红层泥质胶结物干缩裂缝深度与间距预测模型

红层泥质胶结物在干燥条件下会因含水率变化产生开裂,裂缝进一步发展贯通最终导致红层泥岩崩解破坏。目前对红层泥岩崩解机制的研究多为定性描述,缺乏定量分析方法。因此,定量研究红层泥质胶结物开裂的产生及扩展对深化红层泥岩崩解理论研究具有重要意义。基于线弹性断裂力学及非饱和土力学,建立了考虑含水率变化的红层泥质胶结物裂缝深度及间距计算公式,并对公式参数敏感性进行了分析。应用CT试验数据对PFC2D数值模型进行了校准,并基于干缩开裂数值试验结果,对裂缝深度及间距计算公式进行了对比验证。结果表明：提出的计算公式能较好地预测红层泥质胶结物的开裂深度及间距,裂缝深度随含水率减小呈先快速增加再缓慢增长的特点。研究成果有助于加深对红层泥岩崩解的量化理论分析,并为预测工程中红层泥岩的开裂程度提供参考。     

水泥偏高岭土复合稳定粉砂土渗透特性试验研究

水泥稳定粉砂土抗渗性能受粉砂土自身渗透性能、水泥用量、水灰比等因素影响显著,如何在提升其抗渗性能的同时降低水泥用量是提升工程经济效益的关键。通过开展不同水泥偏高岭土掺比、初始用水量、水泥偏高岭土总掺量以及养护龄期条件下的室内渗透试验,研究了上述因素对水泥偏高岭土复合稳定粉砂土抗渗性能的影响规律,探讨了上述因素及无侧限抗压强度与渗透系数之间的经验关系。结果表明：水泥与偏高岭土掺比为5:1时,水泥偏高岭土复合稳定粉砂土抗渗性能最佳,且该掺比不随水泥偏高岭土总掺量的改变而变化;水泥偏高岭土复合稳定粉砂土渗透系数随初始用水量增加呈非线性递增,随水泥偏高岭土总掺量增加和养护龄期发展呈先快后慢降低;基于试验结果归纳提出了4个关于初始用水量、水泥偏高岭土总掺量、养护龄期和无侧限抗压强度的水泥偏高岭土复合稳定粉砂土渗透系数经验模型。研究成果可为水泥稳定粉砂土抗渗性能提升提供理论参考与借鉴。     

粉细砂地层防渗帷幕综合施工方法

四川省武都水库右岸EL574 m灌浆平洞揭露出厚度2.3～9.8 m的粉细砂层,普通水泥高压灌浆无法形成可靠的防渗帷幕。采用高压旋喷、湿磨细水泥、化学灌浆的组合处理方式,取得了较好的施工效果。通过钻孔压水、大功率声波CT、单孔声波、钻孔全景数字成像等方法检测,表明达到了设计防渗要求。     

Statistical approach to determine the salinized ground water flow path and hydrogeochemical features around the underground LPG cavern,Korea

The ground water flow path of the coastal area in the Yellow Sea, Korea, was interpreted using both the cross‐correlation analysis of hydraulic properties and the principal component analysis (PCA) of ground water chemistry. Data was obtained from observation wells in the underground liquefied petroleum gas (LPG) cavern constructed in the coastal area of Pyeongtaek. Cross‐correlation results showed that the operating pressure became more influenced on artificial factors for the variation of the groundwater level of the study area (45–66% of correlation coefficient) even though its affecting area was limited to the region with fractures or faults, and also showed that the delay time from the variation of operating pressure to the fluctuation of ground water level were relatively long periods (28–31 days). Three hydrogeochemical events (encrusted cement dissolution, host rock dissolution, and seawater intrusion), which were dominantly influenced on ground water quality, could be induced from the result of PCA. Quantitative evaluation for these events using the mixed equation with principal component scores suggest that the dissolution of encrusted cement materials was the predominant factor (39·0% of the total mixed proportion) to change the chemical composition of the seepage water during the ground water flow from the observation wells to the cavern. Integration of the statistical results also imply that ground water flow and hydrogeochemistry were predominantly affected by artificial factors such as cavern operation pressure and dissolution of encrusted cement materials, which were interdependent factors on the observation wells with high cross‐correlation coefficients and pH. Copyright © 2007 John Wiley & Sons, Ltd.     

新和地1井复杂地层水泥封孔护壁造斜技术

新和地1井在钻进1314.00～1419.98 m孔段时钻遇巨厚破碎带,地层高度破碎、大倾角、富含水系,孔壁掉块、水敏坍塌现象严重。钻进时孔内阻力大,钻具放不到底,孔内事故多发,破碎带难以钻穿。为处理孔内事故并钻穿巨厚破碎带,采用水泥封孔护壁造斜技术。受孔内复杂因素影响,特别是1358.76～1396.46 m破碎带内水系对水泥浆的稀释和冲蚀破坏作用,前期多次水泥封孔失败,浪费了大量物资及工期。现场通过试验,总结出了一套有针对性的、实用的技术方案,解决了现场的水泥封孔技术难题,提高了水泥封孔护壁造斜的成功率。新和地1井深孔复杂地层水泥封孔护壁造斜技术对今后施工类似工程具有一定的参考意义。     

