中国对虾(Penaeus chinensis)卵子激活过程的研究

许多动物的成熟卵子的激活都是由受精引起的,精子的刺激引起卵子的皮层反应及减数分裂的完成[1].而对虾的成熟卵子的激活可由海水引起,而无需受精[2～9].在对锐脊单肢虾(Sicyonia ingentis)卵子激活研究中发现,其成熟卵子无论受精与否,在接触海水以后具有相同的激活过程,受精卵和未受精卵的皮层反应及减数分裂的完成没有区别,但未受精卵不能进行正常的卵裂[7].     

南极GRV 98003和其它3个铁陨石的化学组成及分类

用仪器中子活化测定了从南极回收的GRV98003铁陨石和乌珠穆沁铁陨石Cr,Co,Ni,Cu,Ga,Ge,As,Sb,W,Re,Ir,Pt及Au的浓度。根据化学组成,重新对这两个未分群的铁陨石进行了分类工作,其中将GRV98003铁陨石划分为IAB群,乌珠穆沁铁陨石划分为与IAB群相关的单独铁陨石。GRV98003铁陨石的元素丰度模式、元素对相关性(如NiAu,CoAu,AsAu,WAu,CuAu,SbAu)等与NWA468铁陨石(IAB)相似,但前者具有明显的难熔亲铁元素(Re,Ir)和中等挥发性元素(Ga,Ge)的贫化。此外,本文还对南丹铁陨石(IIICD)和邕宁铁陨石(IA)的化学群重新进行了讨论,提出将前者划分为IAB复合群的主群,而将后者划分为与IAB复合群相关的单独铁陨石的新观点。     

Properties and organic activation of ocean clay in the East Pacific

In order to make use of ocean clay reasonably and excavate its potential applications the properties of ocean clay in Chinese investigating area of the East Pacific have been tested with the chemical analysis, XRFS, ICP/MAS, granulometry and SSA, etc. The results show that the clay sediments of this area are rich in clay minerals, fine granularity, bigger SSA, bigger water absorbability and lower ion changing ability etc. To improve the adaptability of ocean clay and macromolecule materials, using the dry milling method with silane, aluminate, stearic acid coupling agents etc the properties of ocean clay are improved. The effect has been evaluated by testing the water absorbing of the modified ocean clay and their dispersing in paraffin liquid. The result is that KH550 is better than any other active reagents, and the best activation technics is that 1.5% (volume) of KH550 quantity, 20min of milling time. The DTA, XRD, SEM and IR analyses and SSA testing show that the organic activation can not change the mineral structure but can densify the structure of clay, and activation mechanism is chemical covered mainly and chemical combined secondly.     

土壤类型及组分对热活化过硫酸盐氧化降解土壤中挥发性氯代烃的影响

为了探究高级氧化技术对土壤中有机氯代烃的氧化降解作用,为ISCO（in situ chemical oxidation）技术体系提供重要的理论依据和数据支撑,考察了热活化过硫酸盐（persulfate,PS）氧化降解不同类型土壤（砂类土壤、黏土类土壤）中挥发性氯代烃污染物（三氯乙烯（TCE）、三氯乙烷（TCA）、顺式-1,2-二氯乙烯（cis-1,2-DCE）、1,2-二氯乙烷（1,2-DCA））的效能;同时,通过硫酸盐与土壤相互作用过程研究,探究了不同土壤介质中有机质和无机组分在过硫酸盐消耗中所占比例。结果表明：在50℃时,热活化过硫酸盐可有效降解土壤中1,2-DCA、cis-1,2-DCE、TCA和TCE,砂类土壤介质中4种氯代烃降解效果依次为25%、89%、5%和61%,黏土类土壤介质中4种氯代烃降解效果依次为35%、86%、8%和63%;4种氯代烃的降解效果从高到低顺序依次为cis-1,2-DCE、TCE、1,2-DCA、TCA,砂类土壤中的氯代烃总体降解效果优于黏土类土壤中氯代烃的降解效果。另外,土壤中过硫酸盐氧化降解氯代烃反应研究发现,砂类和黏土类土壤介质组分中有机质消耗率分别为81.3%和72.6%,铁元素消耗率分别为80.5%和38.6%,表明土壤介质组分与过硫酸盐发生了氧化还原反应,从而导致过硫酸盐自身的大量消耗。由此可知,土壤介质中的有机质、铁元素等矿物质均参与过硫酸盐的消耗过程,且土壤有机质、铁元素与氯代烃之间在消耗过硫酸盐反应上存在竞争关系,土壤组分过多地消耗了过硫酸盐,导致了氯代烃的氧化降解效率较低。因此,针对实际有机氯代烃污染场地,采用过硫酸盐氧化技术进行修复时,过硫酸盐的实际投加量要远高于化学计量值,需充分考虑到土壤组分对过硫酸盐自身的消耗作用。     

