新型抗水氯氧镁水泥防渗渠在自然环境的水化产物、相转变规律及其对强度的影响

氯氧镁水泥(Magnesium oxychloride cement, MOC)具有快凝、早强、高强、防火和不腐蚀玻璃纤维等优点,非常适合于制作玻璃纤维增强薄壁制品,在农业灌溉工程中具有良好的应用前景。采用XRD和TOPAS分析了新型抗水氯氧镁水泥制成内蒙古防渗渠的物相组成,探讨了氯氧镁水泥制品在自然环境的水化产物与相转变规律、以及相组成对强度的影响。结果表明,在水分缺少的条件下,氯氧镁水泥的水化产物主要为5Mg(OH)_2·MgCl_2·8H_2O(5·1·8)和Mg(OH)_2;在水分充足的条件下,水化产物主要为Mg(OH)_2和5·1·8,碳化产物为碳化氯氧化镁Mg(OH)_2·MgCl_2·2MgCO_3·6H_2O(1·1·2·6)和水菱镁矿4MgCO_3·Mg(OH)_2·4H_2O(4·1·4)。水化产物对强度有促进作用,而碳化产物会降低强度。通过10年的工程环境考验,证明新型氯氧镁水泥制品在环境中能够保持主要强度相5·1·8的稳定性,具有良好的长期力学性能。     

水泥固化锌污染土电阻率与强度特性研究

以标准砂及普通硅酸盐水泥为试验材料,制作水泥固化锌污染土样,进行了一系列电阻率和无侧限抗压强度试验。研究了交流电频率对水泥固化锌污染土电阻率的影响、不同含量锌离子对水泥缓凝作用的影响、锌离子含量和龄期分别对水泥土电阻率和强度的影响、电阻率与无侧限抗压强度的关系。结果表明：电阻率随电流频率的增加而明显降低,尤其当频率低于50 kHz时为甚;不同含量的锌离子对水泥土的缓凝作用影响明显,随着锌离子含量的增大,水泥土强度的充分发挥所需时间逐渐增长,但在锌离子含量为500 mg/kg时,缓凝作用表现异常;电阻率和强度均随龄期的增加而增长,随锌离子的含量的增加上下波动,电阻率在锌离子含量为50 mg/kg和500 mg/kg时出现极值,强度在锌离子含量为100 mg/kg和500 mg/kg时出现极值;在各个龄期下,电阻率与强度均呈现出很好的线性关系。     

Diagenetic fluid evolution and water-rock interaction model of carbonate cements in sandstone: An example from the reservoir sandstone of the Fourth Member of the Xujiahe Formation of the Xiaoquan-Fenggu area,Sichuan Province,China

Carbonate cement is the most abundant cement type in the Fourth Member of the Xujiahe Formation in the Xiaoquan-Fenggu area of the West Sichuan Depression. Here we use a systematic analysis of carbonate cement petrology, mineralogy, carbon and oxygen isotope ratios and enclosure homogenization temperatures to study the precipitation mechanism, pore fluid evolution, and distribution of different types of carbonate cement in reservoir sand in the study area. Crystalline calcite has relatively heavy carbon and oxygen isotope ratios(δ13C = 2.14‰, δ18O = -5.77‰), and was precipitated early. It was precipitated directly from supersaturated alkaline fluid under normal temperature and pressure conditions. At the time of precipitation, the fluid oxygen isotope ratio was very light, mainly showing the characteristics of a mixed meteoric water-seawater fluid(δ18O = -3‰), which shows that the fluid during precipitation was influenced by both meteoric water and seawater. The calcite cement that fills in the secondary pores has relatively lighter carbon and oxygen isotope ratios(δ13C = -2.36‰, δ18O = -15.68‰). This cement was precipitated late, mainly during the Middle and Late Jurassic. An important material source for this carbonate cement was the feldspar corrosion process that involved organic matter. The Ca2+, Fe3+ and Mg2+ ions released by the clay mineral transformation process were also important source materials. Because of water-rock interactions during the burial process, the oxygen isotope ratio of the fluid significantly increased during precipitation, by about 3‰. The dolomite cements in calcarenaceous sandstone that was precipitated during the Middle Jurassic have heavier carbon and oxygen isotope ratios, which are similar to those of carbonate debris in the sandstone(δ13C = 1.93‰, δ18O = -6.11‰), demonstrating that the two are from the same source that had a heavier oxygen isotope ratio(δ18O of about 2.2‰). The differences in fluid oxygen isotope ratios during cement precipitation reflect the influences of different water-rock interaction systems or different water-rock interaction strengths. This is the main reason why the sandstone containing many rigid particles(lithic quartz sandstone) has a relatively negative carbon isotope ratio and why the precipitation fluid in calcarenaceous sandstone has a relatively heavier oxygen isotope ratio.     

Stabilization of Expansive Clays Using Granulated Blast Furnace Slag (GBFS) and GBFS-Cement

Expansive clays undergo swelling when subjected to water. This can cause damage, especially to light weight structures, water conveyance canals, lined reservoirs, highways, and airport runways unless appropriate measures are taken. In this study, granulated blast furnace slag (GBFS) and GBFS-cement (GBFSC) were utilized to overcome or to limit the expansion of an artificially prepared expansive soil sample (sample A). GBFS and GBFSC were added to sample A in proportions of 5–25% by weight. The effects of these stabilizers on grain size distribution, Atterberg limits, swelling percentage and rate of swell of soil samples were determined. GBFS and GBFSC were shown to successfully decreasing the total amount of swell while increasing the rate of swell.     

