复杂地层钻进中可控复合浆液的研制

复杂地层钻进中常用的注浆材料需要良好的时间可控性和固结体强度,因此研制一种可控时间、增加固结体强度、效果良好的注浆浆液是有意义的。针对以上问题,利用正交试验的方法研制了一种复合注浆材料。在不饱和聚酯中添加水泥及引发剂、促进剂使浆液在要求时间内固化,最终配方的固化时间为62 min,抗压强度为32.6 MPa。该浆液作为化学浆液具有可注性好、浆液粘度低、能注入到细微裂隙中的优点,固结体强度高,并且塑性性能良好,由于在浆液中添加了水泥,降低了成本,较之一些化学浆液有一定的优势。     

Formation of ‘Beach Rock’ at Siesta Key, Florida and its influence on barrier island development

Seaward-dipping strata of carbonate-cemented shell debris located along the coast of Siesta Key on the Gulf Coast of the Florida peninsula have long been interpreted to be beachrock equivalent in age to the Pleistocene Anastasia Formation (Stage 5e) of the east coast of Florida. Detailed examination of thin sections along with radiometric dating and isotopic analyses demonstrates clearly that this is a Holocene deposit that is not beachrock but was lithified in a meteoric environment. Whole rock dates, dates from shells only, and from cement only demonstrate that these beach deposits were in place by at least 1800 yr BP and might have been there as long ago as 4300 yr BP. This means that some type of barrier island was in place at that time. Previous investigations have depicted Siesta Key as having a maximum age of 3000 yr with these deposits being located about 2 km landward of the beach deposits. This suggests that the beach deposits might have been the site of the original position of Siesta Key. These data also indicate that sea level must have been near its present position at the time that these foreshore beach deposits were deposited; sometime between 1800 and 4300 yr ago. This scenario indicates that sea level along this coastal reach probably reached its present level at least about 2000 yr ago.     

水泥加固不同地区软土的试验研究

对不同地区软土经水泥加固后的强度形成特征进行了研究。进行直接剪切试验及无侧限抗压试验测定了水泥加固土的力学指标,发现不同地区的软土经水泥加固后力学性质存在很大差异,从试样的粒度成分、有机质含量及加固后试样的微观结构特征等方面对此进行解释。结果表明,试样的粒度成分及有机质含量会对加固效果产生很大影响,黏粒含量越大,有机质含量越高,对水泥加固土强度的形成越不利。为在用水泥进行不同性质的软土加固处理时采取合理的附加措施提供了理论依据。     

Fe and Mn in calcites cementing red beds: A record of oxidation–reduction conditions: Examples from the Catalan Coastal Ranges (NE Spain)

Fe and Mn occur in calcite cements depending on the oxidizing–reducing conditions of cementing waters, which may change according to depositional and diagenetic environments. In red beds, Mn and Fe are available from the ferruginous matrix. Thus, it is possible to know the oxidizing–reducing conditions of fluids that precipitated calcite as a function of Mn and Fe content in calcite cement. A detailed petrological (with special attention to cathodoluminescence) and geochemical analysis of these cements is a useful tool to constrain the diagenetic evolution of red beds and the history of the basin where they deposited.     

Diagenesis impact on a deeply buried sandstone reservoir (Es1 Member) of the Shahejie Formation,Nanpu Sag,Bohai Bay Basin,East China

Diagenesis has a significant impact on reservoir quality in deeply buried formations. Sandstone units of the Shahejie Formation (Es₁ Member) of Nanpu Sag, Bohai Bay Basin, East China is a typical deeply buried sandstone with large hydrocarbon accumulations. The methodology includes core observations and thin section studies, using fluorescence, scanning electron microscope (SEM), cathodoluminescence (CL), fluid inclusion and isotope and electron probing analysis as well as the numerical determination of reservoir characteristics. The sandstones consist of medium to coarse-grained, slight to moderate sorted lithic arkose and feldspathic litharenite. Porosity and permeability values range from 0.5 to 30% and 0.006 to 7000 mD, respectively. The diagenetic history reveals mixed episodes of diagenesis and deep burial followed by uplift. The main diagenetic events include compaction, cementation alteration, dissolution of unstable minerals and grain fracturing. Compaction resulted in densification and significantly reduced the primary porosity. Quartz, calcite and clay are the dominant pore-occluding cement and occur as euhedral to subhedral crystals. Alteration and dissolution of volcanic lithic fragments and pressure solution of feldspar grains were the key sources of quartz cement whereas carbonate cement is derived from an external source. Clay minerals resulted from the alteration of feldspar and volcanic lithic fragments. Porosity and permeability data predict a good inverse relationship with cementation whereas leaching of metastable grains, dissolution of cement and in some places formation of pore-lining chlorite enhanced the reservoir quality. The best reservoir is thicker sandstone bodies that are medium to coarse-grained, well-sorted sandstone with low primary ductile grains with a minor amount of calcite cement. The present study shows several diagenetic stages in the Es₁ Member, but the overall reservoir quality is preserved.     