膨胀土干缩变形特性试验研究

膨胀土是一种典型的问题性土,对气候变化非常敏感,在干旱气候条件下,极易发生体积收缩变形,引发各种工 程地质问题。为了研究膨胀土的干缩变形特性,开展了一系列室内干燥试验,测定了膨胀土的收缩特征曲线,重点分析 了初始含水率和干密度对干缩变形过程的影响,并进一步探讨了水泥固化抑制膨胀土干缩变形的效果和机理。结果表 明：（1） 膨胀土的干缩变形过程存在三个典型阶段：正常收缩、残余收缩和零收缩;（2） 初始含水率越高,试样蒸发速 率越快,且干缩变形完全后试样孔隙比越小而最终收缩应变越大,干缩变形越明显;（3） 初始干密度越大,试样蒸发速 率和最终体积收缩应变越小,提高初始干密度对试样干缩变形具有一定的抑制作用;（4） 在膨胀土中掺入适量的水泥能 显著降低试样的体积收缩应变,对干缩变形具有良好的抑制效果;（5） 膨胀土的干缩变形具有明显的各向异性特征,并 且与初始状态有关。     

水泥—水玻璃在房屋增层地基加固工程中的应用

当前加层房屋日益增多,其地基加固处理的方法很多。在确定加固方法之前,需对旧楼地基基础及结构进行验算,包括桩端持力层的强度,桩的容许承载力,桩基础沉降等。水泥-水玻璃双液化学灌浆法首次用于房屋增层地基加固,该方法具有可灌性高(K=10-6cm/s)、凝胶时间快(15~120 s)、强度较高(5~20 MPa)等诸多材料特性,可满足新增的上部结构荷载对地基的新要求。文章还介绍了一个工程实例      

Intercalation of kaolinite with acetamide

Upon intercalation of both ordered (low defect) and disordered (high defect) kaolinites with acetamide, two types of interaction are observed. Firstly, hydrogen bonding between the NH₂ groups of the acetamide with the siloxane oxygens is formed, as evidenced by the formation of two new bands at 3400 and 3509 cm^–1. Secondly, the appearance of additional bands at ∼3600 cm^–1 in both the infrared and Raman spectra of the acetamide intercalates is attributed to a second type of hydrogen bonding by the interaction of the C=O group and the inner surface hydroxyls. Changes in the intensity of the hydroxyl deformation modes in the 895 to 940 cm^–1 region are attributed to the changes in the hydrogen bonding of the kaolinite surfaces. It is proposed that the hydrogen bonding between the adjacent kaolinite layers is replaced with hydrogen bonding between both kaolinite surfaces and the acetamide molecule. Changes in the molecular structure of acetamide are observed upon intercalation. The amide 1 band is lost and replaced with a well-defined NH₂ deformation vibration. The loss of the amide 1 band is attributed the hydrogen bond formation between the amide hydrogens and the siloxane surface. The bands of the C=O group at 1680 and 1740 cm^–1 become a single band at 1680 cm^–1. The amide 2 band remains unchanged. The lack of intensity of the 1740 cm^–1 band is attributed to the formation of hydrogen bonding between the inner surface hydroxyl groups and the carbonyl group. Received: 4 February 1998/ Revised, accepted: 30 June 1998     

CHANNEL EROSION DAMAGES AND PROTECTION MEASURES IN SOUTHEAST ARIZONA

1INTRODUCTIONThesouthwesternregionoftheUnitedStates,includingSoutheastArizona,ischaracterizedbyasemiaridclimatewithhotsummers,mildwinters,andephemeralstreamsdrainingsparselyvegetatedareas.ChannelmorphologyoftheephemeralstreamsinSoutheastArizonaisinfluencedbybothlateralandverticalchannelchangesoccurringduringmajorfloods.Lateralchannelchangesoccurinthreewaysbankerosion,meandermigration,andchannelavulsion.Verticalchannelchangesinclude,beddegradationoraggradation,andmayoccurseparatelyorinco…     

新型抗水氯氧镁水泥防渗渠在自然环境的水化产物、相转变规律及其对强度的影响

氯氧镁水泥(Magnesium oxychloride cement, MOC)具有快凝、早强、高强、防火和不腐蚀玻璃纤维等优点,非常适合于制作玻璃纤维增强薄壁制品,在农业灌溉工程中具有良好的应用前景。采用XRD和TOPAS分析了新型抗水氯氧镁水泥制成内蒙古防渗渠的物相组成,探讨了氯氧镁水泥制品在自然环境的水化产物与相转变规律、以及相组成对强度的影响。结果表明,在水分缺少的条件下,氯氧镁水泥的水化产物主要为5Mg(OH)_2·MgCl_2·8H_2O(5·1·8)和Mg(OH)_2;在水分充足的条件下,水化产物主要为Mg(OH)_2和5·1·8,碳化产物为碳化氯氧化镁Mg(OH)_2·MgCl_2·2MgCO_3·6H_2O(1·1·2·6)和水菱镁矿4MgCO_3·Mg(OH)_2·4H_2O(4·1·4)。水化产物对强度有促进作用,而碳化产物会降低强度。通过10年的工程环境考验,证明新型氯氧镁水泥制品在环境中能够保持主要强度相5·1·8的稳定性,具有良好的长期力学性能。