胜利二号极浅海步行坐底式钻井平台防腐措施研究

本文根据胜利二号极浅海步行坐底钻井平台的作业和工作环境特点，进行了防腐措施研究，设计了切合实际的防腐措施。该平台在海上作业近四年进坞修理，经观测防腐情况良好。     

Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO2 levels

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].     

解决山东水资源短缺的对策

分析了山东省水资源现状和存在的主要问题，针对山东省水资源的严重短缺，提出了在传统用水、治水的基础上，实施人工增雨工程，直接利用海水和海水淡化与节约用水，建立节水型社会，调整水源结构，更新用水观念，开发新水源，综合用水，综合治水的路子，只有这样才能长久解决水危机。     

PLATEAU TYPE E(%)-pH CURVES OF INTERFACIAL EXCHANGE BETWEEN LIQUID AND SOLID IN SEAWATER

A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c     

晚新生代亚洲干旱气候发展与全球变冷联系的风尘沉积证据

在干旱气候背景下常常有风尘物质的释放和传输,风尘沉积被认为是干旱环境变化良好的地质记录。在亚洲中部和中国北方,大面积的干旱区被沙漠戈壁覆盖,这些地区是粉尘物质的重要源地,释放的风尘物质影响局地和区域环境,并通过参与生物地球化学循环等影响更大空间尺度的气候变化。因此,亚洲中部干旱气候的形成和演化以及发展趋势一直受到重视。长期以来,关于晚新生代亚洲中部干旱气候发展的驱动机制至少有两种解释:一是青藏高原的隆升控制着亚洲中部的干旱化过程,随着高原的阶段性隆升亚洲干旱气候逐步增强;二是晚新生代全球变冷直接驱动着亚洲变干,全球变冷是主导因素。中国黄土高原及其周边地区堆积的黄土-红粘土序列是指示亚洲干旱化过程良好的地质记录,通过对新获得的风尘堆积记录的分析,发现在晚新生代中国风尘堆积的时空演化与全球变冷有较好的对应,全球变冷可以促使亚洲中部干旱气候发展并加强粉尘活动,而青藏高原隆升的幅度和时间还不清楚,进而认为是全球变冷而不是青藏高原隆升直接驱动亚洲内陆的阶段性变干。基于这些结果,我们认为以前关于青藏高原隆升影响全球气候的结论可能高估了青藏高原在地球环境演化中的作用,关于高原隆升直接驱动亚洲干旱化的结论还需要检验。     

Chronology and cooling history of the Tianmenshan pluton in South Jiangxi Province and their geological significance

Geochronological studies on the crust-derived Tianmenshan pluton were undertaken by SHRIMP zircon U-Pb dating and Ar-Ar dating of biotite, muscovite and K-feldspar, giving a petrogenetic age of 167 Ma. Owing to the closure systems in different minerals, the cooling history of the pluton can be determined with an age-temperature diagram. The late hydrothermal event has been recognized, which is related probably with mineralization. In terms of the comparative geochronological and petrologic records, it is concluded that there are some constrains on tectonic evolution and that the formation of the Tianmenshan pluton proceeded in a transition period from Indosinian post-orogeny extension to strong compressive tectonics. And the timing of the hydrothermal event matches the compressive climax of the Yanshanian orogeny. The temporal gap between granite emplacement and wolframite mineralization could last 10-20 Ma owing to the low cooling rate of the pluton.     

The mass accommodation coefficient of ammonia on water

The mass accommodation coefficient of ammonia gas on water has been determined by measuring the absorption rate of 50–200 ppm NH₃ in one atm of air or helium into a liquid jet of 97 µm diameter as function of the exposed jet length, and comparing the results with numerical simulations which treat as the only free parameter. The model considers in detail transport of NH₃ by molecular diffusion, penetration of the gas/water interface, hydrolysis in the acidified water, and transport of the solutes from the surface into the jet. A correction is applied for the time evolution of the jet surface speed, using literature data on the fluid mechanics of liquid jets. The result of nine sets of independent measurements is

Primary volcanic structures from a type section of Deccan Trap flows around Narsingpur-Harrai-Amarwara, central India: Implications for cooling history

