X射线衍射-红外光谱-扫描电镜表征超声辅助合成GdPO_4:Ce,Tb纳米材料形貌及光学性质

超声辅助方法是制备纳米材料的有效手段,可提高纳米材料的磁学、光学等特殊性能。本文在不同p H条件下超声辅助合成GdPO_4:Ce,Tb三元体系荧光粉,采用X射线粉末衍射、傅里叶变换红外光谱、扫描电镜、透射电子显微镜及光致发光荧光光谱分析方法对样品进行了表征。结果表明:①样品仅在p H=1时,才能生成规则的15 nm×104nm六方晶系纳米棒状正磷酸盐绿色荧光粉,晶体优先选择(102)及(200)晶面生长;p H1无法得到样品;p H1为颗粒状的正磷酸盐绿色荧光粉。②进一步验证了Gd、Ce、Tb三元体系中Ce~(3+)离子能量较高的5d组态将能量传递给Gd~(3+)离子,而Gd~(3+)离子的跃迁发射与Tb~(3+)离子的吸收峰有较大的光谱重叠,故传递途径是Ce~(3+)→Gd~(3+)→Tb~(3+);少量Ce~(3+)的引入可提高以GdPO_4基质发光材料的发光强度。此结果可为开发稀土材料提供理论依据。     

氧化还原障在热液铀矿成矿中的作用

铀是变价元素,氧化还原条件控制铀的迁移和沉淀。铀在氧化环境中呈U~(6+)形式存在,在还原条件下则以U~(4+)形式存在。氧化态六价铀主要以可溶的碳酸铀酰/氟化铀酰络合物形式在水溶液中迁移,还原态四价铀主要以沥青铀矿和铀石等形式富集沉淀成矿。热液铀矿的形成需要一对空间上密切共生的氧化障/氧化剂和还原障/还原剂,二者缺一不可。首先,氧化障中氧化剂将富铀岩石中的铀大量氧化形成U~(6+),溶解进入水溶液迁移;第二,高氧化性富铀溶液遇到还原障,U~(6+)还原成U~(4+)沉淀下来,富集形成铀矿。前人虽然对铀的地球化学性质及氧化还原反应在铀成矿中作用已比较了解,但如何在实际铀矿成矿系统中准确识别氧化还原障,有效利用氧化还原障的控矿机理指导找矿,还存在一些模糊认识,制约了铀成矿理论的发展和找矿方法的提升。本文以我国最重要的砂岩型铀矿、火山岩型铀矿、花岗岩型铀矿和变质型铀矿为例,总结了与铀矿化有关的氧化还原障的主要类型,探讨了红层等蒸发盐地层(氧化障),有机质、煌斑岩等中基性岩脉(还原障)与铀矿之间的关系及控矿机制,揭示了成矿盆地中铀-煤、铀-气(油)共生的机制,阐明了翁泉沟硼、铁、铀矿共生原因,建立了不同类型铀矿成矿模型。     

From river to shelf,anatomy of a high‐frequency depositional sequence: The Late Pleistocene to Holocene Tiber depositional sequence

