全文获取类型
收费全文 | 2394篇 |
免费 | 291篇 |
国内免费 | 556篇 |
专业分类
测绘学 | 39篇 |
大气科学 | 143篇 |
地球物理 | 371篇 |
地质学 | 1567篇 |
海洋学 | 411篇 |
天文学 | 47篇 |
综合类 | 138篇 |
自然地理 | 525篇 |
出版年
2024年 | 7篇 |
2023年 | 23篇 |
2022年 | 65篇 |
2021年 | 67篇 |
2020年 | 86篇 |
2019年 | 94篇 |
2018年 | 67篇 |
2017年 | 63篇 |
2016年 | 73篇 |
2015年 | 96篇 |
2014年 | 99篇 |
2013年 | 139篇 |
2012年 | 127篇 |
2011年 | 146篇 |
2010年 | 124篇 |
2009年 | 153篇 |
2008年 | 138篇 |
2007年 | 146篇 |
2006年 | 182篇 |
2005年 | 150篇 |
2004年 | 136篇 |
2003年 | 145篇 |
2002年 | 130篇 |
2001年 | 117篇 |
2000年 | 111篇 |
1999年 | 93篇 |
1998年 | 86篇 |
1997年 | 74篇 |
1996年 | 59篇 |
1995年 | 48篇 |
1994年 | 25篇 |
1993年 | 39篇 |
1992年 | 19篇 |
1991年 | 21篇 |
1990年 | 17篇 |
1989年 | 15篇 |
1988年 | 16篇 |
1987年 | 8篇 |
1986年 | 14篇 |
1985年 | 5篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1981年 | 7篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1975年 | 1篇 |
排序方式: 共有3241条查询结果,搜索用时 765 毫秒
221.
Sunil Bharati Richard L. Patience Steve R. Larter Guy Standen Iain J. F. Poplett 《Organic Geochemistry》1995,23(11-12)
The significance and validity of integrating data obtained from a variety of analytical techniques to understand, elucidate and model kerogen's complex chemical structure is reported here using degradative (open and closed system pyrolysis, chemical oxidation), non-degradative (13C CP/MAS NMR) and optical (incident white light and blue light) methods. Seven Cambrian Alum Shale samples, ranging in maturity from immature to post-mature with respect to petroleum generation, were studied and were chosen for their simple geological history, uniform organic matter type and high organic carbon content. The Alum Shale kerogens, which primarily consist of algal organic matter, liberate low molecular weight gaseous and aromatic compounds on pyrolysis and give mostly branched dicarboxylic acids on chemical oxidation. 13C NMR spectroscopy shows that the Alum Shale kerogens are anomalously rich in oxygen-bearing functional groups (such as C = O, ArCO, CHO, CHxO), most of which apparently remain intact within the kerogen macro-molecule (KMM) through the diagenetic and catagenetic stages. Fragments released by different degradative techniques are quantified and the aromaticity (fa), O/C and relative proportions of various carbon types estimated by 13C NMR. A synthesis of these data has allowed us to better understand the chemistry of the Alum Shale kerogen. 相似文献
222.
植物栲胶作为护壁堵漏化学灌浆材料的初步研究 总被引:1,自引:0,他引:1
介绍了以植物栲胶为主剂、甲醛为固化剂的化学灌浆材料。对栲胶种类、胶凝反应机理、胶凝时间、浆液流变特征及固结性能的初步理论分析和实验研究表明:缩合型植物栲胶可在固化剂、交联剂和催化剂的作用下,于数秒钟至180分钟内形成热固性体型高分子凝胶,并且对岩土、砂石具有良好的浸润亲和性,完全可作为钻探护壁堵漏材料。 相似文献
223.
红壤退化中的土壤质量评价指标及评价方法 总被引:97,自引:4,他引:93
土壤质量评价与监测是评价土壤退化的重要工作,也是重新设计持续性的土壤管理系统的基础。目前缺乏统一的评价指标以及将各项土壤性质与土壤管理措施结合起来的评价方法。本文首先提出了选择红壤质量评价指标的原则,并从化学、物理学和生物学三个方面初步探讨了评价红壤质量动态变化可资采用的指标体系,综述了国内在南方丘陵区红壤质量演化的研究中应用的指标;最后从土地评价方法中选择了可用于红壤质量评价的方法,并简要综述了国际上最新的土壤质量评价方法。 相似文献
224.
Ahmed A. Melegy 《中国地球化学学报》2003,22(2):150-155
1IntroductionThecomponentsoftheenvironmentaredamagedbyagriculturalpractices.Soilslosstheirfer tilityandwaterdeterioratesduetopollution .Chemicalweatheringofmineralandsoiloccursattheinterfacesbetweentheliquidandsolidphases;consequentlythesurfaceareaandcompositionofthemineralsplayanimportantroleinthisprocess.GarrelsandMackenzie ( 1 96 7)suggestedthatincon gruentweatheringreactionswouldproducedissolvedspeciesandnewsolidsthataremorestableintheweatheringenvironmentthantheoriginalbedrockminerals.Ro… 相似文献
225.
