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A method is described for assessing the strength of evidence for differences in the trends in chemical concentrations in stream water between catchments. A smoothing spline technique is used to model changes in water quality as a result of changes in flow rates, seasonal effects and an underlying trend. The method involves fitting the model twice, once with the underlying trends constrained to be identical for each river and once with the trends unconstrained. Statistical properties are assessed by simulation methods that allow for the autocorrelation in the residuals from the unconstrained fit. The method is applied to data from two streams in the Balquhidder catchments in the Highlands of Scotland and to data from the Dee, Don and Ythan rivers in the north‐east of Scotland. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
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Nitrate monitoring is commonly conducted with low-spatial resolution, only at the outlet or at a small number of selected locations. As a result, the information about spatial variations in nitrate export and its drivers is scarce. In this study, we present results of high-spatial resolution monitoring conducted between 2012 and 2017 in 65 sub-catchments in an Alpine mesoscale river catchment characterized by a land-use gradient. We combined stable isotope techniques with Bayesian mixing models and geostatistical methods to investigate nitrate export and its main drivers, namely, microbial N turnover processes, land use and hydrological conditions. In the investigated sub-catchments, mean values of NO3− concentrations and its isotope signatures (δ15NNO3 and δ18ONO3) varied from 2.6 to 26.7 mg L−1, from −1.3‰ to 13.1‰, and from −0.4‰ to 10.1‰, respectively. In this study, land use was an important driver for nitrate export. Very strong and strong positive correlations were found between percentages of agricultural land cover and δ15NNO3, and NO3− concentration, respectively. Mean proportional contributions of NO3− sources varied spatially and seasonally, and followed land-use patterns. The mean contribution of manure and sewage was much higher in the catchments characterized by a high percentage of agricultural and urban land cover comparing to forested sub-catchments. Specific NO3− loads were strongly correlated with specific discharge and moderately correlated with NO3− concentrations. The nitrate isotope and concentration analysis results suggest that nitrate from external sources is stored and accumulated in soil storage pools. Nitrification of reduced nitrogen species in those pools plays the most important role for the N-dynamics in the Erlauf river catchment. Consequently, nitrification of reduced N sources was the main nitrate source except for a number of sub-catchments dominated by agricultural land use. In the Erlauf catchment, denitrification plays only a minor role in controlling NO3− export on a regional scale. 相似文献
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We studied the relationships between streamwater chemistry and the topography of subcatchments in the Dorokawa watershed in Hokkaido Island, northern Japan, to examine the use of topography as a predictor of streamwater chemistry in a watershed with relatively moderate terrain compared with other regions of Japan. Topographic characteristics of the Dorokawa watershed and its subcatchments were expressed as topographic index (TI) values, which ranged from 4·5 to 20·4 for individual grid cells (50 × 50 m2), but averaged from 6·4 to 7·4 for the 20 subcatchments. Streamwater samples for chemical analyses were collected four times between June and October 2002 from 20 locations in the watershed. The pH of water that passed through the watershed increased from ~5·0 to 7·0, with major increases in Na+ and Ca2+ and marked decreases in NO3? and SO . Distinctive spatial patterns were observed for dissolved organic carbon (DOC), dissolved organic nitrogen (DON), and NO3? concentrations of streamwater across the watershed. Statistical analyses indicated significant linear relationships between the average TI values of subcatchments and DOC, DON, and NO3? concentrations. Furthermore, the proportion of DOC in streamwaters in the wet season increased with TI values relative to other nitrogen species, whereas NO3? concentrations decreased with TI. The gradients of soil wetness and the presence of wetlands explained many of the observed spatial and temporal patterns of DOC, DON, and NO3? concentrations in the surface waters of the Dorokawa watershed. Our results suggest that the TI is especially useful for predicting the spatial distribution of DOC, DON and NO3? in the surface waters of Hokkaido, where topographical relief is moderate and wetlands more common than in other regions of Japan. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
45.
三峡库区梁滩河流域水化学与硝酸盐污染 总被引:8,自引:1,他引:8
运用水化学和水质分析技术,测定了三峡库区梁滩河流域地表水体和地下水体中的水化学组成和硝酸盐氮含量,揭示了梁滩河流域地表水和地下水水体的水化学组成和硝酸盐污染的空间分布规律、来源及循环过程。结果表明:梁滩河流域地表水的硝酸盐污染表现为沿着地表径流从上游到下游呈现出加重的趋势,这种污染趋势与养殖业、生活和工农业废污水的沿程直接排放有着直接关系;而地下水硝酸盐污染呈现出流域上游和下游较轻、而中游东侧支流区域较重的空间分布特征,这种空间分布特征与地表水体中氨氮和有机氮的含量、地表水与地下水之间的补给排泄关系、厚层土壤包气带的存在以及土地利用状况等因素有着密切的关系。 相似文献
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实验研究了4A沸石分子筛经熔融盐处理后对KNO3和NH4NO3的吸持作用。结果表明:在实验条件下,KNO3处理后的4A沸石中含钾(以K2O计)15.01%,含NO-3 9.23%;NH4NO3处理后的4A沸石中含NO-3 10.78%,含NH+4 0.94%。熔融盐处理后的样品X射线衍射峰相对强度发生了变化,红外光谱中1 640 cm-1附近水的吸收带强度减弱,1 390 cm-1附近出现的NO-3离子的强吸收带及825 cm-1附近出现的NO-3离子的弱吸收带,以及热重-差热曲线中KNO3和NH4NO3的热失重和分解热效应均证明沸石中吸持盐的存在。处理后4A沸石分子筛的基本骨架结构没有被破坏,吸持盐的4A沸石对营养盐的储备大大提高,是潜在的缓释肥料。 相似文献
48.
Preliminary study on the dissolved and colloidal organic carbon in the Zhujiang River estuary 总被引:3,自引:0,他引:3
INTRODUCTIONEstuariescompriseamajorbiogeochemicalinterfaceconnectingthelandandthesea (Man toura,1 987) .Thebehaviorandfateofaparticularriver bornesubstanceintroducedintoanestuaryisdeterminedtoalargeextentbythebiogeochemicalpropertiesofthesubstanceaswellasp… 相似文献
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利用氮氧同位素研究桂林寨底地下河硝酸盐来源 总被引:3,自引:0,他引:3
工农业生产的迅速发展使地下水硝酸盐氮(NO3-—N)污染成为世界性的环境问题。地下水中硝酸盐的来源研究在水文地质结构特殊的西南岩溶地区就显得尤为重要。稳定氮同位素和氧同位素在地下水硝酸盐的来源示踪研究中有着广泛的应用。本研究选取岩溶地区典型地下河——广西桂林寨底地下河为研究对象,通过氮氧同位素数据,判断寨底地下河硝酸盐来源是以动物粪便为主的农家肥,为该区地下水的保护和利用提供科学依据。 相似文献