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1.
A constitutive relation is derived for describing the mechanical response of chalk. The approach is based on a phenomenological framework which employs chemo‐plasticity. The properties of the material are assumed to be affected by the physico‐chemical processes that occur through the interaction between the skeleton and the pore fluid. The underlying mechanism is discussed by invoking a micromechanical analysis. The performance of the framework is illustrated by examining the evolution of mechanical characteristics in the presence of different pore fluids. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
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The study of the chemical stability of vitreous material in aqueous media is well‐established. There has to date been little consideration of the implications of variations in the chemical durability of tephra in Quaternary tephrochronology. Chemical alteration can take the form of cationic leaching from the matrix, or complete destruction of the silica network, either of which could constrain the ability to chemically identify distal tephra. Here we apply established models of vitreous durability to the published chemical analyses of a large number of Icelandic tephras in order to predict their relative durabilities under equivalent conditions. This suggests that some important tephras have relatively poor chemical stability, and that rhyolitic tephras are, in general, more stable than basaltic. We conclude that tephras should be expected to show predictable differential chemical stability in the post‐depositional environment. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
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Olga Hadz̆ija Mladen Jurac̆ić Marija Luić Maja Tonković Biserka Jeric̆ević 《Estuarine, Coastal and Shelf Science》1985,21(5):701-709
The investigation of mineral, granulometric and chemical composition of sediments of the River Krka estuary (Yugoslavia) were performed in order to elucidate the origin of the sediments and the pattern of sedimentation. Estuarine surface sediments were found to be fine-grained with a bimodal distribution. Environmental conditions in estuarine sediments favour conservation of the organic matter (anoxic conditions). The carbohydrates in the sediments were investigated to determine whether they are of terrigenous or authigenous origin. Glucose, galactose, mannose, xylose, rhamnose, glucosamine and glucuronic acid were detected in the sediments. Their mutual relationship indicates a preferentially terrigenous source of sedimented organic material in estuarine sediments. 相似文献
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1 Introduction Soil is not only the major natural resource on which human being depends for the production of food, feed, fiber, renewable energy and raw materials, but also plays a key role in maintaining the complex terrestrial ecosystems and climate systems of this planet. Recent rapid increase in the human population is placing a great strain on the worlds soil resources. Only about 11% of the global land surface covered by the soils are being used to raise crops and livestock, in other … 相似文献
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1 INTRODUCTION Sitting in the central part of the Pearl River Delta, Guangzhou is one of the cities in China that are most polluted by acid rain. Broad attention has been brought to the problem. Since the early 1980s, a series of observation and studies h… 相似文献
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The chemical forms, spatial distribution and sources of As, Hg, Cd, Pb and Zn in sediments of the Miyun reservoir were studied. The results of sequential extraction demonstrate that most of As, Pb and Zn were bound to the residual fraction, Hg was associated with the sulfide fraction while Cd was associated with the carbonate fraction and the residual fraction. On the vertical profiles the concentrations of the heavy metals in total and each fractions mostly decreased with increasing depths in sediments, suggesting that the heavy metals input from the upstream watershed increases yearly. Summation of the residual fraction, the sulfide fraction and the carbonate fraction accounts for 60.03%―85.60% of the total heavy metal contents in the sediments, which represent the geochemical background values of the elements and relate closely to soil erosion. Results of the main factor analysis show that most sediments of the reservoir come from the upstream soil erosion, the point source pollution and domestic waste. Moreover, the microbial activities taking place on the sediment-water interface are also one of the major factors to cause the increasing content of the organic matter fraction and the iron-manganese oxide fraction. Environmental change of the reservoir water could make the removability of the heavy metals increase, leading to the increase of their concentrations in pore water in sediments, and imperiling water quality of the reservoir. 相似文献
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辽宁省大民屯凹陷流体化学场特征及油气成藏意义 总被引:5,自引:3,他引:5
从地层水化学场、油气组成的非均质性两方面对辽宁省大民屯凹陷前第三系古潜山和下第三系沙河街组的流体化学场特征进行了分析.结果表明,该区地层水运动规律与油气运移模式吻合较好,即流体以"垂向流动"为主,受断裂和沉积砂体的控制,由沉积中心的中、深部沿断裂垂向运移,而后在各断块内侧向运移至各断块的高部位,横向运移效应只在局部小范围内规律显著,构成了典型的离心状渗流体系.在地层水水头压力、浮力动力场控制下该区形成了自生自储、下生上储、新生古储型油藏. 相似文献
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近6 ka以来科尔沁沙地东部气候变化记录 总被引:1,自引:3,他引:1
根据科尔沁沙地东部TL剖面磁化率、有机质、化学元素等气候代用指标的变化特征和14C测年结果,分析和讨论了科尔沁沙地6 ka BP以来的气候变化过程。实验数据显示,高频磁化率、低频磁化率、有机质、Al2O3含量变化趋势基本一致,且峰值段对应古土壤层,谷值段对应风成砂层。依据气候代用指标的变化将6 ka BP以来科尔沁沙地气候变化分为3个阶段:Ⅰ.6.0~4.2 ka BP,气候暖湿,夏季风逐渐增强,并占主导,冬季风较弱,与全新世大暖期对应,但存在百年尺度的气候波动,其中:6.0~5.6 ka BP,5.6~5.4 ka BP,4.9~4.2 ka BP气候暖湿;5.6~5.5 ka BP,5.4~4.9 ka BP气候相对冷干。Ⅱ.4.2~1.3 ka BP,气候相对暖湿,与上一阶段相比夏季风有所减弱,但仍强于冬季风,其间也存在次一级波动,3.7~3.6 ka BP,3.4~1.3 ka BP,气候相对暖湿,4.2~3.7 ka BP,3.6~3.4 ka BP气候相对干冷。Ⅲ.1.3~0.65 ka BP以来,气候波动频繁,后期有向暖湿发展的趋势。总体而言,区域气候变化与全球具有较好的一致性。 相似文献