Corrosion behavior of anodic oxidized TiO<Subscript>2</Subscript> film in seawater

TiO₂ films were formed on metallic titanium substrates by the anodic oxidation method in H₂SO₄ solution under the 80V D.C.. Phase component and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Water contact angles on titanium oxide film surface were measured under both dark and sunlight illumination conditions. Corrosion tests were carried out in seawater under different illumination conditions by electrochemistry impedance spectrum (EIS) and polarization curves. The result showed that the TiO₂ film prepared by the anodic oxidation method was anatase with a uniform structure and without obvious pores or cracks on its surface. The average water contact angle of the film was 116.4° in dark, in contrast to an angle of 42.7° under the UV illumination for 2 hours, which demonstrates good hydrophobic property. The anti-corrosion behavior of the TiO₂ film was declining with the extended immersion time. Under dark conditions, however, the hydrophobic TiO₂ film retarded the water infiltrating into the substrate. The impedance changed slowly and the corrosion current density was 2 orders of magnitude lower than that with the film illuminated by sunlight. All of those mentioned above indicate that the TiO₂ film possesses much better performance under dark condition, and it can be applied as an engineering material under dark seawater environment.     

井筒电加热改善水平井蒸汽吞吐效果机理实验

针对稠油水平井蒸汽吞吐面临入井渗流阻力大、产量水平低、吞吐递减率高、采收率偏低等问题,提出了电加热辅助水平井蒸汽吞吐方法.首先根据水平井蒸汽吞吐过程中的电加热与蒸汽复合传热特征,建立了电加热辅助蒸汽吞吐三个阶段的(注汽阶段、焖井阶段、生产阶段)储层升温解析模型,在此基础上,设计并开展了电加热辅助蒸汽吞吐和常规水平井吞吐...     

地震区多层石结构抗震抗剪能力的模糊可靠性分析

本文通过考虑地震烈度的随机性和模糊性,以及石结构强度破坏等级界限的模糊性,研究多层石结构抗震抗剪能力的可靠性问题.将地震地面运动模拟为含有模糊烈度参数的平稳过滤有色噪声的随机过程,引入抗剪强度破坏指数,建立了石结构抗震抗剪能力的模糊安全准则,为研究多层石结构的抗震抗剪能力可靠性提供了一个合理的评定方法。     

竖向高荷载作用下大直径超长钻孔灌注桩承载性能试验

通过机场—西华高速大直径超长钻孔灌注桩大吨位竖向单桩静载试验,分析了该地区大直径超长钻孔灌注桩的承载性状以及荷载传递机理。试验结果表明:试桩的Q-S曲线呈缓变型,桩端承载力占总荷载的比例均<10%,即均表现为摩擦桩特性;试桩的侧摩阻力自上而下逐步发挥,侧摩阻力和桩端阻力异步发挥且互相耦合;大直径超长钻孔灌注桩桩侧摩阻力的发挥与土层性质、土层埋深及桩顶荷载水平有关;在高荷载作用下桩侧上部土层摩阻力具有不同程度的软化现象,而中下部土层侧摩阻力具有不同程度的强化现象,甚至即使在最大加载情况下,桩身下部土层的侧摩阻力也并未完全发挥,因此在根据规范计算超长桩承载力时,不同深度土层的侧摩阻力应乘以相应不同的修正系数。     

Cone penetration test in sand: A numerical-analytical approach

Separation of the effects of initial horizontal stress and relative density on cone tip resistance in sandy soils has been a complicated issue for many years. In order to overcome this problem, a numerical modeling of CPT which has been verified by calibration chamber tests, has been used in this paper to achieve a reliable analytical solution. The analytical solution has resulted in two relationships for sleeve friction and cone tip resistance in terms of the initial conditions of sandy soil. Based on the presented solution, the initial horizontal stress and relative density can be determined according to CPT measurements.     

垃圾填埋场衬垫系统穿刺性能评价

垃圾中含有铁、玻璃和陶瓷等尖锐物,在荷载作用下极有可能使衬垫系统发生破坏,导致渗滤液流入地下污染周边环境,如何正确评价衬垫系统的穿刺性能很重要。考虑材料的抗拉强度、厚度以及穿刺棒的直径提出了衬垫系统穿刺力的评价公式,并与试验结果进行了比较。结果表明,单层土工膜的抗穿刺力试验结果与评价值比较吻合,但由土工膜与无纺布组成的衬垫系统抗穿刺力的试验值与评价结果有一定偏差;土工膜与无纺布一起使用能大幅度提高衬垫系统的抗穿刺能力,因此土工膜上应铺设无纺布有利于保护衬垫系统;土工膜的抗拉强度越大,抗穿刺能力越强;基础的存在能在一定程度上提高衬垫系统的抗穿刺性能。所得结果对垃圾填埋场衬垫系统的设计具有一定的指导意义     

某公路顺层滑坡的整治及对该区段选线的反思

通过对某顺层古滑坡的现场调查,分析判断了古滑坡的滑动范围、滑动面,并对滑动面抗剪强度参数进行了反分析计算。据此对古滑坡体进行了初步整治设计,实际整治时未采取防水措施,抗滑指标进一步下降,笔者对此时软化后滑动面抗剪强度进行了计算分析。结合对K89～K95段的调查分析,对此区段的切方边坡违背工程地质选线原则导致的后果进行了反思。     

豫陕鄂交界区县域综合发展水平测度及障碍因子分析

以豫陕鄂交界区为研究对象,测度2000—2017年豫陕鄂交界区县域的综合发展水平,探析其空间分异特征、演化趋势和障碍因素。结果表明：① 2000—2017年,豫陕鄂交界区县域综合发展水平逐步提升,年均增速为6.08%,县域间发展的空间差异逐渐增大;② 县域综合发展水平在空间上呈正相关性,热点显著区呈现由东南部向西南部再向东南部迁移变化特征,冷点显著区在2005年前主要分布在安康市和商洛市,之后主要聚集在南阳市;③ 人文和经济要素为中度和中高障碍水平,资源和环境要素为极低和低障碍水平;随着时间的推移,障碍因子在不同县域空间阻力的分异特征更加显著。④ 豫陕鄂交界区县域发展空间阻力模式可划分为3种类型,其中人文资源要素制约型是主要的空间阻力模式。最后,基于不同空间阻力模式特征解析,提出了分区发展策略。     

海上平台桶基负压沉贯阻力与土体稳定数值计算研究

用有限元分析方法对桶形基础负压沉贯过程中流场进行动态模拟,提出桶形基础沉贯阻力计算方法和土体稳定有限计算方法,提出桶内土体稳定性判断准则,计算结果表明所提方法是合理的,并具有工程实用性。     

承台外区土阻力群桩效应及效应系数的有限元分析

利用三维弹塑性有限元方法,对复合桩基承台外区土阻力群桩效应及其效应系数进行了研究,讨论了土类、桩长、桩距、桩数等对承台外区土阻力群桩效应及其群桩效应系数的影响,结果表明(1)承台外区土阻力随承台宽与桩长之比 (B/L)的增大而增大,但增幅不大;随桩距S增大而增大;受桩数n的影响不大。(2)承台外区群桩效应系数随B/L增大几乎无变化;随S增大而增大;不随n变化而变化。(3)承台外区群桩效应系数与土类有关。