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21.
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研究pH和Ca(Ⅱ)对砷酸根在海水与NaCl介质中对水合氧化物和粘土矿物上交换吸附的影响:(1)在酸性条件下和海水及NaCl介质中,砷酸根在针铁矿上的交换率E(%)—pH曲线呈平顶峰型、在δ-MnO呈峰型、在粘土上分别呈双峰型和肩峰型。这是砷酸根存在多种形式与固体表面发生离子/配位子交换以及介质中阴离子竞争交换吸附共同作用的结果。(2)在碱性条件下的海水介质中,砷酸根与水合氧化物和粘土矿物的E(%)—pH曲线都呈V型,这是因为生成了具有一定结构的液—固界面三元络合物之故。(3)在NaCl介质中,Ca加入起促进作用,再次证明液—固界面三元络合物生成机理与V型曲线的内在关系 相似文献
23.
沉积物对磷酸盐的吸附与释放 总被引:3,自引:0,他引:3
本实验研究黄河口水文站沉积物对黄河水磷的吸附释放过程和东海111号站位沉积物对海水磷的吸附释放过程。并摸拟黄河沉积物在海水中磷的吸附释放过程。结果表明:底沉积物对磷的吸附相当迅速,无论是河泥还是海泥在24h内均能达到吸附平衡。吸附量与沉积物的量和水中原有磷的浓度有关,在不同的pH条件下,沉积物对磷的吸附是有显著差别的 相似文献
24.
采用新极谱技术(1.5次微分)的阳极溶出伏安滴定方法测定天然海水的铜络合容量和条件稳定常数。对测试条件、EDTA回收率和有关问题进行了探讨。青岛近岸水样的九次平行测定表明,铜的表现络合容量为3.01×10~(-7)mol/dm~3,条件稳定常数为7.34×10~7,相对标准偏差分别为9.2%和13.8%。 相似文献
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26.
Distribution of dissolved species and suspended particulate copper in an intertidal ecosystem affected by copper mine tailings in Northern Chile 总被引:1,自引:0,他引:1
The coastline near Chañaral in Northern Chile is one of the most highly Cu-contaminated zones in the world due to discharges from mining activities for more than 60 years. The speciation of Cu has been studied to determine the importance of organic complexation in highly contaminated areas, and to assess the likely physiological impacts of Cu on marine organisms. Dissolved Cu concentrations of up to 500 nM were measured, completely saturating organic ligands and leading to free Cu2+ concentrations in excess of 10− 8 M. These values are higher than those reported in any other marine environment, and because they occur over an extensive area, provide a unique opportunity to study the effects of Cu on marine ecosystems and to see how Cu behaves when its speciation is predominantly inorganic. We found strong gradients in free Cu2+ between Chañaral and adjacent areas with lower Cu, where speciation is dominated by organic complexation. There is also a significant increase in the partitioning of Cu onto suspended particles in the contaminated areas, consistent with previous studies that showed that organic ligands stabilize Cu in the dissolved phase, whilst “excess” Cu is rapidly scavenged. Those high dissolved Cu concentrations persist in spite of solid phase partitioning and advective processes along this open-ocean coastline, suggesting that Cu inputs into the system are still very large. Measurements were made using anodic stripping voltammetry with a thin mercury film coated with Nafion, which previous workers have shown can mitigate ambiguity in the data arising from inadvertent reduction of organic complexes. Our findings suggest that this is a useful methodology for contaminated systems. 相似文献
27.
1 .IntroductionThepenetratingbucketandboxfoundationisanewtypeofstructure ,whichhasbeenappliedinmanyengineeringfields .Inviewofthehighconstructioncostandtheformidableconstructibilityofoff shoreplatformswithpiledfoundations ,Baerheimetal.(1 990 )proposedtheconc… 相似文献
28.
The method has been established to calculate the environmental capacity (ECo),surplus environment capacity (SECo) of water with respect to marine petroleum hydrocarbons associated with oil (PHAOs) and the self-purification capacity (SPCo) of main self-purification process to PHAOs in the Jiaozhou Bay, China, according to the dynamic model for distribution of marine PHAOs among multiphase environments. The variation of concentration of PHAOs in the Jiaozhou Bay is well simulated by the dynamic model. Based on the model.the ECo, SECo of water with respect to PHAOs in the Jiaozhou Bay were calculated during the last 10 years under the first-class and second-class quality standard requirement, according to SPCoof main self-purification process to PHAOs. The results show that about 200 tons of PHAOs could be discharged into the Jiaozhou Bay for maintaining the first class seawater quality standard, and about 600 tons of PHAOs for the second class seawater quality standard later. 相似文献
29.
某港口堆场地基上部5.0m系吹填而成,地表下18m范围均属软土,经真空预压初级加固后地基承载力仅在80—90kPa,局部区域上部淤泥土层土性指标较差,含水量大于50%,地基承载力不足60kPa。为了使地基达到230kPa的承载要求,设计采用深层搅拌法加固超软弱地基。通过现场成桩工艺试验和检测表明,桩身水泥土强度在90d龄期时大于1.80MPa,单桩承载力标准值大于150kN,以φ600桩径、桩长13.5m、置换率为0.308和φ500桩径、桩长13.5m、置换率为0.267两种方案布置的复合地基承载力标准值均超过了230kPa的设计要求。试验结果表明,深层搅拌法在港口超软弱地基土应用只要施工工艺适当,完全可以使地基承载力提高2—3.5倍以土,从而节省大量的工程投资。 相似文献
30.
This paper first presents the molecule design and synthesis of crown-link type alkyd resin,and its enrichment behaviour for potassium ion in low concentration solution and sea water.On the basis of some theory concepts of Host-Guest chemistry developed in recent years,we have designed and synthesized a new polymer enrichment agent of crow-link resin for potassiumion,i.e.,polymacrocyclic ether bislactone of diethylene glycolpyromyllitic acid(briefly called crown-link type alkyd resin or PBL resin).The yield was about 97.4%,almost quantitatively. 相似文献