Active manipulation of the selective alignment by two laser pulses

This paper solves numerically the full time-dependent Schrõdinger equation based on the rigid rotor model, and proposes a novel strategy to determine the optimal time delay of the two laser pulses to manipulate the molecular selective alignment. The results illustrate that the molecular alignment generated by the first pulse can be suppressed or enhanced selectively, the relative populations of even and odd rotational states in the final rotational wave packet can be manipulated selectively by precisely inserting the peak of the second laser pulse at the time when the slope for the alignment parameter by the first laser locates a local maximum for the even rotational states and a local minimum for the odds, and vice versa. The selective alignment can be further optimised by selecting the intensity ratio of the two laser pulses on the condition that the total laser intensity and pulse duration are kept constant.     

Dissolved organic nitrogen dynamics in the North Sea: A time series analysis (1995–2005)

Dissolved organic nitrogen (DON) dynamics in the North Sea was explored by means of long-term time series of nitrogen parameters from the Dutch national monitoring program. Generally, the data quality was good with little missing data points. Different imputation methods were used to verify the robustness of the patterns against these missing data. No long-term trends in DON concentrations were found over the sampling period (1995–2005). Inter-annual variability in the different time series showed both common and station-specific behavior. The stations could be divided into two regions, based on absolute concentrations and the dominant times scales of variability. Average DON concentrations were 11 μmol l⁻¹ in the coastal region and 5 μmol l⁻¹ in the open sea. Organic fractions of total dissolved nitrogen (TDN) averaged 38 and 71% in the coastal zone and open sea, respectively, but increased over time due to decreasing dissolved inorganic nitrogen (DIN) concentrations. In both regions intra-annual variability dominated over inter-annual variability, but DON variation in the open sea was markedly shifted towards shorter time scales relative to coastal stations. In the coastal zone a consistent seasonal DON cycle existed with high values in spring–summer and low values in autumn–winter. In the open sea seasonality was weak. A marked shift in the seasonality was found at the Dogger Bank, with DON accumulation towards summer and low values in winter prior to 1999, and accumulation in spring and decline throughout summer after 1999. This study clearly shows that DON is a dynamic actor in the North Sea and should be monitored systematically to enable us to understand fully the functioning of this ecosystem.     

Geochemical and Isotopic Techniques Constraints on the Origin, Evolution, and Residence Time of Low-enthalpy Geothermal Water in Western Wugongshan, SE China

Geothermal resources are increasingly gaining attention as a competitive, clean energy source to address the energy crisis and mitigate climate change. The Wugongshan area, situated in the southeast coast geothermal belt of China, is a typical geothermal anomaly and contains abundant medium- and low-temperature geothermal resources. This study employed hydrogeochemical and isotopic techniques to explore the cyclic evolution of geothermal water in the western Wugongshan region, encompassing the recharge origin, water–rock interaction mechanisms, and residence time. The results show that the geothermal water in the western region of Wugongshan is weakly alkaline, with low enthalpy and mineralization levels. The hydrochemistry of geothermal waters is dominated by Na-HCO3 and Na-SO4, while the hydrochemistry types of cold springs are all Na-HCO3. The hydrochemistry types of surface waters and rain waters are Na-HCO3 or Ca-HCO3. The δD and δ18O values reveal that the geothermal waters are recharged by atmospheric precipitation at an altitude between 550.0 and 1218.6 m. Molar ratios of major solutes and isotopic compositions of 87Sr/86Sr underscore the significant role of silicate weathering, dissolution, and cation exchange in controlling geothermal water chemistry. Additionally, geothermal waters experienced varying degrees of mixing with cold water during their ascent. The δ13C values suggest that the primary sources of carbon in the geothermal waters were biogenic and organic. The δ34S value suggests that the sulfates in geothermal water originate from sulfide minerals in the surrounding rock. Age dating using 3H and 14C isotopes suggests that geothermal waters have a residence time exceeding 1 kaBP and undergo a long-distance cycling process.     

地磁Z分量低点时间季节性变化研究

通过小波分析和频谱分析,发现Z分量低点时间的小波变换结果曲线(α=6)明显地随节气而变化;对地磁Z分量低点时间季节性变化进行了初步的比较分析.     

