海洋碳循环模式(Ⅱ)——对印度洋的模拟结果分析

把建好的海洋碳模式应用于印度洋区域,模拟得到了印度洋中与碳有关各化学量的表层分布、垂直分布和沿子午线面的等值线分布。与实测的ＧＥＯＳＥＣＳ（ＧｅｏｃｈｅｍｉｃａｌＯｃｅａｎ—Ｓｅｃｔｉｎｎ Ｓｔｕｄｙ）数据作对比,模式较好地再现了印度洋上营养盐浓度、总碳浓度、总碱度和溶解氧的二维分布。通过模拟还发现,在稳定状态下,大气和海洋中总碳含量的分布依赖于发生在海洋中的各种物理化学过程及边界条件,水平扩散系数Ｋｈ和光合作用常数率Ｋｇ对各化学量的分布有较大影响（以前有学者认为不太重要,如 Ｂａｅｓ［１］）;南印度洋中纬地区 １０°Ｓ至 ３０°Ｓ是１４Ｃ的重要向下渗透区域,人为排放的ＣＯ２可通过这片渗透区从海洋的表层输入海洋的深层。     

利用X射线衍射和岩矿鉴定等技术研究河南汤家坪钼矿区主要矿物标型特征

汤家坪钼矿床是2006年探明的一处大型斑岩型钼矿床,前人用常规地质方法对该矿区基础地质工作和成矿规律研究已比较系统和完整,认为汤家坪钼矿床属于深源浅成斑岩型钼矿床,汤家坪花岗斑岩体为矿区钼矿的成矿母岩;但是没有从矿物学角度来应证这些成矿规律。本文从矿物学角度,采用分离单矿物进行化学分析、X射线衍射(XRD)及岩矿鉴定等技术,对汤家坪钼矿区的辉钼矿、黄铁矿、石英、长石4种矿物标型特征(化学组成、微量元素、晶体结构、晶胞参数、结构状态等)进行研究。结果表明:1该矿区辉钼矿全部是2H型多型变体,且成分中Re含量很低;辉钼矿的δ34S值为3.0‰,硫同位素变化范围小,接近于陨石硫,具深源硫的特点,硫来源于花岗斑岩。2黄铁矿微量元素以富含Mo、Co、Cu,贫Ni、Pb、Zn为标型特征,另外Au、Ag含量低,S/Se大于250000,与前人"S/Se大于250000~500000的地区不可能找到金矿"的结论相符。3石英富含Mo;成矿期石英脉中δ18O降低,表明成矿晚期有少量大气降水参与热液蚀变成矿。4长石富含Mo;轻稀土(La~Nd)含量大于中稀土(Sm~Ho)和重稀土(Er~Y)含量;钾长石的有序度、三斜度以及结构参数的值均较高,结构温度较低,表明该矿区钾长石为低温状态下的三斜对称的微斜长石,是热液作用的产物,岩体钾长石化对钼矿化最为有利。本研究应证了汤家坪钼矿床属于深源浅成斑岩型钼矿床,对于总结斑岩型钼矿成矿规律、找矿标志有重要意义。     

地下气体运移变化的物理化学机制研究

在河北省怀来县后郝窑地区，对地下气体运移变化的影响因素进行了野外模拟实验研究。选择３个试验点，对地下气体的扩散作用，物理化学影响因素及水压效应等进行了模拟实验，主要研究Ｈ２，ＣＯ２气体运移变化机制。实验研究表明，Ｈ２，ＣＯ２气体运移变化机制不尽相同，水压效应对Ｈ２，ＣＯ２等地下气体运移影响相当明显     

巴丹吉林沙漠湖泊与地下水的补给来源及化学组成(英文)