Field investigations of the Deccan Trap lava sequence along a 70 km traverse in the Narsingpur-Harrai-Amarwara area of central India indicate twenty lava flows comprising a total thickness of around 480 m. Primary volcanic structures like vesicles and cooling joints are conspicuous in this volcanic succession and are used to divide individual flows into three well-defined zones namely the lower colonnade zone, entablature zone, and the upper colonnade zone. The variable nature of these structural zones is used for identification and correlation of lava flows in the field. For twenty lava flows, the thicknesses of upper colonnade zones of eight flows are ∼5 m while those of eight other flows are ∼8 m each. The thicknesses of upper colonnade zones of remaining four flows could not be measured in the field. Using the thicknesses of these upper colonnade zones and standard temperature-flow thickness-cooling time profiles for lava pile, the total cooling time of these sixteen Deccan Trap lava flows has been estimated at 12 to 15 years.     

Denudation and cooling of the Lake Teletskoye Region in the Altai Mountains (South Siberia) as revealed by apatite fission-track thermochronology

Lake Teletskoye occupies a narrow graben located in the northwestern sector of the Altai fold belt in South Siberia. The lake basin is thought to have formed during the Pleistocene as a distant result of the Cenozoic collision of India and Eurasia that caused a tectonic reactivation of the Palaeozoic Gorny–Altai (GA) and West Sayan (WS) blocks.The present work reports of a pilot fission-track study performed on 13 apatite separates collected from rocks that were sampled along two profiles in close proximity of the lake. The age–length data and AFT thermochronological modelling reveal two important phases of cooling in the Altai Mountains, a first one during the Late Jurassic–Early Cretaceous and a second one that started in the Miocene–Pliocene and that persists until today. The first event is interpreted to result from uplift-induced denudation probably related to the closure of the Mongol–Okhotsk Ocean; the second event can be linked to the young Cenozoic movements that lie at the origin of the formation of the Lake Teletskoye basin.     

Lithium and lithium isotope profiles through the upper oceanic crust: a study of seawater-basalt exchange at ODP Sites 504B and 896A

Ocean Drilling Program (ODP) Hole 504B near the Costa Rica Rift is the deepest hole drilled in the ocean crust, penetrating a volcanic section, a transition zone and a sheeted dike complex. The distribution of Li and its isotopes through this 1.8-km section of oceanic crust reflects the varying conditions of seawater alteration with depth. The upper volcanic rocks, altered at low temperatures, are enriched in Li (5.6-27.3 ppm) and have heavier isotopic compositions (δ⁷Li=6.6-20.8‰) relative to fresh mid-ocean ridge basalt (MORB) due to uptake of seawater Li into alteration clays. The Li content and isotopic compositions of the deeper volcanic rocks are similar to MORB, reflecting restricted seawater circulation in this section. The transition zone is a region of mixing of seawater with upwelling hydrothermal fluids and sulfide mineralization. Li enrichment in this zone is accompanied by relatively light isotopic compositions (−0.8-2.1‰) which signify influence of basalt-derived Li during mineralization and alteration. Li decreases with depth to 0.6 ppm in the sheeted dike complex as a result of increasing hydrothermal extraction in the high-temperature reaction zone. Rocks in the dike complex have variable isotopic values that range from −1.7 to 7.9‰, depending on the extent of hydrothermal recrystallization and off-axis low-temperature alteration. Hydrothermally altered rocks are isotopically light because ⁶Li is preferentially retained in greenschist and amphibolite facies minerals. The δ⁷Li values of the highly altered rocks of the dike complex are complementary to those of high-temperature mid-ocean ridge vent fluids and compatible to equilibrium control by the alteration mineral assemblage. The inventory of Li in basement rocks permits a reevaluation of the role of oceanic crust in the budget of Li in the ocean. On balance, the upper 1.8 km of oceanic crusts remains a sink for oceanic Li. The observations at 504B and an estimated flux from the underlying 0.5 km of gabbro suggest that the global hydrothermal flux is at most 8×10⁹ mol/yr, compatible with geophysical thermal models. This work defines the distribution of Li and its isotopes in the upper ocean crust and provides a basis to interpret the contribution of subducted lithosphere to arc magmas and cycling of crustal material in the deep mantle.