Cement Deep Soil Mixing (CDSM) for Solidification of Soft Estuarine Sediments

A preliminary study was conducted to determine the potential for cement deep soil mixing (CDSM) technology as a method for in-situ solidification of contaminated river and estuarine sediments. The study was conducted in Newark Bay, near the mouth of the Passaic River, New Jersey. The primary objective of the study was to evaluate the viability of CDSM for the in-situ S/S with a focus on: 1) determining the correct mix of the cement slurry, which provides rapid stabilization of the sediment matrix, 2) potential resuspension of solids during CSDM operations, 3) the effects of high organic content on the solidification process, and 4) the feasibility of using conventional dredging/extraction methods once the sediments have been stabilized and allowed to cure. The results of the study show CDSM slurry mixtures, as low as 7% in cement content, result in significant solidification and strength gain of in-situ sediments under ambient conditions. In sediments with very high organic contents (> 20%), the slurry mix would need to be adjusted to account for retardation effects of organics on cement hydration. Sediment resuspension during application was shown to be minimal at a distance of as little as 75 feet from the mixing head. Strength gains were considerable, effectively consolidating the sediment particles in a secure matrix, but not so high as to preclude extraction of solidified sediments with conventional dredging equipment. Dredged solidified sediment exhibited characteristics of a stiff glacial clay, and as such was easier to handle and transport than untreated dredged sediments. This technique has high potential to be used as an interim remedial measure prior to either extraction and decontamination/disposal or proper capping.     

实施低碳水泥标准的影响及协同减排效果分析

采用MAP-CGE模型,模拟了我国水泥行业实施低碳水泥标准对不同生产工艺产出、能耗及污染排放的影响,测算了对其边际减排成本和均衡价格的影响,分析了对不同污染物的协同减排效果。模拟结果表明：实施低碳水泥标准有利于水泥生产工艺的升级换代,并有助于水泥行业节能减排;在现有技术水平下,水泥行业在减排1 t CO2的同时将带来约1.17 kg的SO2减排量和4.44 kg的NOx减排量;实施低碳水泥标准对于水泥行业控制NOx排放很有利;但水泥行业也需承担减排成本并导致其均衡价格的小幅上升。     

具有可靠抗震性能的农居房屋设计

从减少地震波吸收的角度考虑建筑物的安全性,对提升普通农居房屋的抗震性能提出一种新的设计思路。具体做法:一是设计并应用了新的建筑构件承载结构棒和新结构砌块砖;二是将框架结构技术有效应用到普通房屋的建造中,使普通农居房屋具有了框架结构的稳固作用效果;三是对墙体砖块采用捆绑加固手段,并将房屋的墙体结构和屋顶结构实现整体式连接;四是对地基结构进行改进,采用了减震和隔震手段。通过上述做法既加强了墙体强度,消除了应力集中的可能性,同时通过减轻屋顶重量达到降低、缓解地震作用力的目的。     

循环荷载下人工结构性土变形与强度特性试验研究

针对长期动载作用下天然沉积结构性黏土地基强度和刚度循环软化问题,分别以水泥和食糖为模拟粒间胶结和大孔隙的材料,制备了不同胶结强度和初始孔隙比的人工结构性土,开展了人工结构性土与相应重塑土的动三轴试验,分析了土体胶结强度、初始孔隙比、围压和动应力幅值对累积变形和动强度的影响规律。试验结果表明：累积应变-振动次数曲线以临界循环应力为界分为：塑性安定型、临界型和破坏型;临界循环应力随胶结强度增大、初始孔隙比减小而增大;土体胶结强度越高,脆性破坏越明显,累积应变曲线转折点对应的应变越小。动强度的应变破坏标准采用转折点应变值更符合土性变化规律;动强度随胶结强度增大、初始孔隙比减小而增大;动黏聚力cd随破坏振次增大而降低,而动内摩擦角?d基本不变。试验结果可为软弱土地基动力灾变控制提供有益参考。     

便携式钻机在水泥灰岩矿勘查中的应用

便携式钻机已广泛应用于地质与工程勘查中,为了进一步扩大便携式钻机的应用范围,倡导绿色勘查,在湖南省东安县王师岭矿区水泥灰岩矿勘查中,采用ZY-25型便携式钻机以钻代槽进行地表取样,取得了较好的效果。应用实践表明,当矿区构造简单,岩层产状较平缓且稳定,矿体厚度较大,矿石有用组分含量较高且分布均匀,有害组分含量较低时,采用便携式钻机取样代替槽探取样评价矿床是可行的。     

纤维水泥土力学性能的试验研究

为了解加入纤维对水泥土力学性能的影响,对素水泥土及纤维水泥土进行了无侧限抗压和疲劳试验。研究结果表明,添加纤维可小幅度提高水泥土的抗压强度;与素水泥土相比,纤维水泥土在达到应力峰值时的应变明显增大,破坏后的残余强度也有所提高;纤维的加入提高了水泥土的延性,减少了裂缝的开展,改善了其力学性能;添加纤维后水泥土抵抗疲劳的能力明显增强;掺入纤维对水泥土抗疲劳能力的提高程度远大于其对水泥土无侧限强度的提高程度;水泥土的应力水平和疲劳寿命之间具有单对数线性关系;在循环荷载作用下水泥土表现为低应力性破裂特征。