塔里木盆地东部地区天然气地球化学特征及成因探讨(之二)

天然气的组分和碳、氢同位素组成特征研究表明塔里木盆地已发现的天然气均为热解气。通过气源对比可知,该盆地东部地区的天然气主要有两种类型 :1)是来自震旦纪到下古生界海相腐泥型母质的油型气,其甲烷、乙烷、丙烷δ13C值,分别为-44.5‰～-33.8‰、- 42‰～-2 8.1‰和-35.4‰～-2 8.4‰,其甲烷的氢同位素组成大于- 2 0 0‰;2 )是产自中生代陆相腐殖型源岩的煤型气,其甲烷、乙烷、丙烷的δ13C值分别为-40.5‰～-33.1‰、- 2 9.7‰～-2 1.3‰和-2 6.3‰～-2 0.3‰,其甲烷的氢同位素组成小于-2 0 0‰。将天然气的地化特征与地质背景相结合判断可知,在塔北隆起地区一些天然气藏是由成熟 (高成熟 )阶段的油型气与过成熟阶段的油型气混合形成,另一些天然气藏是由成熟阶段的油型气和成熟阶段的煤型气混合形成.     

内蒙古西部额济纳旗地区X井油气显示特征与油气源探讨

根据内蒙古额济纳旗地区X井白垩系额济纳旗组、侏罗系麻木鸟苏组、古生界顶面风化壳等不同层段的油气显示特征和钻井泥浆烃类气体组分、甲烷C同位素的分析结果,认为侏罗系和白垩系油气显示特征相同,为油与气显示,气体样品的干燥系数(C_1/C_总)为0.80～0.87,甲烷C同位素δ~(13)C_1为-48.19‰～-50,87‰,表现了低成熟热解气的特征;古生界风化壳为气显示,天然气干燥系数(C_1/C_总)为0.91～0.92,甲烷C同位素δ~(13)C_1为-21.56‰-30.91‰,表现了高成熟热解气的特征.该井及邻区的中生界、古生界烃源岩干酪根类型及其演化程度具有显著的差别,中生界烃源岩以低成熟混合型干酪根为主,古生界烃源岩为成熟-高成熟(或过成熟)的混合型-腐泥型干酪根.表明该区存在以中生界侏罗系-白垩系低成熟烃源岩为油气源的油气系统和古生界高成熟(或过成熟)烃源岩为气源的油气系统,指示了古生界油气资源前景.     

沼泽湿地垦殖对土壤碳动态的影响

在中国科学院三江平原湿地生态试验站选取相邻的、土壤类型相同的小叶章沼泽化草甸以及不同开垦殖年限的已垦湿地农田,综合运用多种微生物指标,全面地评价沼泽湿地垦殖后土壤有机碳的动态。结果表明,沼泽湿地垦殖初期(1~3年),土壤微生物量碳(MBC)、微生物商以及基础呼吸(BR)都迅速降低,而代谢商(qCO₂)、PR/BR和PR/MBC比值却不断升高。表明湿地垦殖后,有机碳的可利用性下降,微生物对碳源的利用效率降低,造成土壤有机碳的大量损失。各种微生物指标之间有密切的相关关系,综合这些微生物指标能够全面地、准确地评价沼泽湿地垦殖后土壤有机碳的动态。     

