胶州湾沉积物重金属形态不同浸取方法的比较与污染讯息指示作用初探

海洋沉积物中重金属的活性形态对于指示沉积物污染状况具有重要作用;为探寻简洁且能够有效提取重金属活性形态的浸提方法;实验研究了0.1 mol/L和1 mol/L盐酸的单级提取和欧共体标准局（European Community Bureau of Reference）提出的BCR分级提取法对胶州湾表层沉积物中重金属（Cr、Cu、Ni、Pb、Zn）和Al、Fe、Mn的浸取效果。结果显示;3种提取方法提取的金属含量呈显著正相关关系;两种浓度的稀盐酸对BCR方法中的酸可提取态和可还原态金属均具有较好浸提效果;但对可氧化态金属浸提能力相对较弱。不同提取方法的人为信号指数（ASI）计算结果表明;BCR浸取法提取结果的金属ASI值最大;表明其对沉积物中金属活性形态提取效率较高;1 mol/L HCl提取结果的金属ASI值最低;可能是较高浓度强酸使沉积物较大颗粒内层中“惰性”金属被浸取出来;“增加”了金属活性组分的污染讯息信号;对沉积物中Cu、Pb和Zn而言;0.1 mol/L HCl提取结果的ASI值与BCR方法接近。经过Al归一化后;0.1 mol/L HCl浸提的重金属含量的空间分布与胶州湾的实际污染状况相吻合;表明0.1 mol/L的HCl在一定程度上能够代替复杂的BCR浸取法;此方法可简化重金属活性形态的提取步骤;适合大范围沉积物重金属污染评价。     

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

Polar WRF模式海冰密集度方案对北极海雾模拟效果的个例研究

全球变暖的背景下,北极航线的常规通航甚至商业运营有望实现,而海雾会严重影响航道上船只的航行安全。海冰的存在使海气之间相互作用变得更为复杂,是研究北极海雾不可忽略的因素。船载观测发现,与中纬度常见平流冷却雾形成时气温下降速度往往超过海水降温速度不同,北极海雾发生时海冰的存在还会使海水降温速度超过空气降温速度。然而目前海冰分布是否会影响模式模拟海雾的准确性还不得而知,因此本文利用Polar WRF（Polar Weather Research and Forecasting）模式模拟了中国第七次北极考察中观测到的一次海雾过程,并进行海冰密集度敏感性试验。通过与船载观测和欧洲中期天气预报中心再分析数据比对发现,在低浮冰区内（海冰密集度小于50%）考虑海冰分布时可以更加准确地刻画潜热通量与水汽通量,模拟出与观测事实相符的表层空气降温与增湿过程以及相对湿度的变化,因此能够更好地刻画海雾的三维结构及其生消演变。     

Lidar-aided analysis of boreal forest backscatter at Ku band

This paper analyzes the backscatter of the microwave signal in a boreal forest environment based on a Ku -band airborne Frequency-Modulated Continuous Waveform (FMCW) profiling radar—Tomoradar. We selected a half-managed boreal forest in the southern part of Finland for a field test. By decomposing the waveform collected by the Tomoradar, the vertical canopy structure was achieved. Based on the amplitude of the waveform, the Backscattered Energy Ratio of Canopy-to-Total (BERCT) was calculated. Meanwhile, the canopy fraction was derived from the corresponding point cloud recorded by a Velodyne VLP-16 LiDAR mounted on the same platform. Lidar-derived canopy fraction was obtained by counting the number of the first/ the strongest returns versus the total amount of returns. Qualitative and quantitative analysis of radar-derived BERCT on lidar-derived canopy fraction and canopy height are investigated. A fitted model is derived to describe the Ku-band microwave backscatter in the boreal forest to numerically analyze the proportion contributed by four factors: lidar-derived canopy fraction, radar-derived canopy height, the radar-derived distance between trees and radar sensor and other factors, from co-polarization Tomoradar measurements. The Root Mean Squared Error (RMSE) of the proposed model was 0.0958, and the coefficient of determination R2 was 0.912. The fitted model reveals that the correlation coefficient between radar-derived BERCT and lidar-derived canopy fraction is 0.84, which illustrates that lidar surface reflection explains the majority of the profiling /waveform radar response. Thus, vertical canopy structure derived from lidar can be used for the benefit of radar analysis.     

O2-O2云反演算法及其在TROPOMI上的应用

利用遥感技术对大气环境污染进行监测时,云是影响痕量气体反演精度的重要因素,因此在痕量气体反演中需要对云的影响进行校正,通常使用的云参数主要是有效云量和云压。本文基于O₂-O₂ 477 nm吸收波段构建了O₂-O₂云反演算法：首先,根据有效云量和云高与连续反射率和O₂-O₂斜柱浓度之间的对应关系,结合假定的云模型利用VLIDORT辐射传输模型建立关于有效云量和云压的查找表;然后,通过差分吸收光谱技术拟合卫星载荷观测的大气层顶辐射,获得O₂-O₂斜柱浓度并计算连续反射率;最后,结合辅助数据,根据查找表进行插值反演获得有效云量和云压。通过将算法应用到OMI观测数据,将反演结果与OMCLDO2产品进行对比验证,有效云量和云压空间分布一致,相关系数R均超过0.97;并还将该算法应用于下一代大气成分监测仪器TROPOMI,与FRESCO+产品对比,有效云量和云压空间分布基本一致,当地表类型为海洋时,有效云量相关系数R大于0.97,云压相关系数R大于0.94,云压反演结果存在一定的区别;通过将O₂-O₂云反演算法和FRESCO+云压反演结果与CALIOP Cloud Layer产品进行对比,结果表明,在低云情况下,O₂-O₂云反演算法线性回归方程斜率为0.782,截距为198.0 hPa,相关系数R为0.850,算法表现优于FRESCO+。而在高云情况下,FRESCO+反演结果更接近CALIOP云压结果。在OMI和TROPOMI上的应用表明O₂-O₂云反演算法在大气云反演中具有较高的准确性和可行性,可以为大气痕量气体反演的校正提供云参数,并为中国同类型卫星载荷的云反演算法提供算法参考。     

