中国海及大陆架沉积物标准物质系列评介

自20世纪90年代末以来,在有关国家专项的支持下,中国先后研制了分别取自黄海、东海和南海的共9个大陆架沉积物地球化学标准物质,基本构成了一个比较有代表性的中国海及大陆架沉积物标准物质系列,为中国海洋国土及专属经济区调查研究工作提供了有力技术支撑.本文简介了这些标准的研制背景、概况,着重评介了这些标准物质的特点,特别说明了该标准物质系列在海洋地质调查与研究中应用及在地质分析技术发展上的意义.     

海相火山—沉积建造区铜,多金属成矿系列及铁—铜型矿床的勘查前景

拟建了海相火山岩地区的铁－铜－硫成矿系列,它包含两个亚系列,即含铜黄铁矿型亚系列和含铜铁矿型亚系列;并充分肯定了铁－铜型矿床的潜在地位与勘查前景,为新一轮矿产资源大调查拓宽了思路,为铜、多金属矿产的勘查扩展了就矿（铁矿、黄铁矿）找矿（铜、铅、锌、金）的有效途径。     

颗石藻与海洋、环境关系之探讨

笔者在20年的研究中相继发现,自中元古代和古生代以来海相钙质超微浮游生物－颗石藻的新属种达180余种,通过对颗石藻在海洋中分布状态与固碳特征的研究,证明颗石藻乃是海洋中重要的基础生产者,它和海洋碳酸盐及相关生物存在着密切的关系,其能借助光合作用,吸收海水中的CO2,而释放出氧气．对减少全球温室效应与保护地球生态环境平衡,有相当重要的贡献。     

Simulations of seasonal variations of sulfur compounds in the remote marine atmosphere

A photochemical box model is used to simulate seasonal variations in concentrations of sulfur compounds at latitude 40° S. It is assumed that the hydroxyl radical (OH) addition reaction to sulfur in the dimethyl sulfide (DMS) molecule is the predominant pathway for methanesulfonic acid (MSA) production, and that the rate constant increases as the air temperature decreases. Concentration of the nitrate radical (NO₃) is a function of the DMS flux, because the reaction of DMS with NO₃ is the most important loss mechanism of NO₃. While the diurnally averaged concentration of OH in winter is a factor of about 8 smaller than in summer, due to the weak photolysis process, the diurnally averaged concentration of NO₃ in winter is a factor of about 4–5 larger than in summer, due to the decrease of DMS flux. Therefore, at middle and high latitudes in winter, atmospheric DMS is mainly oxidized by the reaction with NO₃. The calculated ratio of the MSA to SO₂ production rates is smaller in winter than in summer, and the MSA to non-sea-salt sulfate (nssSO₄ ^2-) molar ratio varies seasonally. This result agrees with data on the seasonal variation of the MSA/nssSO₄ ^2- molar ratio obtained at middle and high latitudes. The calculations indicate that during winter the reaction of DMS with NO₃ is likely to be a more important sink of NO_x (NO+NO₂) than the reaction of NO₂ with OH, and to serve as a significant pathway of the HNO₃ production. If dimethyl sulfoxide (DMSO) is produced through the OH addition reaction and is heterogeneously oxidized in aqueous solutions, half of the nssSO₄ ^2- produced in summer may be through the oxidation process of DMSO. It is necessary to further investigate the oxidation products by the reaction of DMS with OH, and the possibility of the reaction of DMS with NO₃ during winter.     

2009年秋季珠江口咸潮与风场变化的关系

利用珠江口大万山站潮位资料,横栏岛风资料和磨刀门、横门水道咸潮观测资料,采用对比和相关分析等方法,分析2009年秋季珠江口咸潮与潮位、风场变化的关系,1984～2009年秋、冬月份海平面长期变化趋势。结果表明:咸潮的发生均对应着高海面期且风向偏东,而低潮位时期且偏北风有利于补水。月平均海平面变化方面,珠江口与南海呈准同步变化。大万山站1984～2009年9、11和12月的海平面上升率高达5～6mm/月。2009年9、10月的海平面为近30年来的最高值年,11月为第3高值年。     