江门市某病害挡土墙的工程治理实践

详细介绍了江门市某病挡土墙的工程治理实践，通过对病害挡土墙的原因分析，提出了合理的整治方案及施工处理措施，达到预期整治效果。     

青藏高原现代降水中dδ^18O／dT的变化

不同时间尺度ｄδ＾１８Ｏ／ｄＴ的天气气候意义是不同的，其数值大小也是不一样的。本根据对青藏高原沱沱河、德令哈、西宁三站大气降水中δ＾１８Ｏ与温度关系的分析，并与具有长序列资料的地区进行比较。初步给出了青藏高原不同时间尺度ｄδ＾１８Ｏ／ｄＴ之间的差异。     

事件层的保存潜力探讨

影响事件层保存潜力的主要因素有 :纯粹的沉积速率、生物成因的混合速率以及机械改造的规模,可以从时间规模 (过渡时间和消除时间 )的角度来考虑事件层保存潜力。基底的机械改造同样对于事件层和正常天气下的沉积物的保存具有重要影响。综合分析影响事件层保存潜力的各种因素表明,在近基的临滨带中、上部及滨外带下部,事件层具有较高的保存潜力,而在近基及远基两端之间的临滨带下部及滨外带上部,事件层保存潜力较低.     

宜川—旬邑地区长6～长8储层流体包裹体特征及意义

宜川—旬邑地区显示油气丰富,但是实际勘探效果不佳,通过宜川-旬邑地区延长组长6~长8储层流体包裹体岩相、均一温度、盐度的研究表明,该区主要发育液烃包裹体和气液烃有机流体包裹体。流体包裹体主要分布在石英次生加大边与石英颗粒裂纹、方解石胶结物和裂缝充填物中;包裹体个体多为5~15μm,均一温度为49~127℃,平均89℃。80%以上样品的含油流体包裹体丰度(GOI)大于或等于1%,其中近40%样品的GOI在5%以上。流体包裹体总体偏向低盐度,包裹体盐度与均一温度间的相关性差。结合延长组成岩作用、热史和埋藏史分析指出,延长组发生过广泛的油气运移与充注事件,充注时间主要在早白垩世早期—早白垩世晚期;油藏具储层边致密、石油边成藏的特点,受后期构造运动的影响,原始封闭体系遭到破坏,在方解石胶结物不甚发育且原生粒间孔隙保存较好的区域,有望获得油气勘探的突破。     

高速铁路大断面黄土隧道二次衬砌施作时机研究

隧道工程二次衬砌施作时机是隧道界普遍关注的问题。依托正在修建的郑州-西安铁路客运专线大断面黄土隧道工程,以围岩及初期支护基本稳定速率作为二次衬砌施作时机判定指标,采用位移断面监测数据回归分析和数值分析相结合,建立基本稳定速率的理论求解方法,从而确定二次衬砌施作时机;同时,选取贺家庄隧道试验段作为工程实例,对高速铁路大断面黄土隧道二次衬砌施作时机进行研究。研究结果表明：当拱顶下沉变形速率值小于0.55 mm/d,边墙水平绝对收敛速率值小于0.11 mm/d时,即可进行二次衬砌施作。此次研究为类似工程的设计和施工提供了参考依据。     

GPS RTK技术用于滑坡动态实时变形监测的研究

为了研究GPS RTK技术用于滑坡动态变形监测的精度和可靠性,本文结合某类滑坡的大型物理模型试验,在滑坡体上布设了若干监测点,并用GPS RTK技术、全站仪三维测量技术和GPS单历元定位技术实时跟踪监测了该滑坡在自然状态下从稳定到产生破坏的全部过程。通过对监测数据的处理和分析,获得了RTK技术用于滑坡变形监测的可靠性和精度等技术参数,即在基准站和流动站同步观测到的卫星数在7颗以上且RTK系统的数据链能够正常工作的情况下,RTK测量的平面和高程精度就能分别控制在15mm和20mm以内。研究结果表明,RTK技术在一定条件下完全可用于滑坡灾害的动态实时变形监测。