基于模型模拟的中国秸秆还田固碳潜力空间格局分析（英文）

农作物秸秆还田作为农田土壤和养分管理的推荐做法之一,对于土壤有机碳(SOC)固定和CO_2减排具有重要意义。本研究利用环境政策综合气候模型(EPIC)模拟了4种作物秸秆还田情形下2001年至2010年中国农田表层土壤有机碳变化及其空间格局。模拟结果显示,秸秆完全移除(CR0%)下的土壤有机碳损失为28.89 Tg yr^–1,当前30%的秸秆还田(CR30%)能够减缓22.38 Tg C yr^–1的碳损失。若秸秆还田率从30%提高至50%(CR50%)乃至75%(CR75%),中国农田表层土壤将变为净碳汇。中国农田表层土壤固碳潜力在CR50%和CR75%情形下分别可达25.53 Tg C yr^–1和52.85 Tg C yr^–1,且在不同农业区存在空间异质性。单位面积土壤固碳潜力在西北和华北地区最高,而华东最低。华北地区具有最高的区域固碳潜力。在这十年间,CR50%和CR75%情形下增加的土壤表层有机碳相当于减少了1.4%和2.9%的中国CO_2排放总量。总之,我们建议鼓励我国农民将原本直接焚烧或用作家用燃料的秸秆返还田间以改善土壤性质和减缓大气CO_2增加,尤其是华北地区更应推行这一举措。     

中亚热带人工经济林土壤有机碳含量及分布

人工经济林在中国南方种植面积大,并有不断增加的趋势.人工经济林生态系统受人为周期性经营活动影响比较大,是重要的流动性碳库.因此,选择福建省建瓯市万木林自然保护区内本地条件基本一致的毛竹(Phyllostachys heterocycla)、柑橘(Citrus reticulata Blanco)和锥栗(Castanea henryi)作为研究对象,探讨其土壤有机碳含量及其垂直分布特征,结果表明:3种林地土壤剖面有机碳含量的变化范围分别为毛竹林5.91～19.18 g.kg-1、柑橘5.70～13.31g.kg-1、锥栗3.84～10.78 g.kg-1,3种林地土壤有机碳含量随着深度的增加呈现递减趋势;3种林地0～20 cm、20～40 cm层土壤有机碳含量与40～60 cm、60～80 cm、80～100 cm各层均存在显著性差异(P<0.05);3种林地间土壤有机碳储量均存在显著性差异(P<0.05);使用对数方程对3种林地土壤有机碳含量随土壤深度的变化进行拟合均达到显著水平(P<0.05);土壤有机碳含量与土壤全N、C/N比之间存在一定的相关性,特别是3种林地土壤有机碳含量均与土壤全N含量的相关性最好(...     

基于能源消费的中国不同产业空间的碳足迹分析

Using energy consumption and land use data of each region of China in 2007,this paper established carbon emission and carbon footprint model based on energy consumption,and estimated the carbon emission amount of fossil energy and rural biomass energy of dif-ferent regions of China in 2007.Through matching the energy consumption items with indus-trial spaces,this paper divided industrial spaces into five types:agricultural space,living & industrial-commercial space,transportation industrial space,fishery and water conservancy space,and other industrial space.Then the author analyzed the carbon emission intensity and carbon footprint of each industrial space.Finally,advices of decreasing industrial carbon footprint and optimizing industrial space pattern were put forward.The main conclusions are as following:(1) Total amount of carbon emission from energy consumption of China in 2007 was about 1.65 GtC,in which the proportion of carbon emission from fossil energy was 89%.(2) Carbon emission intensity of industrial space of China in 2007 was 1.98 t/hm2,in which,carbon emission intensity of living & industrial-commercial space and of transportation in-dustrial space was 55.16 t/hm2 and 49.65 t/hm2 respectively,they were high-carbon-emission industrial spaces among others.(3) Carbon footprint caused by industrial activities of China in 2007 was 522.34 106 hm2,which brought about ecological deficit of 28.69 106 hm2,which means that the productive lands were not sufficient to compensate for carbon footprint of industrial activities,and the compensating rate was 94.5%.As to the regional carbon footprint,several regions have ecological profit while others have not.In general,the present ecologi-cal deficit caused by industrial activities was small in 2007.(4) Per unit area carbon footprint of industrial space in China was about 0.63 hm2/hm2 in 2007,in which that of living & indus-trial-commercial space was the highest (17.5 hm2/hm2).The per unit area carbon footprint of different industrial spaces all presented a declining trend from east to west of China.     

