盐湖溶液热化学(Ⅳ) Li_2B_4O_7—Li_2SO_4—LiCl—H_2O体系298.15K时稀释热、热容和表观摩尔热焓的研究

用连续滴定量热法测定了四元体系Li_2B_4O_7—Li_2SO_4—LiCl—H_2O及其次级体系Li_2B_4O_7—Li_2SO_4—H_2O和Li_2B_4O_7—LiCl—H_2O 298.15K时的稀释热,并结合Debye-Hückel热焓极限公式研究了该体系的平均表观摩尔热焓。     

电离层赤道异常两日振荡的数值模拟

近20年来,国外学者对电离层赤道异常问题的数值模拟研究未考虑到大气行星波对潮汐发电机电场的调制效应,因而不能解释赤道异常峰值的逐日变化.本文结果表明二日波对F_2区电子浓度的输运有很大影响.这一方法可以推广到赤道异常各种长周期行星波振荡的数值研究. 本文从非定常等离子体连续方程出发,建立包含行星波振荡对E×B漂移的调制效应的方程,并给出数值模拟的方法以及可与实际观测进行比较的结果.文中取二日波漂移振幅为U_p=0 m/s、5m/s、10m/s,而初位相分别为φ=0°、90°共四种情形进行了模拟,结果表明,二日波的调制可使赤道异常的时空分布以及异常峰值产生明显的逐日变化.在所选取的模型中,取U_p=5m/s,φ=0°所得到的f_0F_2t的二日分布特征与观测较吻合.而u_p约5m/s的变化能引起异常峰值f_0F_2约1-2MHz的起伏,而二天之内f_0F_2的二个峰值表现出约2-4MHz的起伏.     

全波震相分析的应用

全波震相分析法是以弹性波传播理论为基础,以现代数字技术为手段,对地震波进行全面综合分析的理论和方法.它既包括对单一分量震波观测记录中的各种震相的识别、确认和分析,又包括对多分量震波记录的合成、分析和图示.全波震相分析法涉及震源、射线路径、初动、走时、振幅、波形、时域和空域的瞬态谱、质点振动矢量等诸多方面,因而能更全面地揭示地震波场与地下介质之间的关系.本文以实例展示在不同领域的研究中全波震相分析的应用情况.全波震相分析法为实现多种波型的联合应用奠定了理论基础,并提供了新的方法.     

利用长周期面波研究华北地区地壳与上地幔结构的横向非均匀性

本文以太行山为界将华北地区分为东西两部分,东部为河淮块体,西部为鄂尔多斯块体.利用最小二乘法,从混合路径基阶瑞利面波群速度频散提取两块体的纯路径频散,并反演其地壳、上地幔的层状结构.所得结表果明,两块体的面波频散和地壳、上地幔结构存在明显差异.东部的河淮块体地壳较薄,地壳内平均速度比西部的鄂尔多斯块体壳内平均速度约低0.13km/s,壳内20km深度左右出现低速层;而西部的块体壳内速度成层递增,未见低速层出现.两块体上地幔顶部速度均偏低,地幔低速层的埋藏深度基本相同.但西部块体地幔低速层厚,且比东部块体地幔低速层的速度约低0.3km/s.     

Time domain solution for multiple scattering and the coda envelopes

This article summarizes work on multiple scattering based on models of media with randomly distributed scatterers. The scatterers are isotropic and statistically uniform. Measuring distance in terms of mean-free pathL _s and time in terms of the mean-free timesL _s/V, whereV is the velocity of scattered waves, we have more convenient dimensionless distance and time. It can be shown that after the dimensionless time equals 0.65 energy contributed from multiple scattering becomes predominant. Thus the later coda reflects the effect of multiple scattering rather than single scattering. Treating the seismic record, including starting and tail parts, as a whole, the diffusion theory predicts that at a dense distribution of scatterers and a small distance between source and receiver, codas reflect mainly intrinsicQ _i. Of course, this conclusion is coincident with the presumption of the diffusion theory,Q _s>Q _i. However, from a new integral equation of multiple scattering, which deals with the scattered waves and primary waves separately, the conclusion is similar but clearer. This article quotes the new expression for coda energy in two-dimensional space. It shows that if the receiver is close to the source, the coda decay reflects only intrinsicQ _i, then as the distance increases, effects of scatteringQ _s, are involved in the decay feature. The theoretical plots of coda decay show that it seems in most cases in the earthQ _i should not be smaller than one tenth ofQ _s.Project Sponsored by the Joint Earthquake Science Foundation of China.     

meso-四-(4-甲氧苯基)卟啉与铅的显色反应及其双波长和导数光谱行为研究

本文研究了meso-四-(4-甲氧苯基)卟啉与铅的高灵敏显色反应及双波长和导数光谱行为。当有Tween-80存在时,在强碱性介质中,于沸水浴上加热32min,显色反应能定量进行。该体系的表现摩尔吸光系数(ε_(466.5))为1.77×10~5,双波长的ε_(466.5/422)为3.16×10~5,四阶导数光谱的有效摩尔响应值为2.67×10~6。此显色体系用于合成样品中痕量Pb的测定,回收率在96.8～98.2％之间。