1993—2006年中国区域酸雨变化特征及成因分析

中国气象局酸雨站网始建于1989年,最初仅有22个。1993—2005年,一直维持在85至88个,经2006和2007年两次扩建达到294个站。考虑到资料的连续性,本文是以80多个酸雨观测站有系统观测以来(即近14年)的酸雨观测资料为基础,经过客观统计分析,得出中国酸雨的时空变化特征。总的来说,中国酸雨区主体位于长江以南的广大地区,北方也存在小范围的酸雨区。从全国来看,酸雨发生范围总体上呈扩大趋势,北方酸雨发生范围扩大明显,南方基本保持不变;而且,酸雨污染重灾区由西南逐步转移至华中和华南中部。就酸雨强度而言,1993—1998年是最强阶段,1999—2002年强度有所降低,2003—2006年酸雨强度重又持续加强,到2006年已达到1993—1998年的平均水平;另一个显著特点是北方酸雨强度加强非常明显。对于中国区域降水酸度变化的成因,本文利用中国SO2排放量的变化和大气成分本底站降水化学的监测资料进行了分析和阐述。     

An analysis of chemical loads and forms in overland flow from dairy pasture in South Australia

Two adjacent subcatchments on soils with very strong texture contrast between the A soil horizons (sandy loam texture) and B soil horizons (clay texture) in the Adelaide Hills, South Australia were instrumented to collect overland and subsurface flow from dairy pasture. Subcatchments were defined by exclusion drains in the upper reaches and stainless steel barriers at the lower boundary. Water samples were analysed for 20 different chemical fractions. Chemical loads were examined in order to determine relationships among simple empirical event and site characteristics, and between chemical fractions. All but five of the chemical fractions could be separated into one of two clear groups using a statistical technique based on the magnitude of simple correlation coefficients. The two groups consisted of either dissolved or particulate fractions. The clear separation into these groups is consistent with the majority of chemical fractions moving from pasture by one of only two processes. Simple empirical variables in a multiple regression explained a high proportion of variation in chemical loads in runoff water. These findings may have major implications in the modelling and prediction of chemical loads in runoff from agricultural catchments and the setting of environmental limits, in simplifying chemical loss predictions by adding a nutrient loss module to runoff volume predictions. Copyright © 2001 John Wiley & Sons, Ltd.     

Product Evaluation for the Control of Chemical Emissions to Indoor Air – 10 Years of Experience with the AgBB Scheme in Germany

Emissions from construction products may have a significant impact on the quality of indoor air, particularly in energy‐efficient buildings, where the normal rate of air exchange with fresh ambient air may be limited. In this context, reduction strategies to mitigate the concentration of chemicals in the indoor environment have become even more important. German authorities wanted to foster the development of low‐emission products, and as a result it was necessary to quantify and qualify these emissions in a reliable and objective manner. The core principles for evaluation of the standardized measurements in emission tests were established by the “Committee for Health‐Related Evaluation of Building Products” (AgBB) and published in the so‐called “AgBB scheme”. Relevant for evaluation are: (i) Assessment of the emission levels of substances with known toxicological properties; (ii) limits for non‐assessable or unknown substances; (iii) limits for the total amount of chemical emissions. This review describes the stepwise implementation of the test procedure in Germany and the experience gained in evaluation of product emissions over the years. A comprehensive overview of the philosophy, history, current practices, and future directions of the German AgBB scheme for VOC emissions is also provided. Special emphasis is given to the evaluation of a list of about 170 single substances which have an agreed “lowest concentration of interest” (LCI) value for the indoor environment – values that are updated periodically according to present toxicological knowledge.     

杭州城区水域中PAEs分布特征及黄颡鱼(Pelteobagrus vachelli)体内残留消除研究

采用气相色谱(GC-FID)检测技术,对杭州城区水体以及黄颡鱼(Pelteobagrus vachelli)肌肉和脑等可食性组织中5种PAEs类化合物进行检测,确定杭州城区水体中PAEs分布特征,并分析了PAEs在黄颡鱼肌肉和脑中含量随时间动态变化规律。研究结果表明,杭州城区水体中5种PAEs化合物含量均较高,但每种化合物含量差异较大,其中DEHP含量在不同水域中含量均最高。黄颡鱼体内残留检测结果显示,5种PAEs类化合物在黄颡鱼肌肉和脑等可食性组织中均有分布,其中脑和肌肉中的消除半衰期处于17.33—32.54h之间。结果表明,PAEs在杭州城区不同水体中广泛分布,在鱼体肌肉和脑等可食性组织中消除较缓慢。     

