与碱性岩有关的浅成低温热液型金矿特征与控矿因素——以巴布亚新几内亚波尔盖拉金矿为例

与碱性岩有关的浅成低温热液型金矿在全球特别是环太平成矿带中具有重要意义,波尔盖拉金矿位于新几内亚造山带内较为典型的该类型金矿床。矿床的矿化与碱性的波尔盖拉侵入杂岩体有关,矿化主要发育在岩体与白垩纪Chim组的接触部位,矿化作用分为2期,矿化形态主要为脉状和角砾岩矿化,成矿物质和成矿流体具有明显的岩浆来源的特征。与成矿有关的波尔盖拉杂岩体侵入时代为5．99Ma,与成矿时间一致,并来源于被交代富集型的上地幔,该类碱性岩浆对于金的富集具有重要的意义。通过总结该类矿床的控矿因素和找矿标志为中国企业在该地区寻找同类型金矿提供参考。     

辽宁赛马碱性岩体异性石化学成分特征及其蚀变组合对碱性岩浆-热液演化的指示意义

辽宁赛马碱性岩体早年因产铀矿而闻名,该岩体主要由响岩、霞石正长岩和异霞正长岩组成,其中铀、锆和稀土等元素矿化主要集中于异霞正长岩岩浆阶段。异性石是异霞正长岩中特征的锆-稀土矿物,主要分为两期,晚期异性石表现出更加富集Nb、REE等高场强元素的特点。早期异性石经历了一系列的热液蚀变,根据蚀变强弱程度,蚀变矿物组合可分为:(1)异性石+钠锆石+霓石±钠沸石;(2)异性石+钠锆石+锆石+钠沸石±霓石;(3)异性石假晶,假晶主要由残余异性石+钠锆石+锆石+钠沸石+霓石+钾长石+铈硅磷灰石组成。相比于岩浆锆石,蚀变组合中次生锆石具有富Ca、Al、Fe的特点,与异性石本身化学成分和流体性质密切相关。通过对异性石及其蚀变组合的精细矿物学研究,我们得知假晶的形成可能是异性石"溶解-再沉淀"的结果,致使假晶形成的流体至少包括:(1)占主导的富Na(±K)、Al、F的自交代流体;(2)少量晚期富Ca流体。假晶中次生锆石和铈硅磷灰石的结晶说明了Zr和REE等高场强元素的热液活动性,自交代碱性流体和富Ca流体在此过程中起到"搬运"和"提纯"的作用,这对认识碱性岩稀有、稀土成矿机制具有重要的指示意义。     

Geochemisty and tectonic setting of igneous rocks in the Glenrock Station area,N.S.W.

In the Upper Murray Valley, Victoria, Late Silurian, high‐Si igneous rocks, which are closely associated with alkalic, basaltic dykes, were emplaced at high crustal levels following the peak of the Benambran Orogeny, which deformed and metamorphosed the Wagga Zone in Late Ordovician‐Early Silurian times. These rocks, which are informally termed ‘the Upper Murray high‐Si magmatic suite’, include leucogranites, rhyolite dykes and flows, and ash‐flow tuffs characterised by the following features. They are transitional from mildly peraluminous to mildly metaluminous; they represent relatively anhydrous magmas, in which halides were important volatile constituents; they have high Si, total alkalies, Rb, Th, U, Nb, Sn and heavy rare earth elements; and they are relatively repleted in Mg, Ca, Sr, Eu, V, Cr and Ni. In these respects and in their post‐orogenic setting and close association with alkalic basalts, they resemble many post‐orogenic granitoids from elsewhere. Such granitoids appear to have formed as partial melts during crustal extension following major episodes of deformation and high‐Si magmatism. A residual granulitic crust, from which an earlier generation of granitoid magmas had been extracted, is argued to be the source rock‐type for these post‐orogenic magmas. Tectonic extension, affecting such a crust, was accompanied by deep fracturing and basaltic vol‐canism. Mantle‐derived, CO₂‐ and halide‐rich fluids moved into the residual crust, causing widespread metasomatism, and emplacement of basaltic magma caused temperatures to rise until melting took place and a second group of magmas was produced. This model explains most aspects of the trace and major element chemistry of post‐orogenic, high‐Si igneous rocks and, for the Upper Murray high‐Si suite it also provides an explanation for variations in trace elements and isotopic characteristics. Other processes, such as crystal fractionation, magma mixing, thermogravi‐tational diffusion, and separation and loss of a volatile phase, provide explanations for variations within individual units of the suite, but they do not explain overall variations or the highly fractionated nature of the suite.     

古里雅冰帽8米浅冰芯的化学成分组成特征及其来源

对古里雅冰帽８ｍ浅冰芯的８０个雪冰样品化学分析结果表明，化学成分主要来自陆源物质，陆源冰芯样品叶弱碱性，明显不同于一般的大气降水及南北极冰雪样品。     

三江地区高吉碱性岩体的岩石化学特征

三江地区的碱性岩有其独特的地质、岩石学与岩石化学特征；这些特征所记录的信息，不仅提供了高吉碱性岩区别于邻区及其它地方同类碱性岩的证据，而且也给出了识别碱性岩的标志与判定其所处的板块构造位置。     