The Late Pleistocene/Holocene Tiber delta succession represents the most recent and one of the best preserved, high‐frequency/low‐rank depositional sequences developed along the Latium continental margin of the Italian peninsula. Several previous studies have established a robust data set from which it has been possible to describe the stratigraphic architecture of the entire Tiber depositional sequence from the landward to seaward sectors and over a distance of 60 km. The Tiber depositional sequence shows many characteristics found in other Late Pleistocene to Holocene deltaic and coastal successions of the Mediterranean area. The stratigraphic architecture of the Tiber depositional sequence is controlled mainly by glacioeustasy, although factors such as tectonic uplift, volcanism and subsidence, exert an influence at a local scale. The resulting depositional model allowed discussion of some important points such as: (1) the genesis of the Tiber mixed bedrock‐alluvial valley, extending from the coastal plain to the innermost portion of the shelf, recording (i) multiple episodes of incision during relative sea‐level fall, and (ii) a downstream increase of depth and width of the valley during the base‐level fall and the subsequent base‐level rise; (2) the different physical expression of the Tiber depositional sequence boundary from landward to seaward, and its diachronous and composite character; (3) the maximum depth reached by the Tiber early lowstand delta at the end of the sea‐level fall is estimated at ca 90 m below the present sea‐level and not at 120 m as suggested by previous works; (4) the backward position of the Tiber late lowstand delta relative to the deposit of early lowstand; (5) the change of the channel pattern and of the stacking pattern of fluvial deposits within the Lowstand Systems Tract, Transgressive Systems Tract and Highstand Systems Tract. All of these features indicate that the Late Pleistocene/Holocene Tiber delta succession, even if deposited in a short period of time from a geological point of view, represents the result of the close interaction among many autogenic and allogenic factors. However, global eustatic variations and sediment supply under the control of climatic changes can be considered the main factors responsible for the stratigraphic architecture of this sedimentary succession, which has been heavily modified by human activity only in the last 3000 years.     

塔里木盆地东河1油藏低渗层层序控制特征及其对注气开发的影响

通过测井和岩心分析,将塔里木东河1油藏东河砂岩段从下到上划分为前滨-上临滨-下临滨相带,并进一步划分出11个准层序。经岩相学分析,将砂岩段低渗层分为钙质胶结低渗层、杂基充填低渗层和混合低渗层。钙质胶结低渗层主要分布在准层序内部,以方解石胶结砂岩为主,受成岩作用控制;杂基充填低渗层主要分布在准层序边界处,多为海侵背景下的滞后沉积产物;混合低渗层在准层序内部及边界均有分布,但数量很少,无明显规律性,砂粒间主要由杂基和方解石胶结物混合充填,充填物含量低。结合测压资料认为,发育在准层序边界处的杂基低渗层保留了更多的初始沉积特征,易形成横向连续性好的低渗层,是注气开发的重点关注对象。     

基本层序界面类型及其在岩石地层单位划分中的应用

基本层序在垂向上的重大转化面即为基本层序界面,由高到低可划分为旋回性基本层序/不显旋回性基本层序间界面(Ⅰ级界面)、旋回性基本层序/韵律性基本层序间界面(Ⅱ级界面)和向上变细粒序/向上变粗粒序间界面(Ⅲ级界面)。这些界面广泛发育于碎屑沉积岩中,因而是细分地质填图单位的重要选择界面。这一方案是对传统沉积序列分层及地质填图单位界面选择的重要补充,对指导中国造山带巨厚碎屑岩建造的地质填图单位划分、沉积相分析和区域地质研究具有重要意义。     

Design Method,Application and Time Alternative Mechanism of Flexible Use of Airspace

The flexible use of airspace and its practice are the key components of next generation air transportation system and the important technical support of reconstructing the national airspace in Europe, Japan and other countries. On the basis of overview and comprehensive cognition of the generation, implementation and aims of flexible use of airspace, the design methods of sector’s boundary changes were evaluated. Then, from the perspective of “sector-closed”, the effect on sector boundary changes was evaluated, and the time alternative mechanism in flexible use of airspace was revealed. The research shows that “Algorithm+Manual Dynamic Boundary Change” can be a method for better distribution and balancing the unbalanced traffic demand across regions, which will also promote the airspace development and capacity release. The flexible use of airspace based on ICTs realizes the replacement of the factor of space by the factor of time, which enhances the flexibility of airspace configuration and the changing of air routes to the maximun extent. The methods and applications of flexible use of airspace will be not only beneficial to establishing the whole national airspace system and utilization, but also to promoting geography research on airspace resources development and the studies on connection between air and land.     

