The 1985 chlorine and fluorine inventories in the stratosphere based on ATMOS observations at 30° north latitude

The set of high-resolution infrared solar observations made with the Atmospheric Trace Molecule Spectroscopy (ATMOS)-Fourier transform spectrometer from onboard Spacelab 3 (30 April-1 May 1985) has been used to evaluate the total budgets of the odd chlorine and fluorine chemical families in the stratosphere. These budgets are based on volume mixing ratio profiles measured for HCl, HF, CH₃Cl, ClONO₂, CCl₄, CCl₂F₂, CCl₃F, CHClF₂, CF₄, COF₂, and SF₆ near 30° north latitude. When including realistic concentrations for species not measured by ATMOS, i.e., the source gases CH₃CCl₃ and C₂F₃Cl₃ below 25 km, and the reservoirs ClO, HOCl and COFCl between 15 and 40 km (five gases actually measured by other techniques), the 30° N zonal 1985 mean total mixing ratio of chlorine, Cl, was found to be equal to (2.58±0.10) ppbv (parts per billion by volume) throughout the stratosphere, with no significant decrease near the stratopause. The results for total fluorine indicate a slight, but steady, decrease of its volume mixing ratio with increasing altitude, around a mean stratospheric value of (1.15±0.12) ppbv. Both uncertainties correspond to one standard deviation. These mean springtime 1985 stratospheric budgets are commensurate with values reported for the tropospheric Cl and F concentrations in the early 1980s, when allowance is made for the growth rates of their source gases at the ground and the time required for tropospheric air to be transported into the stratosphere. The results are discussed with emphasis on conservation of fluorine and chlorine and the partitioning among source, sink, and reservoir gases throughout the stratosphere.     

Impact of open-ocean convection on nutrients,phytoplankton biomass and activity

We describe the impact of an open-ocean convection event on nutrient budgets, carbon budget, elemental stoichiometry, phytoplankton biomass and activity in the Northwestern Mediterranean Sea (NWM). In the convective episode examined here we estimated an input of nutrients to the surface layer of 7.0, 8.0 and 0.4×10⁸ mol of silicate, nitrate and phosphate, respectively. These quantities correspond to the annual nutrient input by river discharges and atmospheric depositions in the Gulf of Lion. Such nutrient input is sufficient to sustain new primary production from 46 to 63 g C m⁻² y⁻¹, which is the same order of magnitude found in the NWM open waters. Our results together with satellite data analysis, propose new scenarios that explain the origin of the spring phytoplankton bloom occurring in NWM.     

The influence of landsliding on sediment supply and channel change in a steep mountain catchment

Rates of sediment supply by landsliding to an alluvial channel in a small catchment in central Switzerland were estimated over an 11-month study period. Fluvial sediment transport in the channel is independently monitored at the upstream and downstream ends of the study reach, yielding a unique opportunity to quantitatively compare the volume of sediment supplied to the channel with the volume in fluvial transport. Landslide-derived sediment discharge to the channel was greatest during the winter and spring months, while most of the fluvial sediment transport occurred during short, intense summer storms. Approximately 98 m³ of sediment was delivered directly to the study reach by landsliding,  80 m³ was transported into the reach from upstream, and  70 m³ was transported out of the reach. Thus, there was a net accumulation of  100 m³ of sediment during the 11-month study. Decadal-scale channel aggradation was independently assessed by comparing channel longitudinal profiles in 1993 and 2004. During this 11-year period, a total of  1500 m³ of sediment has accumulated in the study reach. Aggradation has occurred largely in two broad zones that correspond with both the locations of major landslide complexes and reaches of high channel slope, indicating that hillslope sediment input left an imprint on the morphology of the channel bed that appears to be stable over at least decadal time scales.     