Characteristics of the Acid Rain Variation in China During 1993-2006 and Associated Causes

The acid rain observation network of China Meteorological Administration was established in 1989 with 22 stations.From 1993 to 2005,more than 80 stations were included and maintained in the network.In 2006-2007,the number of stations in the network went up to 294.In consideration of the data continuity,data used in this paper are the 14-yr observations of the 80 stations from 1993 to 2006.Based on the 14-yr observation of acid rain,analysis shows that the acid rain in China dominates in the vast regions south of the Yangtze River.Limited presence of acid rain is observed in the northern part of China.The 14-yr acid rain data reveal an expanding tendency for acid rain area,with the north of China being a growing zone,and the South China remaining virtually unchanged.The most severely polluted zone of acid rain gradually moves from Southwest China to Central China and the middle part of South China.With regard to the acid intensity of rain,the period of 1993-1998 bears the highest acid intensity; the period of 1999-2002 shows a bit weakening intensity; and in the period of 2003 2006,the acid intensity of rain increases again,basically up to the average acidity of the period of 1993-1998 by the end of 2006.In addition,rain acidity in the north of China increases markedly.As to the causes of the acid rain situation in China,this paper examined the sulfur dioxide emissions as well as the rainwater chemicals monitoring data.     

BOOK REVIEWS

Book Reviewed in this article: The Rice Economy of Asia . Randolph Barker and Robert W. Herdt with Beth Rose. Using Microcomputers: A Guidebook for Writers, Teachers, and Researchers in the Social Sciences . Blaine A. Erie—the Lake that Survived . Noel M. Burns. Geology and Society . Donald R. Coates. Caves and Karst of Kentucky . Percy H. Dougherty, ed. Altered Harvest: Agriculture, Genetics, and the Fate of the World's Food Supply . Jack Doyle. The Middle East and North Africa, A Political Geography . Alasdair Drysdale and Gerald H. Blake. Clamor at the Gates. The New American Immigration . Nathan Glazer, ed. Development and the Landowner: An analysis of the British experience . Robin Goodchild and Richard Munton. Discovering Landscape in England and Wales . Andrew Goudie and Rita Gardner. The Modern Plantation in the Third World . Edgar Graham and Ingrid Floering. Social Relations and Spatial Structures . Derek Gregory and John Urry, eds. The World Food Problem 1950–1980 . David Grigg. Costa Rica: A Geographical Interpretation in Historical Perspective . Carolyn Hall. The Urbanization of Capital: Studies in the History and Theory of Capitalist Urbanization . David Harvey Consciousness and the Urban Experience: Studies in the History and Theory of Capitalist Urbanization . David Harvey. Reviving Main Street . Deryck Holdsworth, ed. Rural Roads and Poverty Alleviation . John Howe and Peter Richards, eds. Uneven Development in Southern Europe: Studies of Accumulation, Class, Migration and the State . Ray Hudson and Jim Lewis, eds. Karst Geomorphology . J. N. Jennings. The Geomorphology of North-west England . R. H. Johnson, ed. Climate Impact Assessment: Studies of the Interaction of Climate and Society . Robert Kates, Jesse Ausubel, Mimi Berberian, eds. Public Service Provision and Urban Development . Andrew Kirby, Paul Knox, and Steven Pinch, ed. State and Market: The Politics of the Public and the Private . Jan-Erik Lane, ed. Living Cities . Twentieth Century Fund Task Force on Urban Preservation Policies. World Climatic Systems . John G. Lockwood. Urban Ethnicity in the United States. New Immigrants and Old Minorities . Lionel Maldonaldo and Joan Moore, eds. Culture and Conservation: The Human Dimension in Environmental Planning . Jeffrey A. McNeely and David Pitt, eds. The Andean Past. Land, Societies, and Conflicts . Magnus Mörner. Gaia: An Atlas of Planet Management . Norman Myers, ed. Progress in Industrial Geography . Michael Pacione, ed. Progress in Political Geography . Michael Pacione, ed. Rivers and Landscape . Geoff Petts and Ian Foster. Urbanization and Planning in the 3rd World: Spatial Perceptions and Public Participation . Robert B. Potter. One Island, Two Nations? A Political Geographical Analysis of the National Conflict in Ireland . D. G. Pringle. Circulation in Third World Countries . R. Mansell Prothero and Murray Chapman. The Ozarks Outdoors: A Guide for Fishermen, Hunters, and Tourists . Milton D. Rafferty. Suburban Burglary: A Time and a Place for Everything . George Rengert and John Wasilchick. Geomorphology and Soils . K.S. Richards, R.R. Arnett, and S. Ellis, eds. The Homes and Homeless of Post-War Britain . Frederick Shaw. Indochinese Refugees in America . Paul J. Strand and Woodrow Jones, Jr. Wild Horses and Sacred Cows . Richard Symanski. Forever Wild: Environmental Aesthetics and the Adirondack Forest Preserve . Philip G. Terrie. The Regional Economic Impact of Technological Change . A.T. Thwaites and R.P. Oakey, eds. The Good Life . Yi-Fu Tuan.     