The carbon cycle and biogeochemical dynamics in lake sediments

The concentrations of organic carbon (OC) and CaCO3 in lake sediments are often inversely related. This relation occurs in surface sediments from different locations in the same lake, surface sediments from different lakes, and with depth in Holocene sediments. Where data on accumulation rates are available, the relation holds for organic carbon and CaCO3 accumulation rates as well. An increase of several percent OC is accompanied by a decrease of several tens of percent CaCO3 indicating that the inverse relation is not due to simple dilution of one component by another. It appears from core data that once the OC concentration in the sediments becomes greater than about 12%, the CO2 produced by decomposition of that OC and production of organic acids lowers the pH of anoxic pore waters enough to dissolve any CaCO3 that reaches the sediment-water interface. In a lake with a seasonally anoxic hypolimnion, processes in the water column also can produce an inverse relation between OC and CaCO3 over time. If productivity of the lake increases, the rain rate of OC from the epilimnion increases. Biogenic removal of CO2 and accompanying increase in pH also may increase the production of CaCO3. However, the decomposition of organic matter in the hypolimnion will decrease the pH of the hypolimnion causing greater dissolution of CaCO3 and therefore a decrease in the rain rate of CaCO3 to the sediment-water interface.     

喜马拉雅珠峰地区冬季大气气溶胶化学组分及光学特征

为了研究喜马拉雅山北坡冬季大气气溶胶化学组分、光学特征及来源,2017年11—12月在珠穆朗玛峰站(QOMS)共采集22个PM2.5样品.结果显示:PM2.5中包括水溶性离子(WSIs)、有机质(OM)、元素碳(EC)在内的所有检测成分,总质量浓度为(3.36±1.06)μg·m-3;有机碳(OC)、元素碳(EC)和水...     

多巴胺在聚3，4-吡啶二羧酸修饰电极上的电化学行为及其测定

制备了聚3,4-吡啶二羧酸修饰电极,研究了多巴胺在修饰电极上的电化学行为。结果表明聚3,4-吡啶二羧酸聚合物膜对多巴胺的氧化具有明显的催化作用,并且可以消除抗坏血酸对多巴胺测定中的干扰。多巴胺的浓度在2.0×10-6～4.0×10-5mol/L内与其氧化电流呈线性关系,相对标准偏差为3.2%(n=10),检出限为8.0×10-8mol/L。将该修饰电极用于分析模拟样品和注射液样品中的多巴胺,分析结果表明,该修饰电极有望用于实际样品分析。     

硫酸参与的长江流域岩石化学风化速率与大气CO2消耗

流域的岩石化学风化过程是全球碳循环中的重要环节。以往的流域水化学碳汇通量估算大多是基于碳酸的风化作用。而实际上,硫酸和碳酸一样,也参与了流域碳元素的地球化学循环,从而对全球碳循环过程产生影响。长江流域水体近几年出现酸化现象,大部分河段SO42-和Ca2+含量增高,其对应的岩石风化过程和大气CO2消耗速率也发生变化。文章对长江干流及主要支流2013年不同季节的离子组成进行监测,利用水化学平衡法和Galy估算模型,对长江流域岩石化学风化速率和CO2消耗通量进行了估算,对硫酸参与下的长江流域岩石风化和碳循环过程进行了分析。结果表明,长江流域水体离子主要来源于硅酸盐岩风化和碳酸盐岩风化。其中碳酸盐岩风化对河水离子贡献率为92%。在硅酸盐岩广泛分布的赣江流域,碳酸盐岩风化离子贡献也达85%。分析表明,硫酸参与了长江流域的岩石风化过程,对水体中离子产生一定影响。硫酸的参与加快了碳酸盐岩的化学风化速率,平均提高约30%,但是使流域大气CO2消耗速率降低。在不考虑蒸发岩溶蚀作用下,平均从516×103 mol/km2·a降至356×103 mol/km2·a,降低约31%。在各支流中,硫酸对乌江流域碳酸盐岩的风化和碳循环的影响最大,而对雅砻江的影响最小,这与乌江流域的含煤地层、矿床硫化物及大气酸沉降有关。