Origin and Accumulation of Natural Gases in the Upper Paleozoic Strata of the Ordos Basin in Central China

The natural gases in the Upper Paleozoic strata of the Ordos basin are characterized by relatively heavy C isotope of gaseous alkanes with δ 13C1 and δ13C2 values ranging mainly from ?35‰ to ?30‰ and ?27‰ to ?22‰, respectively, high δ13C excursions (round 10) between ethane and methane and predominant methane in hydrocarbon gases with most C1/(C1-C5) ratios in excess of 0.95, suggesting an origin of coal-derived gas. The gases exhibit different carbon isotopic profiles for C1-C4 alkanes with those of the natural gases found in the Lower Paleozoic of this basin, and believed to be originated from Carboniferous-Permian coal measures. The occurrence of regionally pervasive gas accumulation is distinct in the gently southward-dipping Shanbei slope of the central basin. It is noted that molecular and isotopic composition changes of the gases in various gas reservoirs are associated with the thermal maturities of gas source rocks. The abundances and δ13C values of methane generally decline northwards and from the basin center to its margins, and the effects of hydrocarbon migration on compositional modification seem insignificant. However, C isotopes of autogenetic calcites in the vertical and lateral section of reservoirs show a regular variation, and are as a whole depleted upwards and towards basin margins. Combination with gas maturity gradient, the analysis could be considered to be a useful tool for gas migration.     

Mechanism for calcite dissolution and its contribution to development of reservoir porosity and permeability in the Kela 2 gas field,Tarim Basin,China

This study is undertaken to understand how calcite precipitation and dissolution contributes to depth-related changes in porosity and permeability of gas-bearing sandstone reservoirs in the Kela 2 gas field of the Tarim Basin, Northwestern China. Sandstone samples and pore water samples are col-lected from well KL201 in the Tarim Basin. Vertical profiles of porosity, permeability, pore water chem-istry, and the relative volume abundance of calcite/dolomite are constructed from 3600 to 4000 m below the ground surface within major oil and gas reservoir rocks. Porosity and permeability values are in-versely correlated with the calcite abundance, indicating that calcite dissolution and precipitation may be controlling porosity and permeability of the reservoir rocks. Pore water chemistry exhibits a sys-tematic variation from the Na2SO4 type at the shallow depth (3600-3630 m), to the NaHCO3 type at the intermediate depth (3630―3695 m),and to the CaCl2 type at the greater depth (3728―3938 m). The geochemical factors that control the calcite solubility include pH, temperature, pressure, Ca2 concen-tration, the total inorganic carbon concentration (ΣCO2), and the type of pore water. Thermodynamic phase equilibrium and mass conservation laws are applied to calculate the calcite saturation state as a function of a few key parameters. The model calculation illustrates that the calcite solubility is strongly dependent on the chemical composition of pore water, mainly the concentration difference between the total dissolved inorganic carbon and dissolved calcium concentration (i.e., [ΣCO2] -[Ca2 ]). In the Na2SO4 water at the shallow depth, this index is close to 0, pore water is near the calcite solubility. Calcite does not dissolve or precipitate in significant quantities. In the NaHCO3 water at the intermedi-ate depth, this index is greater than 0, and pore water is supersaturated with respect to calcite. Massive calcite precipitation was observed at this depth interval and this intensive cementation is responsible for decreased porosity and permeability. In the CaCl2 water at the greater depth, pore water is un-der-saturated with respect to calcite, resulting in dissolution of calcite cements, as consistent with microscopic dissolution features of the samples from this depth interval. Calcite dissolution results in formation of high secondary porosity and permeability, and is responsible for the superior quality of the reservoir rocks at this depth interval. These results illustrate the importance of pore water chemis-try in controlling carbonate precipitation/dissolution, which in turn controls porosity and permeability of oil and gas reservoir rocks in major sedimentary basins.     

Study of celestite flotation efficiency using sodium dodecyl sulfonate collector: factorial experiment and statistical analysis of data

Flotation tests of synthetic mixtures of celestite (SrSO₄) and calcite (CaCO₃) minerals using sodium dodecyl sulfonate as collector were carried out using a factorial experimental design 2³. The independent experimental variables included celestite grade in the feed (50% and 90% SrSO₄), conditioning pH (6.5 and 9) and sodium silicate depressant concentration (10⁻⁵ and 10⁻³ M). All experiments were performed at a constant collector concentration (10⁻⁴ M) and conditioning time of 15 min. The response variables were recovery and grade of SrSO₄ in the concentrate.The factors that had the greatest effect on the grade and recovery of celestite were the celestite grade in the feed (L) and the depressant concentration (C); also the combination of these factors significantly affected the response variables. The highest celestite yield (96% recovery, 98% grade) was obtained when a 90% of celestite grade in the feed was used.     

