基于工程地质条件约束的水泥土搅拌桩强度设计

无置换情况下高饱和度软土容纳水泥浆的掺入量是有限的,以孔隙比、饱和度、气相体积为约束条件,可计算出桩体的最大水泥掺入比。在置换地基土才能使水泥掺入量满足设计要求的情况下,上返水泥土的存在改变了水泥掺入量的分配,桩体实际水泥掺入比随水泥土上返量大小及固相中水泥所占比例而改变。本文依据地基土性状,结合比重、密度、含水量等测试参数,以水泥上返量为线索推导出了桩体实际水泥掺入比公式。并通过工程实例对比分析了水泥土强度设计中考虑地质条件约束的实际意义。     

高温下合成包裹体中流体水分子氢键的拉曼光谱分析

在合成包裹体腔中，用显微激光拉曼探针原位分析了高温下纯水和含气体CO2的流体中水分子的氢键作用。研究结果表明，随着温度升高，流体中水分子的氢键作用不断减弱，但纯水在最高的测量温度400℃，含CO2的流体在520℃都还存在着比较强的氢键作用。含CO2的流体比相同温度下纯水的氢键作用弱，并且当气相与液相混溶成为纯液相后，它的氢键与温度的关系明显出现了转折，温度对氢键的影响比均一前小。     

CFG复合地基桩材特性的试验分析

通过对CFG复合地基桩体材料的室内配比试验，获得了不同配比情况下桩体材料强度的变化规律，提出了CFG桩桩体材料配比时应遵循的某些原则和方法。     

文昌A凹陷珠海组砂岩碳酸盐胶结物发育特征及其对储层质量的影响

碳酸盐胶结物是一类砂岩储层中最常见的成岩胶结交代物.厘清碳酸盐胶结物的发育特征、期次及其含量,可定量分析碳酸盐胶结物对储层质量的影响程度.以文昌A凹陷珠海组海陆过渡相砂岩储层的碳酸盐胶结作用为研究重点,分凹陷中心与近珠三南断裂两个主体区域,利用岩石学分析、铸体薄片显微镜下鉴定、阴极发光分析、同位素分析等技术手段,明确了...     

高压旋喷水泥浆护壁技术的研究与应用

针对深孔复杂夹层（断层）和溶洞地层钻进的护壁困难,常规护壁方法无法解决的问题,提出并研究试验成功了高压旋喷水泥浆护壁技术,经多个矿区、钻孔的实践证明,高压旋喷水泥浆护壁法可以在任意孔深的坍塌超径孔段、软弱松散地层等形成可靠、有效的“水泥套管”护壁。系统介绍了该项技术的工艺原理、技术要点及其推广应用情况。     

贵州紫云上石炭统叶状藻礁灰岩胶结物特征

贵州紫云县猴场镇扁平村的上石炭统叶状藻礁及其周边灰岩中广泛发育大量的各类胶结物。通过对胶结物的形态、结构和阴极发光特征以及胶结物间的接触关系的研究,可以确定成岩作用的先后并识别成岩环境。浅海海底同生成岩阶段大的孔隙中形成等厚环边针状胶结物、葡萄状胶结物,小的孔隙里形成微晶胶结物。早成岩阶段形成微亮晶和斑块状亮晶方解石胶结物和放射纤维扇状胶结物,表生成岩阶段的溶蚀作用和胶结作用强烈,胶结物类型有斑块状或等粒的方解石胶结物和等厚环壁柱状胶结物,等厚环壁柱状胶结物在所有胶结物中体积是较大的。早期胶结作用使叶状藻礁灰岩孔隙度大为降低。中、晚成岩阶段,孔隙被等厚环壁刃状胶结物和晶簇或斑块状亮晶方解石所充填,有些先成的胶结物被热液改造。后生作用阶段发生的主要是构造破裂作用,其中少数裂隙被红褐色含Fe2O3微晶层和晶体粉砂及渗流豆粒充填。叶状藻礁灰岩的孔隙在晚成岩阶段前或中被胶结而之后没有创造出大且连通的孔隙,是它没能成为油气储集层的原因之一。     

