu granite,south India

Syntectonic plutons emplaced in shallow crust often contain intermediate-to low-temperature deformation microstructures but lack a high-temperature, subsolidus deformation fabric, although the relict magmatic fabric is preserved. The Proterozoic Vellaturu granite emplaced at the eastern margin of the northern Nallamalai fold belt, south India during the late phase of regional deformation has a common occurrence of intermediate-to low-temperature deformation fabric, superimposed over magmatic fabric with an internally complex pattern. But high-T subsolidus deformation microstructure and fabric are absent in this pluton. The main crystal plastic deformation and fluid enhanced reaction softening was concentrated along the margin of the granite body. Resulting granite mylonites show Y-maximum c-axis fabric in completely recrystallized quartz ribbonds, dynamic recrystallization of perthites, and myrmekite indicative of fabric development under intermediate temperature (∼ 500–400°C). The weakly-deformed interior shows myrmekite, feldspar microfracturing and limited bulging recrystallization of quartz. The abundance of prism subgrain boundaries is indicative of continuing deformation through low-temperature (∼ 300°C). The relative rates of cooling influenced by advective heat transfer and deformation of the pluton seem to control the overall subsolidus fabric development. The rapid advective heat transfer from the interior in the early stages of subsolidus cooling was followed by slow cooling through intermediate temperature window as a well-developed phyllosilicate rich mylonitic skin around the granite body slowed down conductive heat loss. Low-T crystal plastic deformation of quartz was effected at a late stage of cooling and deformation of the shallow crustal granite body emplaced within the greenschist facies Nallamlai rocks.     

Numerical simulation for the coupling effect of local atmospheric circulations over the area of Beijing,Tianjin and Hebei Province

Using the model system MM5.V3 and multi-layer grid nesting technique, we have done a multi-scale numerical simulation over the area of Beijing, Tianjin and Hebei Province to analyze the temperature and wind field there and study its local circulations. The results show a coupling effect of Urban Heat Island Circulation (UHIC), Mountain Valley Breeze (MVB) and Sea Land Breeze (SLB) occurs in this area when the synoptic system is weak. The SLB can penetrate deep into the mainland for about 200 km when it is blooming. MVB can extend to south and cover almost the whole plain area in Beijing. Both MVB and SLB are diurnal periodical; meanwhile the phase of MVB drops behind that of SLB for about six hours. As a local circulation, the UHIC weakens the two circulations above, and it also has a diurnal period. As a result, the coupling effect of circulations reveals not only different features in spring-summer period and autumn-winter period in a year but also the difference between early morning to noonday and afternoon to night in a day. We noted the diffusion of contamination over the area around Beijing, and found the steady presence of a transport routine of contamination over North-China throughout the year caused by the Coupling Effect mentioned above. This find is important for studying the environment pollution in this area. Supported by Central Public Welfare Special Fund Program for the Institute and Higher Education (Grant No. IUMKY200701), Public Welfare Special Fund Program (Meteorology) of China Scientific and Technological Ministry (Grant Nos. CYHY20080620, CYHY200706004), Spread New Technology Program of China Meteorological Administration (Grant No. CMATG2007M15) and Urban Meteorology Scientific Research Fund Program of the Institute of Beijing Urban Meteorology, China Meteorological Administration (Grant No. UMRF200702)     

松辽盆地地热场

本文实测了65口井的地热数据,从中取得17个大地热流值,松辽盆地地热场具有中部高边部低,并呈环状分布,该区地热具有高特征的地质发展历史。分区计算盆地的沉积岩层、花岗岩质层和玄武岩质层各底部的温度和热流值,也都具有中部高边部低的变化趋势。分析了盆地地热场受影响的状况和地热高的主要原因。还分析了盆地地热场与构造活动性、地震活动性、重磁力场、岩石圈厚度的关系,以及与石油生成、运移和富集的关系。     