方解石和钾长石在模拟蚯蚓肠液中的初始溶解动力学机理及意义

蚯蚓肠道内小分子有机酸与摄入的土壤矿物相互作用,加速矿物溶解。摄入的土壤在蚯蚓肠道内平均停留时间约为12 h,不足以使土壤矿物产生显著的溶解特征,因此这一过程难以在蚯蚓体内进行评估。本研究通过体外实验控制pH值和有机酸浓度,模拟蚯蚓肠道中有机酸对土壤中常见矿物的溶解反应,探讨了方解石和钾长石在蚯蚓肠道环境中的初始溶解动力学。研究发现,矿物在混合有机酸中的溶解速率比在纯水中高一个数量级,说明有机配体和质子促进了矿物溶解。溶解速率及粒度分析表明,方解石(CaCO₃)溶解速率不受溶解过程中粒度变化的影响,而钾长石(KAlSi₃O₈)粒度在溶解期间未出现显著变化。在此基础上,采用初始速率法模拟了钾长石的初始溶解动力学,计算得出的溶解速率表明钾长石在溶解初期主要为表面K~+的释放。使用缩核模型(shrink core model)和Hixson-Crowell模型对方解石溶解过程进行动力学解析,发现方解石的溶解主要受溶液中反应物内扩散的速率影响。这定量描述了两种矿物在有机酸溶液和纯水中的溶解差异。现有研究表明,有机配体和质子协同促...     

The Origin of the Proterozoic Bidjovagge Gold-Copper Deposit, Finnmark, Northern Norway, as Deduced from Rare Earth Element and Nd Isotopic Evidences on Calcites

Abstract: The Bidjovagge gold-copper deposit, northern Norway occurs in the lower Proterozoic Kautokeino greenstone belt, and consists of ten ore bodies in albite felsite, graphite schist and meta-diabase sills, along with a series of syenodiorite dykes. Calcite is one of the most important gangue minerals occurring within the ore veins. The early primary calcite samples from A, C and D ore bodies (copper–rich) show almost flat chondrite-normalised REE curves, and slightly positive Eu anomalies. A Sm-Nd isotope age of 1858 ± 72 Ma (2ρ) has been given based on fifteen primary calcite samples. The Sm-Nd age of calcite is in well agreement with previously published U-Pb davidite age of 1885 ±18 Ma (2ρ) and Sm-Nd davidite age of 1886 ± 88 Ma (2ρ). All these isotopic age data indicate that the gold-copper mineralisation may occur during or slightly after the peak of the Svecokarelian orogeny. Two late primary calcite samples from C and D ore bodies have flat chondrite-normalised LREE curves, positive HREE curves, and negative Eu anomalies. In contrast, most of the early primary calcite samples from B ore body (gold–rich) show an overall negative chondrite-normalised REE slope and negative Eu anomalies. Sm-Nd data on seven primary calcite samples from the B ore body are relatively scattered, and gave an isochrone age of 1809 ± 150 Ma (2ρ), identical to the age of the calcite samples from A, C and D ore bodies. Two late primary calcite samples from the B ore body have almost flat chondrite-normalised REE slope and negative Eu anomalies. REE patterns and eNd (T) values of calcites suggest that the ore fluids for the calcites from the A, C and D ore bodies derived their metals from mafic igneous rocks (diabase sills). For the secondary calcites from the C ore body, their relative high initial Nd (T) values at 1858 Ma imply that much more radiogenic Nd-component were incorporated during calcite crystallisation when another ore fluid emplaced. Combined Nd isotope data and REE geochemical features suggest that the isotopically more evolved source such as albite felsite and syn-genetic high level syenodiorite dykes were probably metal source for these calcites in the B ore body. Three samples of secondary calcite from the B ore body, which obviously deviated from 1809 Ma isochron are easily explained as products of post-ore hydrothermal events.     