用阜新煤矸石制备阿利特一硫铝酸盐水泥的试验研究

我国大量堆存和正在排放的煤矸石，既是一种矿业排量最大的废弃物，又可以被认为是一种可利用的巨型资源。阜新煤矸石主要由石英、长石、伊利石等矿物组成，化学成分含60％～67％SiO2，13％～18％Al2O3，具有高硅低铝特征，属于目前难以利用煤矸石。本文实验采用了C3S—C4A3S—C2S—C4AF体系，利用煤矸石的Al2O3煅烧成无水硫铝酸钙而不是铝酸三钙。添加BaSO4、CaF2和铬渣，使硅酸三钙和无水硫铝酸钙能在1300-1360℃共生，制备出了阿利特-硫铝酸盐水泥。水泥熟料在1360℃，保温1小时烧成。研制的煤矸石水泥3天和28天抗压强度分别达到了34．7～36．8MPa和52．2～54．4MPa，达到了525#早强型高性能水泥指标。     

Hydrothermally induced diagenesis: Evidence from shallow marine-deltaic sediments,Wilhelmøya,Svalbard

Sedimentary basins containing igneous intrusions within sedimentary reservoir units represent an important risk in petroleum exploration. The Upper Triassic to Lower Jurassic sediments at Wilhelm?ya(Svalbard) contains reservoir heterogeneity as a result of sill emplacement and represent a unique case study to better understand the effect of magmatic intrusions on the general burial diagenesis of siliciclastic sediments. Sills develop contact metamorphic aureoles by conduction as presented in many earlier studies. However, there is significant impact of localized hydrothermal circulation systems affecting reservoir sediments at considerable distance from the sill intrusions. Dolerite sill intrusions in the studied area are of limited vertical extent(～12 m thick), but created localized hydrothermal convection cells affecting sediments at considerable distance(more than five times the thickness of the sill)from the intrusions. We present evidence that the sedimentary sequence can be divided into two units:(1) the bulk poorly lithified sediment with a maximum burial temperature much lower than 60-70 ℃,and(2) thinner intervals outside the contact zone that have experienced hydrothermal temperatures(around 140 ℃). The main diagenetic alteration associated with normal burial diagenesis is minor mechanical plastic deformation of ductile grains such as mica. Mineral grain contacts show no evidence of pressure dissolution and the vitrinite reflectance suggests a maximum temperature of ～40 ℃. Contrary to this, part of the sediment, preferentially along calcite cemented flow baffles, show evidence of hydrothermal alteration. These hydrothermally altered sediment sections are characterized by recrystallized carbonate cemented intervals. Further, the hydrothermal solutions have resulted in localized sericitization(illitization) of feldspars, albitization of both K-feldspar and plagioclase and the formation of fibrous illite nucleated on kaolinite. These observations suggest hydrothermal alteration at T 120-140 ℃ at distances considerably further away than expected from sill heat dissipation by conduction only, which commonly affect sediments about twice the thickness of the sill intrusion. We propose that carbonate-cemented sections acted as flow baffles already during the hydrothermal fluid mobility and controlled the migration pathways of the buoyant hot fluids. Significant hydrothermally induced diagenetic alterations affecting the porosity and hence reservoir quality was not noted in the noncarbonate-cemented reservoir intervals.     

考虑黏度时变性的水泥浆液盾构壁后注浆扩散规律及管片压力模型的试验研究

对水泥浆液黏度时变性进行了试验研究,证实了工程常用水灰比范围内水泥浆液服从宾汉姆流体特性;不同水灰比浆液黏度均随注浆时间增大而大幅度增加。根据试验结果,考虑注浆过程中水泥浆液黏度随时间的变化,对盾构壁后注浆水泥浆液的扩散规律及因注浆而造成的管片压力进行了推导及分析。计算表明：相同注浆时间条件下,水泥浆液扩散半径及注浆对管片产生的压力值均随注浆压力的增大而增大。考虑浆液黏度时变性后,扩散半径、注浆对管片压力值等均较不考虑浆液时变性时减小,且随注浆压力的增大,浆液黏度变化对管片压力值的影响更加明显。相同注浆压力条件下,浆液扩散半径及对管片产生的压力值均随注浆时间的增长而增加,但注浆前期增长速度较快,而后逐渐减缓。研究成果对于盾构壁后注浆工艺选择及参数设计具有较大的指导意义。     

外掺Cl对磷酸镁水泥离子溶出和孔结构的影响

通过测试不同Cl-(NaCl)掺量磷酸镁水泥(MPC)浸取液中离子浓度及MPC硬化体的孔结构和吸水率,研究了Cl-掺量和浸取时间对MPC硬化体平均孔径、孔隙率、孔径分布、孔体积分布、吸水率、MPC浸取液中Cl-、Na+、OH-、Mg2+、PO43-和K+浓度的影响,结果表明外掺Cl-对MPC孔结构、离子溶出及吸水率有显...