辉碲铋矿单矿物的化学分析

辉碲铋矿物经ＨＮＯ３－ＫＣｌＯ３溶解，用火焰原子吸收法或乙二胺四乙酸二钠事滴定法测定Ｂｉ，火焰原子吸收法测定Ｔｅ、Ｆｅ、Ｃｕ，３，３＇－二氨基联苯胺光度法测定Ｓｅ，硫酸重量法测定Ｓ。其结果与矿物化学成分理论值十分接近，主、次量元素平行测定６次，其ＲＳＤ小于０．８％，痕量元素ＲＳＤ（ｎ＝６）小于１０％。     

黄土高原晋陕蒙毗邻地区土地退化遥感分析

本文利用遥感技术通过典型区的分析,对黄土高原土地退化现状及其成因过程进行了深入研究。结果表明,黄土高原地区由于特殊的自然条件,加以长期人类活动影响,土地退化十分严重,并处于不断发展之中,主要表现为水土流失和土地沙化等。     

Chemical structural units of macromolecular coal components

Chemical degradations of coal resins, coal asphaltenes and coal residues have been performed with selective, non-oxidative reagents. The coal comprise samples a rank interval 0.30–1.21 %R_m. Degraded low-molecular-weight compounds were analyzed by GC-MS. The distributions of pentacyclic terpanes, isoprenoids, n-alkanes, acids and alcohols obtained as degradation products illustrate a considerable variability between the macromolecular coal fractions. A structural study on the molecular level of the degraded compounds from coal resins and coal asphaltenes show their potential to generate hydrocarbons during coalification process.     

3D chemical model for geological macromolecules

This study defines a chemical representation of the kerogen macromolecule based on data from physicochemical analyses. The model should permit: creation of various schematic drawings representing an average macromolecule; future integration of new analytical results (for instance on structures of biomarkers or biopolymers); and determination of the distribution of chemical bonds.The models developed in this study can be represented in a 3D space, using classical chemical symbols, in the form of cyclic groups linked to each other by aliphatic chains. One cyclic group is a connected set of aromatic, naphthenoaromatic or naphthenic rings. These cyclic groups are constructed using basic elements such as atoms and bonds defined by their length and direction.Modeling of kerogen is done in three successive steps. A library is first created to define atoms, bonds and cyclic groups. Secondly, starting from a set of equations describing the analytical results, cyclic and aliphatic groups are chosen in the appropriate stoechiometric amount to match the analytical data. Finally the construction is done: cyclic groups are placed randomly in a 3D space, connections are made by aliphatic chains, and functional groups are added.The molecular modeling software Xmol^TM can be operated on APOLLO stations. It allows the creation of libraries, the calculation of chemical bonds corresponding to the analyses and the construction of macromolecules. An example is given for a type III kerogen at the beginning of diagenesis.     

第四纪盐湖型钾盐矿床的航空γ能谱异常特征及找矿模式

本文以航空γ能谱测量资料为依据，简述了与找钾有关的部分科研成果，建立了第四纪盐湖型钾盐矿床的找矿模式，进而通过对别勒滩、马海等钾盐矿例剖析，说明航空γ能潜测量在寻找第四纪盐湖型钾盐矿床方面确有明显效果。     

The Chemical Composition of Global Subducting Sediments and Its Geological Significance

Subducted sediments play an important role in crust-mantle interaction and deep mantle processes, especially for subduction zone magmatism and mantle geochemistry. The current rate of Global Subducting Sediments (GLOSS) is 0.5~0.7 km³/a. The GLOSS are composed of terrigenous material(76 wt.%), calcium carbonate(7 wt.%), opal(10 wt.%) and mineral-bound H₂O⁺(7 wt.%). The chemical compositions of GLOSS are similar to those of upper continental crust which is mainly controlled by the terrigenous materials, and yet the materials formed by marine processes will dilute the terrigenous materials. The components of subducted sediments are different among trenches. In the accretionary margin, the components of subducted sediments are similar to those of the upper crust, while in the non-accretionary margin the components are terrigenous materials plus those produced by marine processes. During subduction, subducted sediments will released fluids, melt or supercritical fluid to affect island arc/back-arc basin magmatism by means of aqueous fluid or sediment melt. In addition, a part of subducted sediments, together with underlying altered oceanic crust/lithosphere, recycle into the mantle and contribute to the mantle heterogeneity. Geochemical tracers indicate that subducted sediments play variable contributions to the magmatic processes in different tectonic setting. Thus, subducted sediments play an important role in two relatively independent dynamics systems (plate tectonics and mantle plume), as well as related mantle evolution models. As a result, by accurately calculating the compositions of subduction sediments and using various geochemical indicators, we can further limit the input and output fluxes of various elements or isotopes, and then obtain more accurately residual subducted components, which can provide us some important clues for geodynamic process.     