Based on the analysis of ion chemical composition of lake water and shallow groundwater in the Badain Jaran Desert, this paper discussed the characteristics of ion chemical composition, spatial variation of lake water, and possible supply sources of lake water and groundwater in the desert areas. The results show that the pH, salinity, TDS and electrical conductivity of the lake water are greater than those of groundwater. The ion con-tents of water samples are dominated by Na+ and Cl?. Most of the higher salinity lakes are Na (K)-Cl-(SO4) type, and a few of low salinity lakes belong to the Na-(Mg)-(Ca)-Cl-(SO4)-(HCO3) type. Most of the groundwater is Na-(Ca)-(Mg)-Cl-(SO4)-(HCO3) type, attributed to subsaline lake, and only a few present the Na-Cl-SO4 type, flowing under saline lake. The pH, salinity, TDS and electrical conductivity in the southeastern lakes are relatively low, and there are slightly alkaline lakes. The pH, salinity, TDS and electrical conductivity in the northern lakes are much greater than those of the southeastern lakes, and the northern lakes are moderately alkaline and saline ones. In the southeastern part of the Badain Jaran Desert, the ion chemical characteristics of the lake water from south to north show a changing trend of sub-saline →saline→hypersaline. The changing trend of chemical compositions of ions in recent 9 years indicates that most of the ion contents have a shade of reduction in Boritaolegai, Badain, Nuoertu and Huhejilin lakes, which state clearly that the amount of fresh water supply is increasing in the 9-year period. The ion chemical composition of the lake water reveals that the flow direction of lake water is from southeast to northwest in the Badain Jaran Desert. The ion chemical composition, moisture content of sand layer water level height and hierarchical cluster analysis of the lake water and groundwater demonstrate that the lake water is mainly supplied by local rainfall and infiltration of precipitation in Yabulai Mountains and Heishantou Mountain, and the supply from the Qilian Mountains is almost impossible.     

水泥粘结剂基材边坡绿化技术研究——现场试验研究

通过现场工程试验研究,进一步论证了水泥粘结基材替代化学粘结基材的岩质边坡绿化技术的可行性;同时提出了岩质边坡工程绿化应按"循序渐进"来进行植被恢复的理念.     

秦岭主峰太白山北麓降水化学特征分析

利用太白山北麓2011年12月-2013年7月共39次降水样品数据资料, 定量分析了该区域降水化学的特征和时间变化规律. 结果表明: 太白山北麓地区降水中, 除常量离子Na⁺、NH₄⁺、K⁺、Mg²⁺、Ca²⁺、F^-、Cl^-、SO₄^2-、NO₃^-外, CO₃^2-、HCO₃^-、PO₄^3-及低分子有机酸也占有相当比例. 研究区降水常量离子浓度的顺序依次为: NH₄⁺ > SO₄^2- > Ca²⁺ > NO₃^- > Na⁺ > Cl^- > Mg²⁺ > K⁺ > F^-, 离子总浓度表现出明显的季节变化: 夏季(轻度污染) < 秋季(中等污染) < 春季(严重污染) < 冬季(极重污染). 利用因子分析法得出太白山北麓地区降水组分主要有三种来源; Na⁺、Cl^-、Mg²⁺、Ca²⁺主要来自地壳源, SO₄^2-、NO₃^-、NH₄⁺主要来自人为源, K⁺和F^-主要由海盐源和人为源共同贡献. 根据Hysplit 后向气流轨迹分析, 得出不同路径气团降水离子组分不同: 受地形等因素影响, 北方路径的气团比南方路径气团离子总浓度较高; 受土壤类型影响, 西北方向气团降水Na⁺、Mg²⁺、Ca²⁺浓度较高; 受人为活动影响, 东北方向SO₄^2-、NO₃^-、NH₄⁺浓度较高.     