莫桑比克东部滨海砂矿矿物组成及特征

滨海砂矿是目前全球最大的潜在矿产资源之一。以莫桑比克的滨海砂矿作为研究对象,利用光学显微镜、X射线衍射、扫描电镜、等离子体质谱（ICP-MS）等手段对莫桑比克东部滨海砂矿的矿物组成及特征进行了研究。并用数理统计方法讨论了重砂矿的元素赋存状态及其载体矿物。研究结果表明：（1）砂矿的矿石矿物主要为钛铁矿、金红石和锆石,脉石矿物主要为石英和长石。（2）重砂矿的主要化学组分为Ti和zr;Hf及REE为次要组分;而主要有害元素组分Th和U,其总体含量低,故重砂矿对采选加工和产品利用均无明显环境危害。（3）重砂矿中元素含量与粒度之间呈一定相关性,显示zr、Hf、U、Cr、Ta的载体矿物的粒度相对较细;Ti、Fe、V、Nb的载体矿物的粒度相对较粗。     

COMPARISON OF AEROSOL CHARACTERISTICS OVER MAINLAND OF CHINA AND WESTERN PACIFIC AND ITS LONG-RANGE TRANSPORT

Based on the aerosol data obtained at Shangdianzi regional background monitoring station together withthe air trajectory analysis,the chemical constituents of the aerosol from the different sources are discussed andcompared with the aerosol samples collected over the western Pacific.The results show that the relative massconcentrations of the crustal and pollutant elements in the aerosol collected over the ocean are higher than thosebeing observed at Shangdianzi in particle size above 4.7 μm and below 0.65μm in diameter.The variationsof the enrichment factors of these elements in marine aerosol with particle size are different from those in shang-dianzi's samples.The former enrichment factors are evidently higher than the latter above 1.1 μm in diameter.On the basis of the comparative research,the long-range transport processes of aerosol particles are discussed.     

陵页岩气井新工具的应用与经济评价

涪陵地区页岩层蕴含着丰富的天然气资源,具有较大的开采前景。区块主要目的层为上奥陶统五峰组-下志留统龙马溪组下部页岩气层。上部泥页岩地层井壁稳定性差,地层承压能力低,溶洞发育、易坍塌、易漏失;海相沉积地层流体分布复杂,部分地层岩性变化大,可钻性差,机械钻速较低;采用丛式布井,水平井井眼轨迹复杂,靶前位移大,大井眼定向扭方位困难、托压严重。现场试验使用了旋转导向、扭力冲击器、旋冲马达、水力振荡器等新技术、新工具,大幅度提高机械钻速,缩短钻井周期,取得一定的经济效益。阐述了几种新技术和新工具的工作原理、现场应用情况,并对其经济效果进行了评价。     

Arc Gis在西天山阿吾拉勒东段铁矿资源预测的应用

本文以西天山阿吾拉勒东段海相火山岩型铁矿为例,从研究区的地质背景和已查明的6个海相火山岩型铁矿(点)出发,基于ArcGIS平台,建立空间数据库,结合已知矿(点)地质资料和野外验证分析,建立找矿模型与预测区提取模型,总结本区铁矿的主要控矿因素:①沉积地层;②侵入体;③布格重力异常;次要影响因素:①断层距离;②断层密度,将5个方面的证据图层与铁矿(化)点空间关系合成,采用证据权模型和加权Logistic回归模型进行成矿有利度评价,将研究区划分为6个靶区,结合研究区中主要矿(化)点对各靶区的地质成矿条件进行了探讨,分析了该地区的找矿潜力。     

黔中—渝南石炭纪铝土矿含矿岩系中的海相沉积特征

黔中—渝南地区于紫云运动初期的泥盆纪末已准平原化,在石炭纪铝土矿含矿岩系沉积过程中,含矿岩系下段(铁质-粘土岩段)主要为近海湖泊相,含矿岩系上段(铝质岩段)为近海平原相。在这种大环境前提下,经常会受到海泛与强风暴潮的影响与改造,使得主要是陆相环境沉积形成的铝土矿含矿岩系中,含有少量海相大化石(腕足类)和微体生物化石(疑源类和牙形石);另在下段和上段岩矿层间,时夹海相碳酸盐岩透镜体,具明显海相沉积特征。以上表明,黔中—渝南石炭系铝土矿含矿岩系形成环境具有显著的多样性和复杂性,而非单纯的陆相沉积环境所能概括的。