碱/表面活性剂/聚合物相互作用对河间油藏油水界面张力特征的影响

在任丘油田河间油藏油层及流体性质（90℃温度、矿化度为5 192.2 mg/L的采出水和5 682.6 mg/L的注入水、河间原油）的条件下,研究了表面活性剂、碱和聚合物相互作用对油水界面张力的影响。结果表明,单一石油磺酸盐CDS-1在有效浓度为0.01%-0.3%范围内,瞬时动态界面张力和平衡界面张力降低到10^-2mN/m数量级。向浓度为0.05%的CDS-1溶液中加入Na2CO3,瞬时动态界面张力和平衡界面张力变化不大,仍在10^-2mN/m数量级;与Na2CO3高浓度相比,当Na2CO3浓度为0.5%时,平衡界面张力和瞬时界面张力降低明显,瞬时动态界面张力最低值低至10^-3mN/m数量级。分别在浓度为0.05%的CDS-1溶液和0.5%Na2CO3/0.05%CDS-1二元体系中加入不同浓度（浓度在500-2 500 mg/L范围内）的部分水解聚丙烯酰胺聚合物M2500,瞬时动态界面张力和平衡界面张力无明显变化,仍在10^-2mN/m数量级。该实验结果为河间油藏表面活性剂复合驱油配方的筛选提供了重要依据。     

Preparation of cationic chitosan-polyacrylamide flocculant and its properties in wastewater treatment

Chitosan derived from crab shells,was used to prepare the graft polymer in aqueous solution with acrylamide (AM) and methacrylatoethyl trimethyl ammonium chloride (DMC) as raw materials and ceric ammonium nitrate (CAN) as initiator.The floc-culation ability of the resulting polymer (PCAD) was studied in waste water treatment experiments.Its properties were determined on the basis of the transmittance of waste water after flocculation.The effects of chitosan and DMC content on PCAD’s flocculation ability wer...     

Effects of 17beta-estradiol on the reproduction of Java-medaka (Oryzias javanicus), a new test fish species

17β-estradiol (E2) is a female hormone which is known to be one of the strongest estrogenic chemicals in the environment. The present study investigated the effects of E2 on the reproduction of the estuarine fish, Java-medaka (Oryzias javanicus). Starting from the embryonic stages, Java-medaka was exposed for 6 months to 9.5, 16, 68, 159 and 243 ng/l of E2. The fecundity of Java-medaka exposed to E2 levels >16 ng/l was significantly lower than that of the control. The appearance of secondary sexual characteristics seemed to be inhibited by exposure to 159 and 243 ng/l E2. Vitellogenin concentrations in the liver of male fish exposed to 68, 159 and 243 ng/l were significantly higher than that of the control. Thirty-three and sixty percent of male fishes exposed to 159 and 243 ng/l, respectively, had testis-ova. These results suggest that reproduction in the Java-medaka, especially the male fish, could be affected by exposure to E2 concentrations greater than 16 ng/l.     

THE NATIONAL PATTERN OF AIRBORNE TOXIC RELEASES

Incident-specific data reveal the spatial patterns of two major classes of acute toxic airborne releases in the United States (1982–86): rural agricultural and urban industrial. Rural (primarily truck transport) incidents dominate the distribution in the western US, while rail incidents and fixed site incidents dominate in the east. Using a combination of cartographic and statistical analyses, risk and mitigation measures were calculated to identify high-hazard and low-hazard states. Risk factors, primarily numbers of chemical firms and rail miles per state, best predict the frequency of incidents and their resulting spatial pattern.