Equilibrium constants of triethanolamine in major seawater salts

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.     

A Note on Tsunami Bore Front

A note is presented on tsunami bore front. This tsunami bore front is an old dynamical problem but also a new problem to be understood. The tsunami event on 2004 December 26 has raised this is an urgent problem. The author introduces here a model in order to see a hydrodynamical specific property of the tsunami bore front. This modeling gives us a new understanding about what mechanics is for the interested tsunami bore front, especially, around a coastal zone. This work adds a new understanding about mechanics of water motions as the tsunamis generated by the earthquake undersea at a distant area from the coast. The model in this work points out a specific transitional pattern as a function of time and space of tsunami bore front. This modeling gives what is essential at considering tsunami bore front.     

近岸海浪模式在中国东海台风浪模拟中的应用--数值模拟及物理过程研究

较为详细地介绍了基于能量平衡方程的第三代近岸海浪数值模式SWAN（Simulation Waves Nearshore）及其包含的物理过程（风生浪、底摩擦、白浪耗散、深度诱导波破碎、非线性波－波相作用等），并利用该模式对影响杭州湾－长江口沿岸海域的一次台风浪过程进行了模拟研究：模式所需风场由藤田台风风场模型嵌入对应台风特征等压线，并对相应时段的NCAR／NCEPT资料、单站资料进行同化后提供；利用自嵌套的方式提供波谱边界条件；模式模拟的结果与实际海浪观测资料相符较好，在此基础上，研究了底摩擦、深度诱导波破碎、三波相互作用等物理过程联合对近岸台风浪的影响，初步认识了它们在近岸台风浪生成、传播过程中的重要作用。     

一维扩散方程整体观测资料下的初值变分同化反演

本文考虑一维扩散方程的反问题,利用变分同化方法通过观测资料来确定方程中的未知初值,通过分析观测误差对于初值误差的影响,证明变分同化初值收敛于原问题的真实参数,并得到了参数的收敛精度。同时将得到的初值代入预报模式中,得到预报解,并分析了预报解的收敛性和预报误差。     

Risk assessment of TBT in the Japanese short-neck clam (Ruditapes philippinarum) of Tokyo Bay using a chemical fate model

A risk assessment of Tributyltin (TBT) in Tokyo Bay was conducted using the Margin of Exposure (MOE) method at the species level using the Japanese short-neck clam, Ruditapes philippinarum. The assessment endpoint was defined to protect R. philippinarum in Tokyo Bay from TBT (growth effects). A No Observed Effect Concentration (NOEC) for this species with respect to growth reduction induced by TBT was estimated from experimental results published in the scientific literature. Sources of TBT in this study were assumed to be commercial vessels in harbors and navigation routes. Concentrations of TBT in Tokyo Bay were estimated using a three-dimensional hydrodynamic model, an ecosystem model and a chemical fate model. MOEs for this species were estimated for the years 1990, 2000, and 2007. Estimated MOEs for R. philippinarum for 1990, 2000, and 2007 were approximately 1–3, 10, and 100, respectively, indicating a declining temporal trend in the probability of adverse growth effects.A simplified software package called RAMTB was developed by incorporating the chemical fate model and the databases of seasonal flow fields and distributions of organic substances (phytoplankton and detritus) in Tokyo Bay, simulated by the hydrodynamic and ecological model, respectively.     

Comparison of two three-dimensional hydrodynamic modeling systems for coastal tidal motion

A comparison of two three-dimensional numerical modeling systems for tidal elevations and velocities in the coastal waters is presented. The two modeling systems are: (1) the Princeton Ocean Model (POM) and (2) the MIKE 3 flow model. The model performance results for Singapore's coastal waters show that the predicted tidal elevations from the two hydrodynamic modeling systems are almost identical and are in very good agreement with field measurement data. The simulated tidal current velocities match well with field measurement data at the selected stations, but it seems that the POM provides the slightly better simulation, compared to the MIKE 3 flow model. The depth profiles of the velocities obtained from the two modeling systems may be greatly different at some time, due to the vertical diffusion coefficient calculated from different turbulent sub-models in the two modeling systems. The POM generally predicts larger peak tidal velocities. The maximum speed differences for the model results from the two modeling systems occur in the top and differ from time to time and from location to location, reaching up to 20%.     

Investigation on the Deposition in an Excavated Trough at the East Shore of Jiaozhou Bay, China

- Based on field investigations, this paper analyzes three types of harbour basinns and navigation channel excavated on seabed in Jiaozhou Bay, get a general rule of deposition for excavated trough, it found that pollution is one of crucial factors resulting in the deposition of the excavated trough in the east shore of Jiaozhou Bay. With these results, it predicted the annual deposition thickness for the excavated trough and disclosed the fact that it can't be deposited deadly during one storm. At the same time, with two-dimensional numerical model, it studied the effects of the excavated trough and the reclamation near shore on tidal cureent and said that the excavated trough can decrease the current velocity passing through the trough about 10- 15%, but only limited inside and near the trough and there are no effect on other regions; reclamation can cut off the pollution sources and no obvious effect on the currents of the Jiaozhou Bay. Connecting the deep trough and Cangkou tidal channel with a new     

模型沙干重度的变化规律及其在泥沙模型试验中的作用

模型沙干重度在动床模型试验中是影响起动流速比尺和冲淤时间比尺的重要参数，其随淤积历时、粒径变化、埋置深浅和加工方法的不同有着不同的变化规律。通过试验，结合已有的成果，对模型沙干重度受以上几种因素的影响进行了研究，并进一步分析了其变化规律在动床模型试验中的作用。     

A phase-averaged Boussinesq model with effective description of carrier wave group and associated long wave evolution

From the phase-resolving improved Boussinesq equations (Beji and Nadaoka, Ocean Engineering 23 (1996) 691), a phase-averaged Boussinesq model for water waves is derived by more effectively describing carrier wave groups and accompanying long wave evolution with less CPU time. Linear shoaling characteristics of carrier wave equations are investigated and found to agree exactly with the analytical expression obtained from the constancy of energy flux for the improved Boussinesq equations themselves, showing that the present model equations are the results of a consistent derivation procedure regarding energy considerations. Numerical simulations of the derived equations for the single wave group and narrow-banded random waves show the validity of the present model and its high performance, especially on the CPU time.