内孤立波数值造波方法及其与理论和实验结果的比较

为评估不同内孤立波数值造波方法,本文基于Kd V、m Kd V和e Kd V三种理论模型,分别采用双推板、平板拍击和速度入射边界三种数值造波方法,对内孤立波进行了模拟,并将数值模拟结果与理论及实验结果进行对比和分析。结果表明:三种数值造波方法均能实现对内孤立波的模拟,但在造波效果及效率方面存在差异。速度入射边界法在造波效果及效率方面都比较好;平板拍击法的造波效果较好,效率略差;双推板法在造波效果及效率方面均略劣于以上两种方法。     

浅化波浪层流边界层流速分布特性的数值分析

建立了同时考虑波致雷诺应力和时均水平压强梯度影响的二阶波浪边界层数学模型,模型计算得到的浅化波浪层流边界层内瞬时流速剖面、振荡速度幅值和时均流速剖面均与水槽实验数据吻合较好,在此基础上探讨了浅化波浪边界层流速分布特性及其影响机制。随着波浪的浅化变形,边界层内时均流速剖面"底部向岸、上部离岸"的变化特征越来越明显。这是二阶对流项引起的波致雷诺应力和离岸回流引起的时均水平压强梯度共同作用的结果,在床面附近由波致雷诺应力占主导作用并趋于引起向岸流动,在上部区域由时均水平压强梯度占主导作用并趋于引起离岸流动。     

风浪和海洋飞沫对海表面拖曳系数和风廓线的影响

基于埃克曼理论,本文将波致应力和飞沫应力引入到海-气边界层的界面应力中,来研究海表面风浪和海洋飞沫对海-气边界层动量交换的影响,并得到修改后的埃克曼模型的理论解。波致应力是由风浪谱和波增长函数估计,并得到在中低风速下,波致应力、飞沫应力与湍流应力相比,对海表面拖曳系数和风廓线的影响非常小。当风速高于25米/秒时,海洋飞沫通过飞沫应力对海-气界面应力的作用远高于波致应力,以至于波致应力可以忽略。海表面拖曳系数在高风速下,随着风速的增大而减小。通过采用风浪谱的不同波龄,得到海洋飞沫的产生会导致海-气边界层风速的增加。最后,理论解与现场的观察数据进行了对比。对比后的数据表明,在中高风速下,飞沫对海-气边界层的影响远大于表面风浪。     

祁连山北缘酒西盆地新生代沉积通量变化对周缘山体构造隆升-风化剥蚀历史的响应

酒西盆地是青藏高原东北缘的一个内陆沉积盆地,发育了巨厚且连续的中-新生代地层,详细记录了盆地及周缘山地的构造、环境演变历史。本文在利用平衡剖面法恢复不同时期酒西盆地原始盆地边界基础上,通过盆地天然露头控制剖面和钻井资料的地层厚度,恢复了酒西盆地新生代各组沉积等厚图。根据不同时期盆地大小和沉积等厚图的计算,获得了酒西盆地新生代不同时期的沉积通量。结合前人对该区构造与古气候研究成果,认为古近纪持续干旱的气候条件下从火烧沟组(40.2~33.4 Ma)到白杨河组(30.9~23.8 Ma)盆地沉积通量增加主要由青藏高原持续挤压使祁连山快速构造隆升导致风化剥蚀量增加所致;中新世早期(疏勒河组弓形山段,23~14 Ma)虽然气候相对温暖,但此时祁连山构造带相对稳定,控制了物源区祁连山风化剥蚀量相对前期减小,使盆地沉积通量相对减小;中新世中期(疏勒河组胳塘沟段,14~8.3 Ma)盆地沉积通量增大可能是气候和构造共同作用的结果;中新世晚期以来(<8.3 Ma,疏勒河组牛胳套段-玉门组)盆地沉积通量呈阶段性大幅陡增,主要由祁连山晚新生代以来阶段性急剧构造隆升导致风化剥蚀量猛增所致。