“97.12”高原暴雪过程中尺度热量和水汽收支诊断

应用非静力模式MM5V2对1997年12月（简称：97．12”）一交高原暴雪过程进行控制模拟试验。利用其输出资料以及热量和水汽收支方程，对这次暴雪过程进行了热量及水汽收支诊断。视热源（Q1）和视水汽汇（Q2）的诊断结果表明：Q1和Q2垂直积分的正值区分布形势相似且较强，并与地面降雪带的分布一致，因而，此次过程的Q1、Q2主要是由水汽凝结和潜热解释决定的。Q1在对流层为加热层，对流层上层相对为冷层，是暴雪发生发展的主要热力机制。Q1、Q2区域平均的垂直廓线峰值非常相近，该峰值区正是水汽凝结层，它与水汽输送带的水汽凝结变干有关。视水汽汇Q2与视热源Q1具有相近的垂直廓线，表明“97．12”暴雪过程中非对流性凝结降水起决定因素。这些结果为改进和发展用于模拟和预报高原暴雪的中尺度数值模式模拟系统提供了一些物理依据。     

Zero carbon energy system pathways for Ireland consistent with the Paris Agreement

The Paris Agreement is the last hope to keep global temperature rise below 2°C. The consensus agrees to holding the increase in global average temperature to well below 2°C above pre-industrial levels, and to aim for 1.5°C. Each Party’s successive nationally determined contribution (NDC) will represent a progression beyond the party’s then current NDC, and reflect its highest possible ambition. Using Ireland as a test case, we show that increased mitigation ambition is required to meet the Paris Agreement goals in contrast to current EU policy goals of an 80–95% reduction by 2050. For the 1.5°C consistent carbon budgets, the technically feasible scenarios' abatement costs rise to greater than €8,100/tCO₂ by 2050. The greatest economic impact is in the short term. Annual GDP growth rates in the period to 2020 reduce from 4% to 2.2% in the 1.5°C scenario. While aiming for net zero emissions beyond 2050, investment decisions in the next 5–10 years are critical to prevent carbon lock-in.

Key policy insights

• Economic growth can be maintained in Ireland while rapidly decarbonizing the energy system.

• The social cost of carbon needs to be included as standard in valuation of infrastructure investment planning, both by government finance departments and private investors.

• Technological feasibility is not the limiting factor in achieving rapid deep decarbonization.

• Immediate increased decarbonization ambition over the next 3–5 years is critical to achieve the Paris Agreement goals, acknowledging the current 80–95% reduction target is not consistent with temperature goals of ‘well below’ 2°C and pursuing 1.5°C.

• Applying carbon budgets to the energy system results in non-linear CO₂ emissions reductions over time, which contrast with current EU policy targets, and the implied optimal climate policy and mitigation investment strategy.

     

ROx Budgets and O3 Formation during Summertime at Xianghe Suburban Site in the North China Plain

Photochemical smog characterized by high concentrations of ozone (O3) is a serious air pollution issue in the North China Plain (NCP) region, especially in summer and autumn. For this study, measurements of O3, nitrogen oxides (NOx), volatile organic compounds (VOCs), carbon monoxide (CO), nitrous acid (HONO), and a number of key physical parameters were taken at a suburban site, Xianghe, in the NCP region during the summer of 2018 in order to better understand the photochemical processes leading to O3 formation and find an optimal way to control O3 pollution. Here, the radical chemistry and O3 photochemical budget based on measurement data from 1-23 July using a chemical box model is investigated. The daytime (0600-1800 LST) average production rate of the primary radicals referred to as ROx (OH + HO2+ RO2) is 3.9 ppbv h-1. HONO photolysis is the largest primary ROx source (41％). Reaction of NO2 + OH is the largest contributor to radical termination (41％), followed by reactions of RO2 + NO2 (26％). The average diurnal maximum O3 production and loss rates are 32.9 ppbv h-1 and 4.3 ppbv h-1, respectively. Sensitivity tests without the HONO constraint lead to decreases in daytime average primary ROx production by 55％ and O3 photochemical production by 42％, highlighting the importance of accurate HONO measurements when quantifying the ROx budget and O3 photochemical production. Considering heterogeneous reactions of trace gases and radicals on aerosols, aerosol uptake of HO2 contributes 11％ to ROx sink, and the daytime average O3 photochemical production decreases by 14％. The O3-NOx-VOCs sensitivity shows that the O3 production at Xianghe during the investigation period is mainly controlled by VOCs.     

区域尺度陆地生态系统碳收支评估方法及其不确定性

定量评估区域和不同类型生态系统的碳收支,可以为科学预测气候变化、服务于减缓和适应气候变化的区域碳管理提供科学依据,是生态系统与全球变化科学研究的重要科技问题.虽然区域碳收支的定量评估和认证还很难用当前的各种直接观测和评估方法来精确实现,但是,近年来这方面做了很多研究工作,也取得了一定进展.为此,本文综述了陆地生态系统碳...