沉水植物黑藻对上覆水中各形态磷浓度的影响

室内模拟研究了沉水植物黑藻对上覆水中不同形态磷浓度的影响及其季节性变化,并从沉水植物生长、间隙水和碱性磷酸酶活性(APA)三方面进行了讨论,进一步揭示磷在浅水湖泊水-沉积物界面的交换机理。结果表明,在本研究条件下,上覆水中各形态磷以溶解性总磷(DTP)为主,其他形态磷浓度变异较大,黑藻降低了上覆水中总磷(TP)、溶解性活性磷(SRP)和DTP浓度,也降低了DTP和SRP占总磷的比例,从而使颗粒态总磷(PP)和溶解性有机磷(DOP)占总磷比例升高。黑藻主要通过吸收上覆水中的磷和抑止沉积物、上覆水中APA使上覆水中各形态磷浓度保持较低水平,其中对SRP和DTP浓度的影响更明显。上覆水中各形态磷浓度呈现明显的季节性变化。在7～8月,TP、SRP和DTP浓度呈下降趋势,并在8月达到最低值;9～10月间有所升高,但仍然维持在较低水平,不同采样时间存在波动。     

Geochemical approach to magmatic evolution of Mt. Erciyes stratovolcano Central Anatolia, Turkey

Erciyes stratovolcano, culminating at 3917 m, is located in the Cappadocian region of central Anatolia. During its evolution, this Quaternary volcano produced pyroclastic deposits and lava flows. The great majority of these products are calc-alkaline in character and they constitute Kocdag and Erciyes sequences by repeated activities. Alkaline activity is mainly observed in the first stages of Kocdag and approximately first-middle stages of Erciyes sequences. Generally, Kocdag and Erciyes stages terminate by pyroclastic activities. The composition of lavas ranges from basalt to rhyolite (48.4–70.5 wt.% SiO₂). Calc-alkaline rocks are represented mostly by andesites and dacites. Some compositional differences between alkaline basaltic, basaltic and andesitic rocks were found; while the composition of dacites remain unchanged. All these volcanics are generally enriched in LIL and HFS elements relative to the orogenic values except Rb, Ba, Nb depleted alkaline basalt. ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd isotopic composition of the volcanics range between 0.703344–0.703964, 0.512920–0.512780 for alkaline basalts and change between 0.704322–0.705088, 0.512731–0.512630 for alkaline basaltic rocks whereas calc-alkaline rocks have relatively high Sr and Nd isotopic ratios (0.703434–0.705468, 0.512942–0.512600). Low Rb, Ba, Nb content with high Zr/Nb, low Ba/Nb, La/Yb ratio and low Sr isotopic composition suggest an depleted source component, while high Ba, Rb, Nb content with high La/Yb, Ba/Nb, low Zr/Nb and low ⁸⁷Sr/⁸⁶Sr ratios indicate an OIB-like mantle source for the generation of Erciyes alkaline magma. These elemental and ratio variations also indicate that the different mantle sources have undergone different degree of partial melting episodes. The depletion in Ba, Rb, Nb content may be explained by the removal of these elements from the source by slab-derived fluids which were released from pre-collisional subduction, modified the asthenospheric mantle. The chemically different mantle sources interacted with crustal materials to produce calc-alkaline magma. The Ba/Nb increase of calc-alkaline samples indicates the increasing input of crustal components to Erciyes volcanics. Sr and Nd isotopic compositions and elevated LIL and HFS element content imply that calc-alkaline magma may be derived from mixing of an OIB-like mantle melts with a subduction-modified asthenospheric mantle and involvement of crustal materials in intraplate environments.     

金鱼藻(Ceratophyllum demersum)调控浮游植物捕获磷与生长的策略

水体浮游植物具有捕获利用磷的能力以及沉水植物能够显著抑制水体中藻类生长已得到国内外广泛共识,但相应的潜在机制尚缺乏深入了解.本研究选取金鱼藻(Ceratophyllum demersum)为研究对象,基于室内模拟实验,探讨了沉水植物调控浮游植物捕获磷与过度生长的机制.结果显示,尽管未种植金鱼藻的对照组上覆水中总磷、总溶解态磷和可溶性活性磷的平均浓度均显著高于种植金鱼藻的实验组(约4倍),但是两个系统中这3种磷浓度随时间的变化趋势均符合S形的对数曲线.实验组藻类密度、有效光量子产量、总碱性磷酸酶活性(TAPA)以及细颗粒碱性磷酸酶活性(细颗粒APA)也远低于对照组.此外,对照组中粗颗粒碱性磷酸酶活性(粗颗粒APA)占TAPA的44.7%,显著高于细颗粒APA.结构方程模型结果表明,对照组水体藻类密度对TAPA具有直接的正向作用,而金鱼藻的生长显著弱化了不同形态磷与APA、藻类密度、细菌动力以及光量子产量之间的相互作用.这说明沉水植物对水体浮游植物生长的调控具有多种策略.     

水热条件下利用微波加热从粉煤灰合成沸石研究

着重选用NaOH水溶液为反应前驱物, 通过改变反应温度、NaOH浓度与合成时间等参数, 在水热条件下利用微波加热直接对粉煤灰进行晶化, 合成得到了浊沸石、菱沸石、NaP1沸石3种沸石.粉煤灰转化为沸石率约15%~40%.研究表明: (1) 反应体系在15min左右即有合成沸石产生, 30min左右合成沸石转化率达到最佳; (2) 为保证沸石晶核生成和晶体的生长, 反应体系的溶液/粉煤灰比不应低于2.5; (3) 在溶液/粉煤灰比为2.5时, 应控制加热时间在30min左右.