A Three-year Study of Nonmethane Hydrocarbons in Surface Air over Saxony (Germany)

Measurements of the nonmethane hydrocarbon (NMHC) mixing ratio over a period of 42 months were carried out for the first time in the air of a research station situated in the former East Germany during the SANA project. Apart from four species, all other species analysed showed a statistically significant downward trend at the 95% significance level. The decrease of the hydrocarbon concentrations was superimposed by seasonal variations. A drop of about 40% of the annual mean values from 1993 to 1995 was observed. This development reflects the dramatic changes in traffic, industry, power economy, and agriculture in Saxony after the reunification of Germany. The remove of two-stroke engined cars is reflected in NMHC mixing ratio changes, as is the removal of obsolete chemical plants. Generally it was not possible to relate causes and effects of a single event, but in some cases major changes in concentrations and NMHC ratios occurred coincidentally with the disappearance of a specific emission source.     

Further discussion on the intercomparison of the trace metal concentrations and particle size of fluvial sediment recovered from two centrifuge systems

A single large volume water sample taken at the mouth of the Upper Rhone River on Lake Geneva was processed directly in parallel through two continuous flow centrifuges, a Westphalia and an Alfa-Laval. Sediment was recovered from the Westphalia, and separately from the bowl and brass core of the Alfa-Laval. The three sediment samples were analyzed for particle size and the following elements: Zn, Cu, Mn, Cr, P, Co, B, V, Be, Sr, Na, Pb, Ni, Ba, Fe, Ca, and Mg. Results indicate that the particle size recovery of both machines is similar when sediment from the brass core and bowl of the Alfa-Laval are combined, and that the recovery for all elements other than Cu, V, B, and Pb are the same when the particle size differences are taken into account. Sediment from the Alfa-Laval brass core is clearly contaminated by Cu, B and is also elevated in V and Pb but not to a significant extent. The sediment recovered from the bowl of the Alfa-Laval is contaminated only with Cu, with a 10 ppm increase over the 52 ppm recovered in the Westphalia sediment. Operating procedures involve the discarding of the brass core sediment and the mixing of the Alfa-Laval bowl sediment with that from the Westphalia. The consequent increase in Cu is estimated at less than 5 ppm or within the confidence level of the analysis. These procedures are recommended to all operators of non modified Alfa-Laval units.     

Variability of sediment diatom assemblages in an upland,wind-stressed lake (Loch Fleet,Galloway, S.W. Scotland)

The variability of diatom distribution in an acidified, upland wind-stressed lake (Loch Fleet, Galloway, S. W. Scotland) was assessed by analysis of 28 surface sediment samples and 11 cores. Correspondence analysis (CA) and cluster analysis were used to illustrate the variability of the surface sediment and core samples. There was reasonable uniformity of taxa in most of the surface sediment samples, although 7 samples, as indicated by both CA and cluster analyses were atypical. Most cores recorded clearly the acidification of the lake, although percentages of individual taxa varied up to 20% between cores. Two cores had old, preacidification diatom assemblages (of indeterminate age) close to the sediment surface. These old sediments were probably the source of the re-worked diatoms found in the atypical surface sediment assemblages. Diatom trends, as CA ordinations and pH profiles, were less variable than the surface sediment assemblages. It is argued that non-uniform sediment accumulation rates and diatom deposition cause variability in surface sediment diatom samples. This variability may be reduced in core profiles by homogenization during further resuspension/deposition cycles and burial. Cores, and the associated time component they offer, may be useful in assessing the variability of surface sediment assemblages.     

渤海叶绿素 a 浓度与环境因素的响应关系研究

基于 2003－2018 年的遥感反演和再分析数据, 分别在时域和频域上分析了渤海海表面温度、光合有效辐射、气溶 胶厚度、风速与叶绿素 a 浓度之间的响应关系。通过傅里叶变换在频域上得到各因素之间的相关性系数, 其显著高于直接在 时域上计算得到的相关性系数, 表明由于相位差的影响, 直接在时域进行相关性分析很可能会低估各因素之间的相关性。傅 里叶变换后的频谱图显示, 叶绿素 a 浓度存在一年、半年、4 个月与季节周期; 风速与气溶胶厚度存在明显的一年和半年周 期; 海表面温度和光合有效辐射具有明显的一年周期, 半年周期较其他几个因素不明显。交叉谱分析的结果表明： 叶绿素 a 浓度和所选的环境因子都在一年周期下具有最大的交叉振幅, 表明在此频率下响应最大; 风速、气溶胶厚度、光合有效辐射 分别超前于叶绿素 a 浓度约 5.0 个月、0.2 个月、0.2 个月, 海表面温度则滞后 1.9 个月。各环境因子之间相互关联, 共同影 响叶绿素 a 浓度的时间分布。     

A model of regional fluid flow: Sand concentration factors and effective lateral and vertical permeabilities

Permeabilities of sand and shale differ by five to seven orders of magnitude. In the depositional pattern characteristic of the Gulf Coast, lenticular sand bodies occur randomly dispersed within a shale matrix, even though they can be grouped into stratigraphic sequences, contributing to net permeability of the sand-shale system and thus facilitating upward flow of pore water. In addition, a substantial lateral flow develops as fluid flow is directed toward sand bodies, thus concentrating fluid from a wide source area into sand bodies of limited lateral and vertical extent. Calculations reported here determine the effect of randomly distributed sands on both vertical and lateral permeabilities of composite sandshale systems. Effective permeabilities depend only on mean sand percent and local variance about the mean, because the effects of sand body shapes and their orientation and dip are not incorporated in the analysis. Results indicate that at a mean sand percentage of 20–50% a large lateral migration of fluid flow develops as sand bodies attract flow from a region two to seven times the radius of the sand body itself. For a mean sand percentage in excess of 50–60%, large vertical migration results and thus hydrocarbon trapping should not be expected for sand percentages in excess of 50–60%. Results of these calculations are in accord with observations that most larger oil accumulations on the Gulf Coast are found in regions having sandiness between about 20 and 50%.     

