Soluble organic compounds in fog and cloud droplets: what have we learned over the past few years?

We have recently set up a new procedure for characterising the water soluble organic compounds (WSOC) in fog water, for which information is still rather limited. Fog samples collected during the 1998–1999 fall–winter season in the Po Valley (Italy) were analysed following this procedure, which allows a quantitative determination of three main classes of organic compounds (neutral species, mono- and di-carboxylic acids, polycarboxylic acids), together accounting for ca. 85% of the total WSOC. This procedure also provides information on the main chemical characteristics of these three classes of compounds (functional groups, aliphatic vs. aromatic character, etc.). The enhanced chemical knowledge on fog/cloud chemical composition opens new scenarios as far as chemical and microphysical processes in clouds and fogs are concerned.     

均匀土-箱基-结构相互作用体系的计算分析

采用通用有限元程序ANSYS，针对捱动台试验中的均匀土-箱基-结构试验进行了三维有限元分析，计算中土体的本构模型采用等效线性模型，利用面-面接触单元考虑土体与基础交界面的状态非线性。计算表明，基础底面和土体发生滑移，基础侧面和土体之间发生了滑移和脱离，上部结构柱顶加速度反应主要由基础转动引起的摆动分量组成，通过与试验结果的对照研究，二者得出的规律基本一致，验证了采用的计算模型与分析方法的合理性，为进一步计算研究和实际工程应用奠定了基础。     

Seismic analysis of base-isolated liquid storage tanks using the BE–FE–BE coupling technique

A three-dimensional soil–structure–liquid interaction problem is numerically simulated in order to analyze the dynamic behavior of a base-isolated liquid storage tank subjected to seismic ground motion. A dynamic analysis of a liquid storage tank is carried out using a hybrid formulation, which combines the finite shell elements for structures and the boundary elements for liquid and soil. The system is composed of three parts: the liquid–structure interaction part, the soil–foundation interaction part, and the base-isolation part. In the liquid–structure interaction part, the tank structure is modeled using the finite elements and the liquid is modeled using the internal boundary elements, which satisfy the free surface boundary condition. In the soil–foundation interaction part, the foundation is modeled using the finite elements and the half-space soil media are modeled using the external boundary elements, which satisfy the radiation condition in the infinite domain. Finally, above two parts are connected with the base-isolation system to solve the system's behavior. Numerical examples are presented to demonstrate the accuracy of the developed method, and an earthquake response analysis is carried out to demonstrate the applicability of the developed technique. The properties of a real LNG tank located in the west coast of Korea are used. The effects of the ground and the base-isolation system on the behavior of the tank are analyzed.     

液化场地桩-土-桥梁结构动力相互作用振动台试验研究进展

本文在全面归纳与总结液化场地桩－土－桥梁结构动力相互作用振动台试验及与之相关领域的国内外研究进展基础上，直接针对我国桥梁工程中的主要震害问题，提出在我国开展液化场地桩－土－桥梁结构动力相互作用振动台试验研究的必要性，并阐述作者对液化场地桩－土－张桥梁结构动力相互作用振动台试验中若干问题的认识。     

考虑轴向变形、双轴弯曲耦合效应的钢筋混凝土柱的弹塑性分析

在实际地震作用下，高层，特别是高宽比较大的高层结构中，由于倾覆力矩的作用、柱子、特别是外边柱所受轴力的变化将不可忽略。轴向变形与双轴弯曲的耦合作用，将是柱子塑性变形的显著特征。基于材料本构关系的“纤维模型”，能较精确地反映轴向变形，双轴弯曲三者之间的耦合作用。一组钢筋混凝土柱子双轴压弯的计算结果与试验结果的比较，证明了“纤维模型”的有效性和精确性。     

金山金矿热液蚀变粘土矿物特征及水-岩反应环境研究

粘土矿物是流体作用过程中水—岩反应的产物，因此其特征反映了流体活动的特征和水-岩反应的环境。金山金矿蚀变粘土矿物主要由伊利石和绿泥石组成，其中，蚀变糜棱岩中的伊利石含量大于绿泥石含量；而蚀变超糜棱岩中的绿泥石含量大于伊利石含量。蚀变糜棱岩中伊利石的多型为2M1，超糜棱岩中为2M1和1M。金山金矿蚀变绿泥石的成份分析结果表明其为富铁绿泥石，由蠕绿泥石、铁镁绿泥石和密绿泥石组成，绿泥石中Fe、Mg质组分不仅来自围岩，而且也有一部分来自流体。利用地质温度计计算绿泥石的形成温度为206-258℃，流体的f(O2)为10^29.56～10^-31.48。本文认为金山金矿热液蚀变为酸性蚀变，其环境为还原环境，流体作用的水／岩比较高；在水—岩反应过程中，流体中的Fe、Mg、Si为带出组分。粘土矿物的形成机制为溶解—迁移—沉淀。     

Gneiss-Water Interaction and Water Evolution During the Early Stages of Dissolution Experiments at Room Temperature

Gneiss-distilled water interaction at room temperature was investigated with batch-reactors to study water-rock reaction and geochemical evolution of the aqueous phase with time. The ion concentrations in water were controlled not only by the dissolution of primary minerals, but also by the precipitation of secondary minerals. The decreasing fraction sizes of gneiss could favor dissolution and precipitation simultaneously. Ca^2 and K^ were the major cations, and HCO3^- was the major anion in water. All the ions except Ca^2 increased in concentration with time. The Ca^2 release from the rock to the aqueous phase was initially much faster than the release of K^ , Na^2 and Mg^2 . But after about 5 - 24 hours, the Ca^2 concentrations in water decreased very slowly with time and became relatively stable. During the experiment, the water varied from the Ca-( K)-HCO3-type water to the K-Ca-HCO3-type water, and then to the K-(Ca, Na)-HCO3-type water. The water-gneiss interaction was dominated by the dissolution of Kfeldspar in the solution. The remaining secondary minerals were mainly kaolinite, illite and K (Mg) -mica.     

桩承载力时效对桩土相互作用及沉降的影响分析

对软土中两根47 m长灌注桩分别在成桩28 d和1 750 d后进行了承载力试验，其极限承载力提高幅度达到30％左右。分析了单桩承载力随时间提高(称为时效)的机理，提出了单桩承载力时效对桩筏基础桩土相互作用影响的分析方法，并结合工程实例进行了分析。     

秦岭显生宙地幔组成及其演化

通过对秦岭造山带及扬子克拉通北缘显生宙时期 3个含地幔捕虏体的煌斑岩、钾镁煌斑岩、碱性玄武岩以及 11个不含捕虏体的辉石岩、辉长岩、玄武岩出露点的岩石地球化学对比研究 ,揭示出研究区地幔演化经历了自古生代的OIB亏损地幔到中生代的高度富集地幔再到中生代末期 -新生代的OIB MORB的亏损地幔的两次明显变更。制约这种变更的主要因素是熔融岩浆时源区发生的层圈相互作用类型。鉴于大陆岩石圈软流层体系的特征 ,有必要划分出岩石圈 /软流层相互作用带(过渡带 ) ,它是大陆岩浆作用的重要源区。