煤岩显微组分热解气相色谱特征与化学结构剖析

煤结构是目前地球化学研究领域中的一个难点，但却具有极其重要的理论及实际意义，本文采用分步热解气相色谱技术将树皮体，镜质体和丝质体分解为分子量较小的可测定的有机化合物，在此基础上，据不同温度下热解产物的组成特征来还原显微组分的化学结构，实验结果表明，煤显微组分主要由四大类官能团组成，一是热稳定性较低的NOS杂原子官能团；二是脂族（脂链、脂环）结构；三是苯、烷基苯（甲苯、二甲苯）、萘等芳香族化合物，四是热稳定性很高的难以分解的稠环芳烃。上述四类化合物集中于显微组分的不同结构简单中，树皮体和镜质体结构单元外侧主要由热稳定性较低的杂原子化合物以及分子量较小的苯和烷基苯组成，而丝质体结构单元外侧则主要以短链脂族结构为主，三组分结构核部由热稳定性很高的难以分解的稠环芳烃组成。连结核部稠环芳烃与结构单元外侧杂原子等官能团的主要是热稳定性较高的脂链结构，煤显微组分热成烃主要按结构中各官能团键的强弱随热演化程度的加深依次脱除，生成油气，基本上属平行独立依次反应机制，亦“官能团脱除型”，此外，还包括少量的长链脂族结构裂解为短链脂肪烃的“解聚”过程。     

Weathering control over geomorphology of supermature Proterozoic Delhi quartzites of India

Quartz and quartzite are thought to be resistant as a mineral and a rock respectively; however, we have shown that the presence of small amounts of pyrite in the quartzites makes them vulnerable to weathering. We observe that weathering of Proterozoic quartzite in the semi‐arid conditions around Delhi proceeded from fractures towards the inside and produced weathering rinds. The chemical index of alteration (CIA), which is actually a measure of weathering of aluminosilicate minerals, increases from the core outwards, through the rinds. Although aluminosilicate minerals occur only as minor phases (<2 per cent), their weathering indicates a movement of the weathering front from the periphery towards the core. We have suggested a coupled mechanism in which the dissolution of pyrites by moving water produced a sulphate‐bearing acidic solution and ferrous iron, which reacted with aluminosilicate minerals and quartz, respectively. This initially makes the Delhi quartzite porous and subsequently friable. The total disintegration of grain to grain contacts imparted friability to this quartzite to produce silica sand. Subsequent physical erosion of loose sand, produced during rind development in the outermost zones, has given rise to features like tors, spheroids, gullies, cavities and small‐scale caves on these quartzites. Thus, the terrain has acquired ruggedness in semi‐arid conditions. Copyright © 2003 John Wiley & Sons, Ltd.     

A Linear Programming Approach to Determine the Normative Composition of Sedimentary Rocks

The analysis of modal and normative composition of sedimentary rocks is widely used for studying their sources and tectonic settings. The normative calculation of the mineral composition of rocks in this study is formulated as a linear programming problem and is solved by means of the simplex method. This enables both simultaneous and successive subtraction of a set of basic minerals from a rock sample represented by its chemical composition {SiO₂...LOI}. Such an approach provides a more exact calculation of the contribution of basic minerals in the rock. This mathematical approach is used to study two representative sets of sandstones and fine-grained rocks from a Meso- to Neoproterozoic marginal basin of southeastern Siberia (Uchur–Maya region, Yakutia) and a Pennsylvanian-Lower Permian uplifted continental block in Colorado, USA. The calculated normative mineral compositions of the Siberian sandstones are consistent with the observed modal compositions. These sandstones vary from K- Feldspar rich arkoses at the base of the sequence (the Uchur Group, lower Riphean) to quartz arenites or lithic sandstones and wacke in transgressive successions of the middle-upper Riphean. Arkoses and quartz arenites are dominant in Meso- to Neoproterozoic Siberia. These samples represent craton interior uplifted basement and quartzose, recycled orogen provenance of a stable craton in Rodinia. There are higher but consistent discrepancies between the calculated and observed compositions for the Pennsylvanian to Lower-Permian arkoses and quartz arenites (Sangre de Cristo, Belden, and Maroon Formations). The differences between the predicted and observed mineralogy may be due to uncertainties in the modes in the matrix and cement of the sandstones. This normative program should supplement modal calculations and provide better genetic constructions, especially in case of matrix-rich sandstones.     