50年来我国化工地质找矿及相关的研究工作都取得了显著的成绩,虽然我国化工矿产种类较齐全,但人均占有资源量偏低,保证程度与需求相比尚有不同程度的差距。化工地质工作今后应统筹规划,突出重点;发挥优势,确保化工;面向市场,拓宽领域,狠抓基础,强化竟争;严格质量,规范管理;科技创新,加强装备;突出效益,转变机制;争取政策,多元投入。在化工地质队伍推行“三新、两高、两精”的运行机制。为确保“十五”期间工作部署能顺利实施,需要国家在宏观层面上给子相应的政策支持。 相似文献
226.
Hydrocarbon degraders from tropical marine environments 总被引:1,自引:0,他引:1
Analysis of 20 samples of marine mud and water around Mumbai resulted in the isolation of 17 bacteria and yeasts all of which were able to degrade more than 10% of the supplied crude oil. The yeasts strains were important degraders of the aliphatic fraction of crude. All the isolated yeasts belonged to the genus Candida. Using biochemical tests these were identified as Candida parapsilosis, C. albicans, C. guilliermondii, Yarrowia lipolytica, C. tropicalis and C. intermedia. Y. lipolytica was the best degrader utilizing 78% of the aliphatic fraction of Bombay High crude oil. None of these isolates degraded the aromatic or ashphaltene fractions. All the isolates required aeration, nitrogen and phosphate supplementation for optimal degradation. Four out of the six yeasts are human pathogens. 相似文献
227.
Relationship between structures of substituted indolic compounds and their degradation by marine anaerobic microorganisms 总被引:1,自引:0,他引:1
Degradation of selected indolic compounds including indole, 1-methylindole, 2-methylindole, and 3-methylindole was assessed under methanogenic and sulfate-reducing conditions using the serum-bottle anaerobic technique and marine sediment from Victoria Harbour, Hong Kong as an inoculum. Our results showed that indole degradation was achieved in 28 days by a methanogenic consortium and 35 days by a sulfate-reducing consortium. During degradation under both conditions, two intermediates were isolated, purified and identified as oxindole and isatin (indole-2,3-dione) suggesting that both methanogenic and sulfate-reducing bacteria use an identical degradation pathway. Degradation processes followed two steps of oxidation accomplished by hydroxylation and then dehydrogenation at 2- and then 3-position sequentially prior to the cleavage of the pyrrole ring between 2- and 3-positions. However, none of 1-methylindole or 2-methylindole was degraded under any conditions. 3-Methylindole (3-methyl-1H-indole, skatole) was transformed under methanogenic conditions and mineralized only under sulfate-reducing conditions. It is clear that methyl substitution on 1- or 2-position inhibits the initial attack by hydroxylation enzymes making them more persistent in the environment and posing longer toxic impact. 相似文献
228.
Harald Geiger Ian Barnes Karl H. Becker Birger Bohn Theo Brauers Birgit Donner Hans-Peter Dorn Manfred Elend Carlos M. Freitas Dinis Dirk Grossmann Heinz Hass Holger Hein Axel Hoffmann Lars Hoppe Frank Hülsemann Dieter Kley Björn Klotz Hans G. Libuda Tobias Maurer Djuro Mihelcic Geert K. Moortgat Romeo Olariu Peter Neeb Dirk Poppe Lars Ruppert Claudia G. Sauer Oleg Shestakov Holger Somnitz William R. Stockwell Lars P. Thüner Andreas Wahner Peter Wiesen Friedhelm Zabel Reinhard Zellner Cornelius Zetzsch 《Journal of Atmospheric Chemistry》2002,42(1):323-357
Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere. 相似文献
229.
Weathering rinds, zones of alteration on the exterior surfaces of rock outcrops and coarse unconsolidated surficial debris are widely used by geomorphologists and Quaternary geologists as indicators of the relative age of landforms and landscapes. Additionally they provide unique insights into the earliest stages of rock and mineral weathering, yet the origin of these alteration zones is relatively poorly understood. This lack of understanding applies especially to the initial stages of rind formation. The study reported in this paper has two principal objectives. The first is to use lightly polished granite discs inserted in soil profiles under several different plant communities in an Arctic alpine environment for a period of four or five years to investigate the nature of incipient weathering rind development. The second is to investigate the factors responsible for spatial variability in the nature and rates of rind formation. Incipient weathering rind development on the outer edges of the granite discs is observable and measurable over a period of time as short as four years in the mild Arctic alpine environment of Swedish Lapland. The earliest stages of rind development involve the development of a porous structure consisting of a combination of pits and fractures which have been solutionally enlarged and modified. Solution appears to be preferentially concentrated on the surfaces of feldspars and, to a lesser extent, quartz. In addition, iron oxides are present along grain boundaries and in grain interiors and are interpreted to have been derived from the oxidation of ferromagnesian minerals. Spatial variability in weathering rind development appears to be particularly driven by differences in moisture but is not related to soil pH. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
230.