Temperature and heat flux spectra in the turbulent buoyancy subrange

The physical nature of motions with scales intermediate between approximately isotropic turbulence and quasi-linear internal gravity waves is not understood at the present time. Such motions play an important role in the energetics of small scales processes, both in the ocean and in the atmosphere, and in vertical transport of heat and constituents. This scale range is currently interpreted either as a saturated gravity waves field or as a buoyancy range of turbulence.We first discuss some distinctive predictions of the classical (Lumley, Phillips) buoyancy range theory, recently improved (Weinstock, Dalaudier and Sidi) to describe potential energy associated with temperature fluctuations. This theory predicts the existence of a spectral gap in the temperature spectra and of an upward mass flux (downward buoyancy and heat fluxes), strongly increasing towards large scales. These predictions are contrasted with an alternate theory, assuming energetically insignificant buoyancy flux, proposed by Holloway.Then we present experimental evidences of such characteristic features obtained in the lower stratosphere with an instrumented balloon. Spectra of temperature, vertical velocity, and cospectra of both, obtained in homogeneous, weakly turbulent regions, are compared with theoretical predictions. These results are strongly consistent with the improved classical buoyancy range theory and support the existence of a significant downward heat flux in the buoyancy range.The theoretical implications of the understanding of this scale range are discussed. Many experimental evidences consistently show the need for an anisotropic theory of the buoyancy range of turbulence.     

峨眉山超级地幔柱对四川盆地烃源岩热演化的影响

四川盆地的构造、热演化与峨眉山超级地幔柱有密切关系.峨眉山超级地幔柱对四川盆地中二叠统之下的烃源岩热演化有着十分重要的影响.在四川盆地热历史恢复的基础上,研究了峨眉山超级地幔柱对盆地内烃源岩,特别是中二叠统之下的古生界烃源岩热演化的影响.结果表明,中二叠统及下伏烃源岩的热演化受中晚二叠世发生在盆地西南方向的峨眉山超级地幔柱的影响巨大,且具地区差异性.即在靠近峨眉山地幔柱中心的地区,有机质迅速成熟并达到其成熟度的最高值(以H1井为代表),古生界烃源岩迅速进入过成熟,此后未有二次生烃;而远离峨眉山地幔柱的盆地大部分地区,古生界烃源岩在二叠纪以来具有多次生烃过程.中生界烃源岩热演化,主要和前陆盆地阶段的构造过程包括前陆沉积和断裂的逆冲推覆等相关. 在烃源岩有机质成熟度演化史的基础上,从盆地热史和烃源岩热演化的角度指出了下二叠统及之下烃源层在四川盆地不同地区油气勘探中的不同意义.     

海底热流长期观测系统研制进展

浅海和俯冲海沟等海域,不仅是矿产和油气资源主潜力区,也是构造地震频发区,其浅表热流和深部温度信息对于了解板块俯冲和岩浆活动等过程至关重要.这些区域浅层地温场和热流场受到底水温度波动（BTV）强烈扰动,其背景热流需由长期观测来获取.在全面分析了国内外海底热流长期观测技术特点后,我们提出了系缆式海底热流长期观测方案,2013年起陆续开展了部分核心技术的预研究及一系列海底、湖底及浅孔试验.结果表明：（1）自主研制的长周期低功耗微型测温单元,在2~36℃的环境下可连续观测1年;系缆式投放与回收方案即使在地形陡峭、1.5 kn流速及无动力定位等条件下仍然可行.（2）南海北部BTV总体随水深变浅而增强,在浅水区对浅层地温场扰动不可忽略.例如,在水深2600~3200 m和850~1200 m海域分别为0.025~0.053℃（17天内）、0.182~0.417℃（2天内）,而台西南盆地北坡（水深763 m）夏季的海底热流由浅表的0.69 W·m^-2转变为0.83 m以深的-0.25~-0.05 W·m^-2.（3）兴伊措和湖光岩玛珥湖BTV向深部传导过程中其幅度逐渐减弱、相位滞后,进而导致热流方向与强度随季节发生变化.而康定中谷浅层（7 m内）地温在不同深度处同步波动,且冬高（35~36℃）夏低（28~32℃）.推测为夏季大量降雨所致;其热流浅部低（0.504 W·m^-2）深部高（0.901 W·m^-2）,指示着鲜水河断裂带深部热流体上涌.这些预研究工作为后续系缆式海底热流长期观测系统的正式研制与应用奠定了扎实基础.