Late Quaternary shedding of shallow-marine carbonate along a tropical mixed siliciclastic–carbonate shelf: Great Barrier Reef, Australia

Abstract The north-east Australian margin is the largest modern example of a tropical mixed siliciclastic/carbonate depositional system, with an outer shelf hosting the Great Barrier Reef (GBR) and an inner shelf dominated by fluvially sourced siliciclastic sediment wedges. The long-term interplay between these sediment components and sea level is recorded in the Queensland Trough, a 1–2 km deep N–S elongate basin situated between the GBR platform and the Queensland Plateau. In this paper, 154 samples from 45 surface grabs and six well-dated piston cores were analysed for total carbonate content, carbonate mineralogy and Sr concentration to establish spatial and temporal patterns of carbonate accumulation in the Queensland Trough over the last 300 kyr. Surface carbonate contents are lowest on the inner-shelf (<5%) and in the trough axis (<60%) because of siliciclastic dilution. Carbonate on the shelf is mostly Sr-rich aragonite and high-Mg calcite (HMC), whereas that in the basin is mostly low-Mg calcite. Once normalized to remove the effects of siliciclastic dilution, surface Sr-rich aragonite and HMC abundances decrease linearly to background levels ≈ 100 km seaward of the shelf edge. Core samples show that, over time, normalized aragonite and Sr abundances are greatest during periods of shelf flooding and lowest when sea level drops below the shelf edge. This is consistent with changes in the production of coral and calcareous algae, and the shedding of their debris from the shelf. Interestingly, normalized HMC concentrations on the slope peak during periods of major transgression, perhaps because of maximum off-shelf transport from inter-reef areas or intermediate water dissolution. After accounting for siliciclastic dilution, there are strong similarities in both spatial and temporal patterns of carbonate minerals between slopes and basins of the north-east Australian margin and those of pure carbonate margins such as the Bahamas. A limited set of basic processes, including the formation and breakdown of carbonate on the shelf, the transport of carbonate off the shelf and eustatic sea level, probably controls carbonate accumulation in slope and basin settings of tropical environments, irrespective of proximal siliciclastic sediment sources.     

太平洋中部柱状沉积物中的自生矿物

根据《海洋四号》861—881航次获得的岩心资料,通过对沉积物类型的观察,对其中的几种自生矿物钙十字沸石、蒙脱石、重晶石、微结核、非晶质SiO_2等矿物的成因和与沉积物类型的相关性进行了探讨。     

利用水电站PD16硐方解石研究划分坝区岩溶发育期

本文在分析采集于西南某水电站PDl6硐壁裂缝中不同位置的方解石形成年代以及碳氧同位素的基础上，结合坝区具体的水文地质情况，确定了研究河段岩溶发育的时间及其演化。     

自生绿泥石对储集层质量影响的定量评价:以北部湾盆地涠西南凹陷涠洲组三段为例*

为了定量研究自生绿泥石对储集层质量的影响,在限定控储因素前提下,通过常规岩心分析、扫描电镜、薄片鉴定、激光粒度分析和黏土矿物X衍射等资料,以北部湾盆地涠西南凹陷涠洲12-X油田古近系涠洲组三段碎屑岩储集层为例,探讨了自生绿泥石对石英次生加大、孔隙结构及储集层物性的影响,并提出了综合得分评价法,定量评价自生绿泥石对储集层物性的控制作用。研究结果表明,当溶蚀作用积极意义大于绿泥石沉淀的消极影响时,石英加大和方解石含量较高(7.3%)及自生绿泥石相对含量较低(20%~30%)的细砂“控孔喉”作用,等同于石英加大和方解石含量较低(2.4%)及自生绿泥石含量较高(30%~40%)的细砂,二者的“控孔喉”作用具有互补性。自生绿泥石的“控孔、控渗”作用与碎屑颗粒粒度、分选、胶结物及泥质含量等因素的“控孔、控渗”作用相互制约,存在互补性和差异性,绿泥石相对含量较低的中砂“控孔、控渗”作用等同于绿泥石相对含量较高的细砂(互补性);泥质含量较低的细砂岩中绿泥石“控孔、控渗”作用弱于泥质含量较高的细砂岩(差异性)。总之,在岩相一定的情况下,包膜或衬里状绿泥石与孔渗呈正相关关系,孔隙充填状绿泥石与孔渗呈负相关关系。