电感耦合等离子体质谱法测定铅合金中的微量杂质元素镉和锡

铅合金中的镉和锡由于含量较低,国家标准方法均为单一元素分析,步骤繁琐,检出限高,难以达到理想的检出要求。本文建立了应用电感耦合等离子体质谱法(ICP-MS)测定铅合金中微量级(μg/g级)杂质元素镉和锡的分析方法。采用单一的低浓度硝酸溶解铅合金,用低温慢溶的方式使样品溶解更加完全,减少了多离子对仪器的干扰;通过铅基体匹配和加入酒石酸保证了标准与样品介质的一致性,同时避免了锡的水解;以~(103)Rh作为内标元素,~(111)Cd和~(118)Sn作为测量同位素克服了质谱干扰。方法检出限为镉0.05 ng/g、锡0.04 ng/g,比国家标准方法的检出限(1~6μg/g)低,精密度小于4%。该方法试剂用量少,减少了处理样品的复杂性,实现了合金中微量级元素的准确测定。     

黄土斜坡地震动时程分析

应用地震危险性分析理论和地震动人工合成技术，给出Newmark法中所需的地震动时程，解决了斜坡稳定性分析Newmark法中难以选取合适地震动时程的难题。通过对黄土斜坡实例计算，给出了坡体中地震动峰值加速度与深度的关系；在计算坡体位移时，提出了等效峰值加速度的概念；对比了使用地面地震动时程和使用坡体内等效地震动时程的计算结果。     

浅谈超声波透射法在灌注桩检测中的应用

目前国内外对于钻孔灌注桩水下混凝土质量检测的方法很多,如低应变反射波法、高应变动测法、单桩竖向静载抗压试验、钻芯法、超声波透射法等,每种检测方法都有它的适用范围和局限性。超声波透射法与其他检测法相比,该方法检测精度高,结果直观可靠,适合大直径桩、超长桩的基桩检测,故在钻孔灌注桩的完整性检测中,得到了广泛的运用,尤其在桥梁灌注桩中,超长、大直径桩几乎都采用了超声波透射法检测。本文对某工地大直径桩进行了超声波透射法检测,通过波形与照片对比,更好地验证了超声波透射法测试超长、大直径取得的效果。     

药用滑石粉酸中可溶物测定方法考察

考察药用滑石粉酸中可溶物测定方法的重复性、耐用性 ,分析主要影响因素。比较酸溶物提取液滤过介质对测定结果差异的影响 ;采用重量法随机测定酸溶物含量和室间差异。两种滤过介质处理对测定结果没有显著差异 ;室间测定结果没有显著差异 ;30批样品平行测定结果的 RSD值范围为 0 %～ 18.2 %。酸中可溶物测定法存在重复性和耐用性不佳的问题 ,应相应调整酸中可溶物含量限度     

Finite element analysis for a finite conductivity fracture in an infinite poroelastic medium

In the technology of oil recovery, oil production rate can be increased by generation of a vertical conductive fracture adjacent to the well-bore. In this paper the seepage flow and isothermal deformation in both the oil formation and the fracture are studied by modelling the formation as a two-dimensional infinite poroelastic medium and the conductive fracture as a one-dimensional poroelastic material, saturated by a one-phase compressible fluid. The plane strain condition is employed. Solutions for a growing conductive fracture and a stationary conductive fracture in the infinite medium are obtained by means of the finite element method based on a variational principle for the formation which can impose the governing equations of the fracture. Infinite elements are used outside the finite element domain. Numerical results indicate that the injection rate, the applied pressure and the crack mouth opening displacement at the well-bore oscillate during the propagation of the conductive fracture. The production rate of a well with the conductive fracture is compared with that of a well without the conductive fracture. Finally, a new definition of the conductivity coefficient for the conductive fracture is presented. Copyright © 1999 John Wiley & Sons, Ltd.     

Developing constitutive models from EPR‐based self‐learning finite element analysis

A constitutive model that captures the material behavior under a wide range of loading conditions is essential for simulating complex boundary value problems. In recent years, some attempts have been made to develop constitutive models for finite element analysis using self‐learning simulation (SelfSim). Self‐learning simulation is an inverse analysis technique that extracts material behavior from some boundary measurements (eg, load and displacement). In the heart of the self‐learning framework is a neural network which is used to train and develop a constitutive model that represents the material behavior. It is generally known that neural networks suffer from a number of drawbacks. This paper utilizes evolutionary polynomial regression (EPR) in the framework of SelfSim within an automation process which is coded in Matlab environment. EPR is a hybrid data mining technique that uses a combination of a genetic algorithm and the least square method to search for mathematical equations to represent the behavior of a system. Two strategies of material modeling have been considered in the SelfSim‐based finite element analysis. These include a total stress‐strain strategy applied to analysis of a truss structure using synthetic measurement data and an incremental stress‐strain strategy applied to simulation of triaxial tests using experimental data. The results show that effective and accurate constitutive models can be developed from the proposed EPR‐based self‐learning finite element method. The EPR‐based self‐learning FEM can provide accurate predictions to engineering problems. The main advantages of using EPR over neural network are highlighted.     

Tests and applications of an approach to absorbing reflected waves towards incident boundary

If the upstream boundary conditions are prescribed based on the incident wave only, the time-dependent numerical models cannot effectively simulate the wave field when the physical or spurious reflected waves become significant. This paper describes carefully an approach to specifying the incident wave boundary conditions combined with a set sponge layer to absorb the reflected waves towards the incident boundary. Incorporated into a time-dependent numerical model, whose governing equations are the Boussinesq-type ones, the effectiveness of the approach is studied in detail. The general boundary conditions, describing the down-wave boundary conditions are also generalized to the case of random waves. The numerical model is in detail examined. The test cases include both the normal one-dimensional incident regular or random waves and the two-dimensional oblique incident regular waves. The calculated results show that the present approach is effective on damping the reflected waves towards the incident wave boundary.     

上海地区单桩水平承载力的若干影响因素研究

结合上海软土地区12个场地57根单桩水平静载荷试验,研究建筑桩基单桩在水平荷载作用下的受力特点。根据试验实测数据,探讨不同桩径、不同试验加载方法及灌芯对预应力空心桩受力性状影响等因素,认为建筑工程中,可选择桩径较大或者采用在桩顶一定范围内扩大桩径的做法进行单桩水平承载力优化设计,试验加载方式建议可采用单向单循环恒速水平加载法,预应力空心桩顶部灌芯可作为水平承载力的安全储备,为软土地区类似工程的单桩水平承载力的设计和理论研究提供参考。     

强震作用下陡倾顺层岩质边坡失稳机制研究

安县茶坪乡冷浸沟陡倾顺层岩质边坡在\     

基于航测的三维建模方法研究

随着“数字城市”项目在各大城市如火如荼地发展,城市景观重建是数字城市发展的首要步骤和重要内容。本文结合实际生产项目,对基于航测的三维建模方法进行研究。航测法三维建模通过立体采集建筑物平面几何高程数据,并结合测区DEM成果、影像数据等,使用Dibud软件自动生成三维模型,然后,使用3DMAX软件参考外业采集照片精细修模,给模型贴图等。