Cryptic sequence boundaries in braided fluvial successions

In braided fluvial deposits, consisting of monotonous successions of sandstone or conglomerate, it may be difficult to distinguish regionally significant bounding surfaces (sequence boundaries) from autogenic channel-scour surfaces. Major surfaces may be characterized by erosional relief and draped by lag deposits, but not all sequence boundaries show these characteristics. Other clues to the presence of a major surface are sharp changes in detrital composition, shifts in regional palaeocurrent trends and evidence of early diagenesis of the sandstones immediately below the sequence boundary. Examples of these attributes of cryptic sequence boundaries are illustrated from three Mesozoic units in the Colorado Plateau area of the United States. In the Chinle Formation (Triassic), near Moab, Utah, angular intraformational unconformities overlie sandstones showing evidence of early diagenesis. In the Castlegate Sandstone (Upper Cretaceous) of east-central Utah, a cryptic sequence boundary can be discriminated from other erosion surfaces by the evidence of detrital petrography and early diagenesis. Palaeocurrent data indicate changes in regional palaeoslope at two sequence boundaries within this unit. Evidence of early diagenesis is also present at a sequence boundary in the Kayenta Formation (Jurassic) of westernmost Colorado.     

论祁雨沟式金矿

祁雨沟金矿是典型的爆破角砾岩型金矿。系统地论述了其成矿地质背景、矿床地质、地球化学特征、及其成因意义。根据围岩蚀变和矿物包裹体温度、成分的研究,确定了矿床形成的物理化学条件及其各阶段的演变;通过氧同位素研究证明了成矿溶液的来源由早期岩浆水转变为晚期大气降水;用硫、碳和铅同位素组成说明成矿物质的复杂来源。以板块构造理论为指导,建立了矿床的形成模式,并指出找矿方向。     

钙质土力学性质研究现状与进展

概述了钙质土的成因，在世界范围内的分布及一般性质，综述了国内外对钙质土静、动力学性质研究持现状与进展，得到有关结论并提出今后应加强研究的方向。     

鄂尔多斯盆地下奥陶统白云岩成因类型及其地球化学特征

鄂尔多斯盆地天然气藏的主要储集层段,下奥陶统白云岩,按成因可分为准同生、成岩和深埋藏三种类型,它们在岩石结构、X射线衍射、阴极发光、稳定同位素、微量元素特征以及白云石化机理上均有较大差别。     

Effects of groundwater flow on mineral diagenesis, with emphasis on carbonate aquifers

 This article provides a critical synopsis of the effects of groundwater flow on mineral diagenesis. Emphasis is placed on those aspects and processes that change porosity and permeability in carbonate aquifers, because they are of particular importance to human societies as sources of supplies of water for human consumption (drinking, irrigation) and of crude oil and natural gas. Diagenetic settings in carbonates as well as clastics are generally ill defined. This paper proposes a new comprehensive classification of diagenetic settings into near-surface, shallow-, intermediate-, and deep-burial diagenetic settings; hydrocarbon-contaminated plumes; and fractures. These settings are defined on the basis of mineralogy, petroleum, hydrogeochemistry, and hydrogeology. This classification is applicable to all sedimentary basins. Diagenesis is governed by various intrinsic and extrinsic factors that include thermodynamic and kinetic constraints, as well as microstructural factors that may override the others. These factors govern diagenetic processes, such as dissolution, compaction, recrystallization, replacement, and sulfate–hydrocarbon redox-reactions. Processes such as cementation, dissolution, and dolomitization require significant flow of groundwater driven by an externally imposed hydraulic gradient. Other processes, such as stylolitization and thermochemical sulfate reduction, commonly take place without significant groundwater flow in hydrologically nearly or completely stagnant systems that are geochemically "closed." Two major effects of groundwater flow on mineral diagenesis are enhancement and reduction of porosity and permeability, although groundwater flow can also leave these rock properties essentially unchanged. In extreme cases, an aquifer or hydrocarbon reservoir rock can have highly enhanced porosity and permeability due to extensive mineral dissolution, or it can be plugged up due to extensive mineral precipitation. Received, April 1998 · Revised, July 1998 · Accepted, September 1998     