     

Evaluation of riverbed magnetic susceptibility for mapping biogeochemical hot spots in groundwater-impacted rivers

Redox hot spots occurring as metal-rich anoxic groundwater discharges through oxic wetland and river sediments commonly result in the formation of iron (Fe) oxide precipitates. These redox-sensitive precipitates influence the release of nutrients and metals to surface water and can act as ‘contaminant sponges’ by absorbing toxic compounds. We explore the feasibility of a non-invasive, high-resolution magnetic susceptibility (MS) technique to efficiently map the spatial variations of magnetic Fe oxide precipitates in the shallow bed of three rivers impacted by anoxic groundwater discharge. Laboratory analyses on Mashpee River (MA, USA) sediments demonstrate the sensitivity of MS to sediment Fe concentrations. Field surveys in the Mashpee and Quashnet rivers (MA, USA) reveal several discrete high MS zones, which are associated with likely anoxic groundwater discharge as evaluated by riverbed temperature, vertical head gradient, and groundwater chemistry measurements. In the East River (CO, USA), widespread cobbles/rocks exhibit high background MS from geological ferrimagnetic minerals, thereby obscuring the relatively small enhancement of MS from groundwater induced Fe oxide precipitates. Our study suggests that, in settings with low geological sources of magnetic minerals such as lowland rivers and wetlands, MS may serve as a complementary tool to temperature methods for efficiently mapping Fe oxide accumulation zones due to anoxic groundwater discharges that may function as biogeochemical hot spots and water quality control points in gaining systems.     

Thermal conductivity in a vadose zone: A novel spectral solution and application by the implication of significant coherence of thermal condition in the shallow soil water layer

In the context of the heterogeneity in the unsaturated or vadose zone, accurately representing the analytical mechanisms and in-situ water content within the soil layer poses a significant challenge. Particularly in shallow layers, thermal conditions exhibit rapid changes in response to evolving surface temperatures. This study proposes a hypothesis suggesting that the in situ heat mechanism may notably impact the soil water layer. The research introduces an innovative approach to theoretically uncover thermal conditions, including soil temperature, soil temperature gradients, and heat flux, within the shallow Quaternary gravel layer at various depths through spectral analysis of temporal observations. The study presents a stochastic inverse solution to estimate thermal conductivity by leveraging spectral analysis of soil heat flux and temperature gradients. The findings reveal that thermal conditions exhibit the most prominent periodic fluctuations during the diurnal process over a 24-hour cycle. The soil temperature gradients and heat flux measurements at depths of 0.1, 0.3, 0.6, and 1.2 m demonstrate their ability to capture changes in soil temperature and air temperature to a certain extent within the frequency domain. Furthermore, the analysis highlights the intrinsic uncertainty and sensitivity of estimating thermal conductivity in heterogeneous soil environments. The wide variability observed in thermal conductivity values, coupled with their dependence on soil type and environmental conditions, underscores the need for careful consideration of these factors in future studies and modeling efforts. Applying the derived inverse spectral solution allows for determining thermal conductivity throughout the soil-water system across depths ranging from 0.1 to 1.2 m. As a result, this research demonstrates the feasibility and practicality of assessing the thermal conductivity of the soil layer in conjunction with heat flux and temperature gradients through spectral analysis.     

Measuring and interpreting heat fluxes from shallow volcanic bodies using vertical temperature profiles: a preliminary test

 To test the potential of heat flux prospecting in active volcanic areas using shallow temperature data taken along vertical profiles, we carried out two thermal profile surveys, one not far from Yasur cone on Tanna Island, and another inside the caldera of Ambrym (New Hebrides arc, southwestern Pacific). The basic steady heat flux of internal volcanic origin was determined, taking into account both conductive and convective heat transfers. At both locations there exists, over small distances, significant differences in the heat flux. These differences correspond to shallow sources of heat. The use of a network of vertical profiles allowed: (a) heat flux mapping; (b) location of shallow volcanic heat sources; and (c) observation of the detailed structure of the heat release at quiescent but active volcanoes. Received: 18 July 1997 / Accepted: 13 May 1998