A Linear Programming Approach to Determine the Normative Composition of Sedimentary Rocks

The analysis of modal and normative composition of sedimentary rocks is widely used for studying their sources and tectonic settings. The normative calculation of the mineral composition of rocks in this study is formulated as a linear programming problem and is solved by means of the simplex method. This enables both simultaneous and successive subtraction of a set of basic minerals from a rock sample represented by its chemical composition {SiO₂...LOI}. Such an approach provides a more exact calculation of the contribution of basic minerals in the rock. This mathematical approach is used to study two representative sets of sandstones and fine-grained rocks from a Meso- to Neoproterozoic marginal basin of southeastern Siberia (Uchur–Maya region, Yakutia) and a Pennsylvanian-Lower Permian uplifted continental block in Colorado, USA. The calculated normative mineral compositions of the Siberian sandstones are consistent with the observed modal compositions. These sandstones vary from K- Feldspar rich arkoses at the base of the sequence (the Uchur Group, lower Riphean) to quartz arenites or lithic sandstones and wacke in transgressive successions of the middle-upper Riphean. Arkoses and quartz arenites are dominant in Meso- to Neoproterozoic Siberia. These samples represent craton interior uplifted basement and quartzose, recycled orogen provenance of a stable craton in Rodinia. There are higher but consistent discrepancies between the calculated and observed compositions for the Pennsylvanian to Lower-Permian arkoses and quartz arenites (Sangre de Cristo, Belden, and Maroon Formations). The differences between the predicted and observed mineralogy may be due to uncertainties in the modes in the matrix and cement of the sandstones. This normative program should supplement modal calculations and provide better genetic constructions, especially in case of matrix-rich sandstones.     

Incipient weathering rind development on introduced machine‐polished granite discs in an Arctic alpine environment,northern Scandinavia

Weathering rinds, zones of alteration on the exterior surfaces of rock outcrops and coarse unconsolidated surficial debris are widely used by geomorphologists and Quaternary geologists as indicators of the relative age of landforms and landscapes. Additionally they provide unique insights into the earliest stages of rock and mineral weathering, yet the origin of these alteration zones is relatively poorly understood. This lack of understanding applies especially to the initial stages of rind formation. The study reported in this paper has two principal objectives. The first is to use lightly polished granite discs inserted in soil profiles under several different plant communities in an Arctic alpine environment for a period of four or five years to investigate the nature of incipient weathering rind development. The second is to investigate the factors responsible for spatial variability in the nature and rates of rind formation. Incipient weathering rind development on the outer edges of the granite discs is observable and measurable over a period of time as short as four years in the mild Arctic alpine environment of Swedish Lapland. The earliest stages of rind development involve the development of a porous structure consisting of a combination of pits and fractures which have been solutionally enlarged and modified. Solution appears to be preferentially concentrated on the surfaces of feldspars and, to a lesser extent, quartz. In addition, iron oxides are present along grain boundaries and in grain interiors and are interpreted to have been derived from the oxidation of ferromagnesian minerals. Spatial variability in weathering rind development appears to be particularly driven by differences in moisture but is not related to soil pH. Copyright © 2005 John Wiley & Sons, Ltd.     

岩溶地区飞机草化学防治研究

在飞机草(Eupatorium odoratum L.)入侵严重的岩溶区,用样方法进行百草枯(paraquat)、草甘膦(glyphosate)及草甘臃与2,4-D的混合药剂防治野外飞机草试验,每种药剂分别设0.25%、0.5%和1%三个浓度.结果表明:施药5天后,各浓度百草枯处理的飞机草植株全部干枯;高浓度的草甘膦及高、中浓度的草甘膦+2,4-D处理下,飞机草植株2/3的叶干枯,茎半干枯.施药30天后,低浓度百草枯处理的飞机草的死亡率为77%,高浓度处理下的达100%,各处理的新生苗密度极显著小于对照;低浓度草甘膦和草甘膦+2,4-D处理的飞机草死亡率均为33%,高浓度处理的约为50%,各浓度处理下新生苗密度与对照均无显著差异.由此可见:(1)各浓度处理下百草枯的药效高于草甘膦和草甘膦+2,4-D的药效,对土壤中飞机草种子葫发具明显影响,宜用在飞机草单优势群落中.(2)较高浓度的草甘膦和草甘膦+2,4-D可防除大部分飞机草,对土壤中种子影响小,可考虑使用在飞机草为伴生植物的耕地、果园等生境中.