Artificial Maturation of Organic Matter from Recent Venezuelan Sediments

Laboratory simulation of the catagenesis of organic matter in sedimentary rocks has been used to provide an understanding of the processes involved in petroleum generation. Several of these studies have focused on the thermal evolution of organic matter (OM) present in Recent sediments. This study examines the geochemical characteristics and experimental thermal evolution of primary organic matter from two organic facies that are thought to be major contributors to Venezuelan hydrocarbon source rocks. A third facies, generally considered unimportant for petroleum formation, is used to contrast the experimental results. Hydrous pyrolysis maturation experiments were performed for three intermediate temperatures. The products of the final 330°C stage are shown in this paper because they best illustrate the changes in the OM during catagenesis. Results from the hydrous pyrolysis experiments show that at 280°C and higher all three samples yield liquid hydrocarbons similar in composition to natural crudes and the transformed organic matter is similar to kerogen that occurs in natural source rocks. Chromatograms from the saturated fraction of extracts at 330°C are similar to natural crudes with respect to n-alkane distribution and abundance of beta; and beta;alpha; hopanes. The only difference seems to be the relative abundance of 22R over 22S isomers, which indicates immature oil. This is in contrast to indications from the R _o and T _max parameters measured on the accompanying kerogen.     

Stable Eocene Magnetization Carried by Magnetite and Iron Sulphides in Marine Marls (Pamplona-Arguis Formation,Southern Pyrenees,Northern Spain)

In order to establish the magnetic carriers and assess the reliability of previous paleomagnetic results obtained for Eocene marine marls from the south Pyrenean basin, we carried out a combined paleo- and rock-magnetic study of the Pamplona-Arguis Formation, which crops out in the western sector of the southern Pyrenees (N Spain). The unblocking temperatures suggest that the characteristic remanent magnetization (ChRM) is carried by magnetite and iron sulphides. The ChRM has both normal and reversed polarities regardless of whether it resides in magnetite or iron sulphides, and represents a primary Eocene magnetization acquired before folding. Rock magnetic results confirm the presence of magnetite and smaller amounts of magnetic iron sulphides, most likely pyrrhotite, in all the studied samples. Framboidal pyrite is ubiquitous in the marls and suggests that iron sulphides formed during early diagenesis under sulphate-reducing conditions. ChRM directions carried by magnetic iron sulphides are consistent with those recorded by magnetite. These observations suggest that magnetic iron sulphides carry a chemical remanent magnetization that coexists with a remanence residing in detrital magnetite. We suggest that the south Pyrenean Eocene marls are suitable for magnetostratigraphic and tectonic purposes but not for studies of polarity transitions, secular variations and geomagnetic excursions, because it is difficult to test for short time differences in remanence lock-in time for the two minerals. The presence of iron sulphide minerals contributing to the primary magnetization in Eocene marine marls reinforces the idea that these minerals can persist over long periods of time in the geological record.     

Effects of nitrate on phosphorus release: comparison of two Berlin lakes

After installation of phosphorus elimination plants at the inflows of the eutrophic Lake Tegel and Schlachtensee, phosphorus (P) loading declined by a factor of 40 and 100, respectively. This resulted in a pronounced reduction of phosphorus concentrations in the lake water, followed by a decline of chlorophyll‐a concentrations. However, for many years P release from sediments due to mineralization and desorption of sedimentary P continued. In Schlachtensee, the presence of nitrate above the sediment suppresses P release, because the Fe/P ratio is sufficient to provide enough aerobic sorption capacity. In Lake Tegel, some P release occurs even under aerobic conditions because of the low aerobic P sorption capacity of the sediments. There, nitrate could moderate the P release peaks which occur when the Fe‐P cycle at the sediment water interface is disturbed by precipitation of iron sulfide after reduction of sulfate during times of high mineralization intensity. The potentially mobile P pool in the sediments of both lakes is rather small, indicating that the P release could subside after sufficient reduction of the external P load in Lake Tegel and the disruption of the internal P cycle in Schlachtensee.     

Age model, physical properties and paleoceanographic implications of the middle Pleistocene core sediments in the Choshi area, central Japan

Abstract   A continuous, well-preserved core was obtained from the Choshi area, on the Pacific side of Japan, to investigate paleoceanographic and paleoclimatic changes around the northwestern Pacific region during the middle Pleistocene. Siliciclastic sequences in the core are divided into five formations – the Obama, Yokone, Kurahashi and Toyosato Formations in the Inubo Group and the Katori Formation, in ascending order. Examination of calcareous nannofossils and magnetic polarities detected four datums in the core sediments of the Inubo Group: the top of Reticulofenestra asanoi , the base of Helicosphaera inversa , the top of Pseudoemiliania lacunosa and the Brunhes–Matuyama boundary. Fourteen marine isotope stages (MIS24–MIS11) were identified in the δ¹⁸O and δ¹³C records based on detected datums and the graphic correlation with the standard stack oxygen isotope curve. Magnetic susceptibility and gamma-ray attenuation porosity evaluator density were also measured and low values characterize the glacial intervals. Biogenic sedimentation by primary production may be larger during the glacial periods because of invasions of nutrient-rich northern surface-waters related to the southward shift of the Kuroshio front in the Choshi area.