金矿化探

使用地球化学方法找寻金矿床近年来在我国取得突破性进展。这是因为我国将金列为区域化探全面扫面必分析的元素,将金的分析捡出限降至百亿分之几,并研制了高效率的能达到这样捡出限要求的分析方法。但今后要使化探找金的效果继续提高,还需加强研究工作,包括综合研究已发现的大量金与其伴生元素的区域异常,金在表生环境中的行为及金矿床的原生晕并探索找金的地球化学新技术。     

澜沧江上游德钦县亚高山、高山草地群落类型及其特点

摘要：采用样方调查方法获得94个草地群落样方,对澜沧江上游德钦县亚高山、高山草地群落类型及其特点进行了初步分析。结果表明,该县亚高山、高山草地群落类型存在20个类型。在放牧干扰下,大多数群落类型处于退化状态,相互之间存在明显的群落替代关系;调查发现群落中每平方米内平均含8种草本植物,平均盖度62．4％,地上平均生物量是4859kg／hm^2,平均可食率为61．5％;鸢尾群落、牛旁群落和小狼毒群落是草地严重退化后形成的典型有毒害群落类型;长期的高强度放牧虽然增加了群落类型多样性,但减少了群落内物种多样性。总体而言,长期的放牧干扰降低了德钦草地的生物多样性的质量及其生态服务功能,导致草地生态系统的非持续发展。     

Pastoralists’ perceptions and realities of vegetation change and browse consumption in the northern Kalahari, Namibia

Pastoral production around artificial watering points in semi-arid environments affects the density and composition of plant communities. In the Kalahari desert of southwestern Africa, bush encroachment is often regarded as the major form of land degradation resulting from pastoral production around watering points. We investigated the OvaHerero pastoralists’ perceptions of the extent of vegetation change since the establishment of artificial watering points in the northern Kalahari desert of Namibia, and related this to ecological data on vegetation change. We determined the utility of woody vegetation to pastoralists’ livelihoods in terms of provision of construction material, fuel wood and browse. We quantified local knowledge of cattle browse consumption and correlated this with field data. We also assessed the purposes for which major livestock types were used. Our results showed that: (1) pastoral knowledge of bush encroachment and browse consumption was consistent with concurrently collected field data, (2) the current level of bush encroachment was perceived to be beneficial for pastoral production, and (3) cattle played an important role in the production of milk and milk by-products for domestic use, and served as a source of cash income, while sheep and goats were primarily kept for meat consumption. This result contrasts with historical studies that mainly portray cattle as a symbol of social status among OvaHerero pastoralists.     

干酪根化学降解产物的碳同位素组成研究

采用一系列温和的化学降解法对松辽盆地南部嫩江组烃源岩的干酪根进行连续的选择性化学降解，并对不同降解产物进行色谱—同位素比值质谱分析。研究表明碱性水解和脱硫产物以一元脂肪酸和正构烷烃为主，其中正构烷烃碳同位素分布曲线呈现一定的“负倾”（即随碳数增加呈现逐渐贫13C）趋势；一元脂肪酸以C16和C18为主，具有明显的偶碳优势，与同碳数的正构烷烃具有相似的碳同位素组成。氧化产物则以一元脂肪酸和α,ω 二元脂肪酸为主，一元脂肪酸低碳数部分呈现“负倾”趋势，高碳数部分则呈现“正倾”的趋势；α,ω 二元脂肪酸与低碳数的一元脂肪酸具有相似的分布，表明它们可能具有相同的母源。对比研究表明JL 30抽提物中正构烷烃可能存在混源的影响，其碳同位素组成是多源混合的结果。