西南印度洋中脊表层沉积物非碳酸盐组分的粒度特征及其地质意义

The carbonate-free fraction of 20 surface sediments collected from the ultraslow-spreading Southwest Indian Ridge(SWIR) was studied by grain size analysis and mineralogical analysis with X-ray powder diffraction(XRD),stereo microscopy and scanning electron microscopy(SEM). The characteristics of the carbonate-free fraction of the sediments were obtained, and related influential factors were discussed. The results show that the mean grain size of this fraction is in 1.96Φ–8.19Φ, with poorly sorting and unimodal, bimodal or irregular bimodal distribution patterns. Four grain size end members of the fraction are derived with the End Member Model method. The finest end member EM1 shows a significant contribution of terrigenous materials of the aeolian input and sediment carried by the bottom current. End member EM2 with medium size mainly reflects sediment of a siliceous bioclast origin. EM3 and EM4 are interpreted as representing the coarser volcanic materials related to bedrock weathering or volcanic activities. Multi-provenance is the dominant factor controlling the grain size pattern of the carbonate-free fraction of the sediments in that area. In addition, sediment transport processes such as the bottom current and wind are the minor factors that influence the grain size distribution of the carbonate-free fraction sediments.     

Application of S-SEBI model for crop evapotranspiration using Landsat-8 data over parts of North India

Estimation and monitoring of crop evapotranspiration (ET_c) or consumptive water use over large-area holds the key to irrigation management plans and regional drought preparedness. The objective of this study was to estimate ET_c by applying the simplified-surface energy balance index (S-SEBI) model to Landsat-8 data for the 2014–2015 period in parts of North India. An average ET_c was estimated 2.72 and 2.47 in mm day^?1 with 0.22, 0.18 standard deviation and 0.11, 0.07 standard error for Kharif and Rabi crops, respectively. On validation part, a close relationship was observed between S-SEBI derived and scintillometer observed evaporative fraction with 0.85 correlation coefficient and 0.86 agreement index. The statistical analysis also endorses the results accuracy and reliability with 0.026 and 0.602, relative root-mean square errors and model efficiency for wheat crop, respectively. The study showed that normalized difference vegetation index and LST are closely related and serve as a proxy for qualitative representation of ET_c.     

东、黄海典型海区分粒级浮游植物叶绿素a的周日波动及影响因子

本文分析了东、黄海典型海区3个测站在2000~2003年间4个航次的叶绿素a周日变动特征,结果表明由于地理环境、水文特征以及季节差异,各海区叶绿素a表现出各自不同的变动特点.在东海陆架区,日变化上表层各粒级主要以半日周期为主,受黑潮入侵程度不同而略有变化;长江口由于受到潮汐的影响,各粒级的日变化同潮汐的涨落相对应,主要为半日周期;黄海中部海区叶绿素a尤其是NANO级浮游植物在周日变化上以全日周期为主,受黄海冷水团强弱不同而不同.本文进一步应用渐近回归初步分析了多种环境因子对叶绿素a周日变化的影响.     

Classification of inorganic natural fine-grained soils in Korea based on modified plasticity chart

Classification of fine-grained soils is typically conducted using plasticity charts. The typically used plasticity chart proposed by Casagrande was questioned by Polidori proposing different classification criterion in separating clayey and silty soils. Using natural clayey and silty soils sampled from four different coastal sites in Korea, applicability of both Casagrande’s and Polidori’s plasticity charts was evaluated. Classification results of Korean natural soils based on the Casagrande’s and Polidori’s plasticity charts did not match well with those based on the soils’ behavior reported in the previous publication. The disagreement in classification of Korean natural fine-grained soils may result from disregard of considerable silt fraction effect on plastic and liquid limits for Polidori’s chart. Consequently, revised proposal of Polidori’s plasticity chart was tentatively made for further classification of fine-grained soils suitable for Korean natural soils by accounting the effect of silt fraction on soil classification.     

椒江河口沉积物As、Hg黄铁矿矿化程度及其生物有效性

本文利用取自浙江椒江河口3个未扰动柱状沉积物样,进行了孔隙水化学测试、固相沉积物的活性分量与黄铁矿分量的分级提取和测试,结果表明：Hg主要以黄铁矿态形式存在于沉积物中。As在有机碳较高的河口区潮上带和沉积速率较慢的潮下带主要以黄铁矿形态存在[DTMP（degree of trace metal pyritization,痕量元素黄铁矿矿化程度）〉50%）],而在中潮带As的黄铁矿矿化程度略低（DTMP均值为40.99%）,研究区DOP（Fe的黄铁矿矿化程度）值普遍较低（〈35%）,Mn-DTMP低于3.32%。从而揭示了浙江椒江河口沉积物在数厘米以下,毒性痕量元素Hg和As被高度黄铁矿矿化的规律性,并指出在遇有海事活动或风暴潮事件对海底沉积物进行扰动时,河口沉积物与充氧的海水反应,高度黄铁矿矿化的痕量元素会转变成活性态,从而导致近海生态系统的毒性事件。