Holocene initiation and expansion of the southern margins of northern peatlands triggered by the East Asian summer monsoon recession

Northern peatlands represent one of the largest biospheric carbon reservoirs in the world. Their southern margins act as new carbon reservoirs, which can greatly influence the global carbon dynamics. However, the Holocene initiation, expansion and climate sensitivity of these peatlands remain intensely debated. Here we used a compilation of basal peat ages across six isolated peatlands at the southern margins of northern peatlands to address these issues. We found that the earliest initiation event of these peatlands occurred after the Younger Dryas (YD, 12,800–11,700 years ago) period. The second initiation event and rapid expansion occurred since 5 ka cal. BP. The recession of East Asian summer monsoon (EASM) during the YD period and at around 5 ka cal. BP likely played a major role in controlling the initiation and expansion of these peatlands. The rapid expansion of these peatlands possibly contributed to the significant increases in atmospheric methane concentrations during the late Holocene because of the minerotrophic fens status and rapid expansion of them. These ecological processes are different from northern peatlands, indicating the special carbon sink and source implications of these peatlands in the global carbon cycle.     

内陆水体叶绿素a浓度反演的区域化三波段模型研究

以太湖和石头口门水库为例,建立了一种可直接计算水体叶绿素a浓度的区域化三波段模型。该模型通过对研究水体的光学特性分析,明确三波段组合与叶绿素a浓度间的函数关系参数,不仅可较好指示研究水体叶绿素a浓度水平,而且大大减小了回归算法所带来的模型不确定性。利用高精度、长时间序列的水体光学特性观测数据,建立针对不同研究水体的区域化三波段模型可为实现内陆水体叶绿素a浓度遥感监测业务化运行提供方法借鉴。     

天山天池水体季节性分层特征

于2014年6-10月,对高山深水湖泊天山天池水温、电导率、溶解氧、p H值、叶绿素a浓度和蓝绿藻细胞密度进行垂直剖面的连续监测,通过对其季节动态和垂直分层结构的分析,探讨天池水体季节性分层特征.天池出现明显水温分层的时间短(6-9月),夏季温跃层变化范围为2~18 m,而秋季温跃层不断下移,10月在18 m水深以下;受水温分层影响,天池水体溶解氧浓度、电导率、p H值、叶绿素a浓度和蓝绿藻细胞密度在垂直剖面表现出明显的季节性分层,尤其是夏季水温分层影响溶解氧浓度、叶绿素a浓度和蓝绿藻细胞密度在水体中的分布,对天池水质变化产生重要影响.天池浅水层(水深小于10 m)溶解氧浓度较高(大于8 mg/L),而深水层(水深超过18 m)溶解氧浓度9月接近4 mg/L,季节性缺氧导致底泥营养盐向上扩散,对水体水质产生不利影响.所以,应在夏、秋季节加强水质监测,以防止天池水华发生;天池叶绿素a浓度与蓝绿藻细胞密度的垂直剖面变化趋势相似,均随水深增加呈先增加后减小的趋势,但叶绿素a浓度在2~12 m水深处较高,蓝绿藻细胞密度在5~15 m水深处较高,表明5~15 m深度适合藻类生长,同时,电导率、p H值的垂直变化也说明藻类的生长情况,这为监测天池水体富营养化取样和分析提供依据.     

太湖叶绿素a同化系统敏感性分析

太湖叶绿素a同化系统对于不同参数的敏感性将直接影响到该系统能否精确的估算太湖叶绿素a的浓度分布.利用2009年4月21日环境一号卫星(HJ-1B CCD2)影像数据反演太湖叶绿素a浓度场信息.以此作为背景场信息,结合基于集合均方根滤波的太湖叶绿素a同化系统,分析和评价了样本数目、同化时长、背景场误差、观测误差和模型误差对于同化系统性能的影响.结果表明:从计算成本、系统运行时间和同化效果等方面分析,当集合样本数目达到30~40左右时同化系统取得了较好的结果;同化系统对于背景场误差的估计变化不是很敏感,即初始场的估计是否准确对于同化系统的性能影响不是很大;同化系统对于模型误差和观测误差的变化较为敏感,不同的测试点位由于水体动力学性质不一,其敏感性的表现形式有所差异;利用数据同化方法可以有效地估算太湖叶绿素a浓度.     

CO2浓度升高对浮游藻类元素化学计量值的影响

通过梅梁湾和东太湖的四季原位实验,研究CO_2浓度升高对不同营养水平淡水生态系统中浮游藻类C、N、P元素计量值的影响.实验设置了270、380和750 ppm共3个CO_2浓度,分别代表工业革命前、当前和IPCC预测的21世纪末的CO_2浓度.结果表明梅梁湾水体营养盐浓度在四季均高于东太湖水体营养盐浓度,但梅梁湾原位实验中浮游藻类C、N、P含量却普遍低于东太湖原位实验中浮游藻类营养元素含量,并且前者在季节上变化更大.CO_2浓度升高使梅梁湾原位实验中浮游藻类C∶P比明显增加,N∶P比略有增加,这种增加归因于藻细胞内C、N含量的升高,而东太湖浮游藻类化学计量值对CO_2浓度变化的响应不显著.因此浮游藻类元素化学计量值对CO_2浓度变化的响应程度与水体营养盐的绝对浓度无关,而与浮游藻类的生长是否受营养盐限制有关,只有当藻类生长受到水体营养盐浓度限制时,CO_2浓度升高才会显著改变其元素组成.