养护温度对水泥固化淤泥强度影响试验研究

采用水泥固化海泥（CSMC）作为围海垦地填料正在被广泛关注。由于水化放热,当环境温度较高时大体积填筑的CSMC内部实际养护温度可能明显高于室内标准养护温度（≈ 20 ℃）,这必然会对CSMC的强度发展产生影响,但目前工程实践中并未考虑这一温度差异的影响。因此,基于室内试验,测试了不同配合比CSMC试样在不同养护温度下的强度发展过程,并重点探讨了养护温度对CSMC强度发展的影响规律及其内在机制。结果表明：养护温度对CSMC强度发展影响显著,高的养护温度不仅会显著提高CSMC的早期强度,而且会比较明显地提高CSMC的晚期强度,这就意味着在CSMC垦地工程实践中考虑养护温度的影响是十分必要的。鉴于此,文中最后给出了如何在CSMC垦地工程实践中考虑养护温度对强度发展影响的建议和设计流程。     

纤维水泥土力学性能的试验研究

为了解加入纤维对水泥土力学性能的影响,对素水泥土及纤维水泥土进行了无侧限抗压和疲劳试验。研究结果表明,添加纤维可小幅度提高水泥土的抗压强度;与素水泥土相比,纤维水泥土在达到应力峰值时的应变明显增大,破坏后的残余强度也有所提高;纤维的加入提高了水泥土的延性,减少了裂缝的开展,改善了其力学性能;添加纤维后水泥土抵抗疲劳的能力明显增强;掺入纤维对水泥土抗疲劳能力的提高程度远大于其对水泥土无侧限强度的提高程度;水泥土的应力水平和疲劳寿命之间具有单对数线性关系;在循环荷载作用下水泥土表现为低应力性破裂特征。     

四川盆地震旦系灯影组葡萄状白云岩成因

四川盆地震旦系灯影组发育巨厚的白云岩,其中灯影组二段和四段发育大量具有各种形态的葡萄状白云岩,其直径最长可达75cm,有的平行于层面,有的穿层。剖面资料表明,葡萄状白云岩发育多期等厚环边胶结物,中部残留大量未充填的不规则洞穴,这成为与岩溶喀斯特作用相关的地下溶蚀作用的证据。围岩泥晶白云石为早期海水中原生结晶的产物,后来的胶结物可划分为4期: (1)自泥晶化白云石(部分样品中可见)作为最早的一期胶结物,由于各种生物化学作用和生物作用的影响而紧贴着围岩发育;(2)第2期胶结物纤维状白云石可能为海水中直接沉淀的产物,经历后期成岩作用后,具有完全有序的结构,晶胞参数接近理想值;(3)细—中晶白云石为第3期胶结物,包含纤维状白云石溶蚀残余,形成于构造抬升之后的近地表大气淡水环境;(4)第4期胶结物中—粗晶白云石为埋藏环境下直接结晶的产物,充填了孔洞中心,残留部分未充填孔洞。灯影组受到了岩溶喀斯特作用、胶结作用以及白云石化作用等成岩作用的影响,其中与葡萄状白云岩有关的岩溶喀斯特作用对于灯影组储集层的发育至关重要。对灯影组葡萄状白云岩的研究,不仅有助于深入探讨灯影组储集层成因和演化及灯影组白云岩的成因,而且有助于指导四川盆地前寒武系油气勘探。     

The diagenetic history of Oligocene-Miocene sandstones of the Austrian north Alpine foreland basin

Diagenesis is an essential tool to reconstruct the development of reservoir rocks. Diagenetic processes - precipitation and dissolution - have an influence on pore space. The present paper aims to study the diagenetic history of deep-marine sandstones of the Austrian Alpine Foreland Basin. To reach that goal, sediment petrology and diagenetic features of more than 110 sandstone samples from water- and gas-bearing sections from gas fields within the Oligocene-Miocene Puchkirchen Group and Hall Formation has been investigated. Special emphasis was put on samples in the vicinity of the gas-water contact (GWC). The sediment petrography of sandstones of Puchkirchen Group and Hall Formation is similar; hence their diagenesis proceeded the same way. In fact, primary mineralogy was controlled by paleo-geography with increasing transport distance and diverse detrital input.Sediment petrographically, investigated sandstones from the water-bearing horizon seemed quite comparable to the gas-bearing sediments. In general, they can be classified as feldspatic litharenites to litharenites and display porosities of up to 30% and permeabilities of up to 1300 mD. The carbon and oxygen isotopic composition of bulk carbonate cements from these sandstones range from−3.8 to +2.2 and from −7.5 to +0.2‰ [VPDB]. However, near the Gas-Water Contact (GWC) a horizon with low porosities (<3%) and permeabilities (<0.1 mD) is present. This zone is completely cemented with calcite, which has a blocky/homogenous morphology. A slight, but significant negative shift in δ18O isotopy (−2.5‰) is evident.During early diagenesis the first carbonate generations formed. First a fibrous calcite and afterwards a micritic calcite precipitated. Further siliciclastic minerals, such as quartz and feldspar (K-feldspar and minor plagioclase), exhibit corroded grains. Occasionally, clay minerals (illite; smectite, chlorite) formed as rims around detrital grains. Late diagenesis is indicated by the formation of a low permeable zone at the GWC.     

京珠高速许漯段路基干拌水泥碎石桩加固研究

干拌水泥碎石桩是一项施工快速、不开挖路基的新型加固技术。针对京珠高速公路许漯段出现大量路基病害,采用此桩型进行加固处理。试验桩长为5.0 m,成孔直径为150 mm,间距为1.0 m×1.0 m,每层虚填料为25 cm,夯距为1.0 m,用120 kg重锤,分别对每层夯实10、8、7击的3根桩进行载荷试验,然后对每层夯实8、7击的2根桩进行重Ⅱ型动力触探试验。根据试验结果对比分析每层夯7击,单桩极限承载力达400 kPa,效果最优。通过地质雷达测试和室内土工试验对比分析加固前后路基土体变化,加固后路基不均匀变形减小,土体有效重度增加,含水率有所减少,桩体的吸水排水效果明显,桩的夯实挤密作用良好,路基的承载力和变形性能得到改善。经过桩加固后1年运行观测,加固后路段没有再次出现翻浆、叽泥等病害,表明此桩型加固高速公路路基效果显著。