止水帷幕在高层建筑深基坑中的应用

某高层建筑基坑西侧紧邻一道河沟,水量较大,采取三重管高压摆喷帷幕止水[1～4],施工完成后通过监测,未发现渗漏、地下水位明显下降和周围建筑物沉降现象。     

Rivers, chemical weathering and Earth's climate

We detail the results of recent studies describing and quantifying the large-scale chemical weathering of the main types of continental silicate rocks: granites and basalts. These studies aim at establishing chemical weathering laws for these two lithologies, describing the dependence of chemical weathering on environmental parameters, such as climate and mechanical erosion. As shown within this contribution, such mathematical laws are of primary importance for numerical models calculating the evolution of the partial pressure of atmospheric CO₂ and the Earth climate at geological timescales. The major results can be summarized as follow: (1) weathering of continental basaltic lithologies accounts for about 30% of the total consumption of atmospheric CO₂ through weathering of continental silicate rocks. This is related to their high weatherability (about eight times greater than the granite weatherability); (2) a simple weathering law has been established for basaltic lithologies, giving the consumption of atmospheric CO₂ as a function of regional continental runoff, and mean annual regional temperature; (3) no such simple weathering law can be proposed for granitic lithologies, since the effect of temperature can only be identified for regions displaying high continental runoff; (4) a general law relating mechanical erosion and chemical weathering has been validated on small and large catchments. The consequences of these major advances on the climatic evolution of the Earth are discussed. Particularly, the impacts of the onset of the Deccan trapps and the Himalayan orogeny on the global carbon cycle are reinvestigated. To cite this article: B. Dupré et al., C. R. Geoscience 335 (2003).     

地下气体运移变化的物理化学机制研究

在河北省怀来县后郝窑地区，对地下气体运移变化的影响因素进行了野外模拟实验研究。选择３个试验点，对地下气体的扩散作用，物理化学影响因素及水压效应等进行了模拟实验，主要研究Ｈ２，ＣＯ２气体运移变化机制。实验研究表明，Ｈ２，ＣＯ２气体运移变化机制不尽相同，水压效应对Ｈ２，ＣＯ２等地下气体运移影响相当明显     

Disequilibrium for Ca during growth of pelitic garnet

Compositional zoning in hundreds of almandine-rich garnets in amphibolite by facies micaceous quartzites from the Picuris Range, north-central New Mexico USA, indicates that although Mn, Mg and Fe achieve chemical equilibrium at hand-sample scale during garnet growth, Ca does not. Instead, Ca concentrations at the surface of growing garnets appear to depend strongly on kinetic factors that govern the local chemical environment, yielding disequilibrium for Ca at scales larger than the region immediately surrounding an individual porphyroblast. Detailed zoning profiles were obtained for 371 garnet crystals in a small volume of a single sample of garnetiferous quartzite, and core analyses were made of 97 additional crystals. Each analysis was made on a section that passed precisely through the morphological centre of the crystal, located by means of 3-D imagery from computed X-ray tomography. The data reveal strong correlations between crystal size and concentrations of Mn, Mg and Fe (but not Ca) in garnet cores; a relationship between crystal size and isolation; rigorous cross-correlations among concentrations of Mn, Mg and Fe (but not Ca); and systematic variations in Ca concentrations as a function of crystal size and core composition that are anomalous in comparison to the behaviour of the other divalent cations. We interpret these observations as the result of thermally accelerated diffusion-controlled garnet growth, in circumstances that promoted rapid intergranular diffusion and thus rock-wide equilibration of Mn, Mg and Fe, but that prevented equilibration at similar scale for Ca because of its more sluggish intergranular diffusion. The anomalous behaviour of Ca is made evident in these garnets by the presence of sharp spikes in Ca concentration, which are demonstrably not a consequence of any simultaneous rock-wide event, such as a change in pressure, temperature, or some other intensive parameter. Instead, Ca concentrations probably reflect the local extent of reaction in the immediate vicinity of each porphyroblast. To the degree that such kinetic factors introduce departures from chemical equilibrium for Ca, thermobarometric estimates that involve grossular contents of pelitic garnet will be in error.     

榴辉岩中铁铝榴石的测定方法研究

对国内主要矿区铁铝石榴子石纯矿物中铁的价态规律进行了研究。证明其所含Ｆｅ均以Ｆｅ＾２＋为主，其质量分数在８３－９４，并将Ｆｅ＾２＋这特征性成分用于某地榴辉岩中铁铝榴石的间接测定，获得结果与焙烧磁化－磁选法一致且精度好，较磁化法简便，快速。     

遥感技术在化工环境保护中的应用

遥感技术获取的可见光、红外及微波信息，可以对化工企业及化学矿山环境污染（水、粉尘、大气、废渣污染等）及环境地质灾害（滑坡、泥石流、地面塌陷等）进行实时动态监测，并可获得较高的社会经济效益，达到地面环保及常规环境地质工作难以达到的效果。特别是对重点大中型化工企业及化学矿山建立环境遥感信息动态监测系统，可以为国家决策部门及时准确地提供环境治理和改造的依据。     

论湖南柿竹园多金属矿床成岩成矿的化学模式─—与毛景文先生等商榷

从湖南柿竹园多金属矿床成岩成矿的事实出发，用化学基本定律对其矽卡岩的形成，蚀变及成岩成矿的化学反应方程式进行研讨，建立了比较符合矿床实际与地球化学理论的化学模式。认为地球科学与化学是在相互交叉，相互渗透，相互促进中共同发展的。