论韧性剪切带研究及其地质意义

系统研究韧性剪切带变形岩在天然强剪切应力作用条件下常量元素迁移机制及活化转移的应力排序、微量元素迁移的动力控制、稀土元素配分变化和变形矿物晶体化学变异的应力制约等构成了当代韧性剪切带研究的前沿课题,也是当前糜棱岩岩石地球化学研究难点和精华所在。其研究成果将对动力成岩（成矿）机理的认识有重要的突破,具有重要的理论意义和潜在应用价值。对韧性剪切带及其变形岩石的研究现状和研究意义进行系统的综述,提出了未来韧性剪切带及其糜棱岩的研究方向和目标: ①系统研究糜棱岩中主要造岩矿物组合及其变形特征,计算剪切变形岩石的应力—应变参数,搞清韧性剪切带所处的应力应变环境;②系统研究韧性剪切带岩石在天然分强剪切应力作用条件下常量元素迁移机制及活化转移的应力排序问题;③系统研究剪切变形作用过程中岩石化学组成的微量和稀土元素变化,讨论强变形条件下岩石中微量元素活化和迁移规律,深入探讨微量元素迁移的动力控制,包括稀土元素配分变化的应力制约以及应变矿物晶格化学变化行为及其对其寄主的变形岩石元素（组分）在应变过程中迁移变化的制约和影响;④从理论上探讨天然强剪切应变条件下岩石中组分活化、转移与应力（应变）的因果联系,为深入探讨韧性剪切带动力成岩（成矿）作用提供理论的科学依据,为探讨中、下地壳中韧性剪切带的形成和演化提供科学依据（如韧性剪切带金的富集）,同时为韧性剪切变形作用条件下成岩、成矿地球化学作用提供理论和实验依据;⑤现代分析技术如激光同位素原位分析以及激光ICP MASS分析技术对研究变形域内的岩石（矿物）的元素和同位素的活化迁移规律,对深刻揭示糜棱岩化过程中的元素活化迁移机制提供更高质量的地球化学证据具有重要的作用。     

库布齐沙漠南缘沙丘固定与活化过程中的形态演变

以1998-2014年5期库布齐沙漠南缘的遥感影像为主要数据源,结合野外调查分析了沙丘固定与活化过程中的形态演变,探讨了区域风况和降水等气象要素对沙丘固定与活化及形态演变的影响。结果表明：研究区沙丘随降水量的年际波动经历了固定-活化-再固定3个阶段。监测初期的片状流动沙丘演变为大型抛物线形沙丘并得以固定,固定的抛物线形沙丘以发育风蚀坑形式活化,进而形成多个抛物线形沙丘,最后这些沙丘又被植被固定,沙丘形态趋于更加复杂。但在此过程中,风的作用并不显著.研究区抛物线形沙丘既可起源于新月形沙丘或片状流沙,也可由风蚀坑发育而成,其中植被作为沙丘的重要组成部分,起着重要作用。同时发现在抛物线形沙丘移动过程中,当背风坡发育滑落面时,沙丘的移动最快。     

A vortex-tube model of eddies in the inertial range

Abstract

A vortex-tube geometry of the cascade of energy to small-scale eddies, in the inertial range of fully-developed turbulence, is proposed. The model is a special case of the beta model of Frisch, Sulem and Nelkin (1978). We require that the cascade conserve the principal invariants of inviscid, incompressible flow, namely volume, topological knottedness, circulation, and, at discrete times marking the termination of steps in the cascade, energy. The process terminates in a finite time, as in any beta model, leaving behind a self-similar network of “inactive” tubes. We associate a self-similar scaling dimension D with the structure, equal to the Hausdorff dimension of the set of “active” tubes at the termination of the cascade. Because circulation Λ plays a key role in the analysis of the cascade, we refer to these vortex-tube geometries as “gamma models”. The viewpoint throughout is entirely deterministic.

We describe two examples of gamma models. In the ring geometry, an eddy is a vortex ring, and the cascade produces “rings upon rings”, so we allow cutting and fusing of tubes while conserving total helicity. In the preferred helical model, no cutting is needed, and the cascade produces an infinite progression of braided “coils upon coils”. We suggest that latter geometry as a candidate for the topology of a singularity of the inviscid limit of a Navier-Stokes flow, when modeled by discrete vortex tubes.

A crucial ingredient of a gamma model, not explicitly present in a beta model, is the possibility of “splitting” a vortex tube into sub-tubes carrying smaller circulation. We suggest a dynamical basis for this process, as an instability of tubes whose cores violate the Rayleigh criterion.

The parameters describing a gamma model are not uniquely determined by our study, but there is a “simplest” helical gamma model, involving minimal splitting and distortion of tubes. The dimension D of the structure is 13/5, with a scale factor Λ = 2^?5/4. This value of D agrees with that suggested by Hentschel and Procaccia (1982), by analogy with established results for certain branched polymers.     

山东烟台环境介质中重金属元素富集特征及与酸化土壤的关系

利用山东省烟台市生态地球化学调查及相关专题研究所取得的分析测试数据,通过高灵敏度的识别系统和多参数地球化学评价体系的建立,揭示了在重金属污染区内酸化的土壤环境中Cd、Hg、Pb、As等重金属元素活化迁移的地球化学机制、影响因素,以及浅层地下水和玉米等主要粮食作物籽实中重金属超标的原因及生态危害。与全国土壤基准值和背景值对比,研究区内Cd、Cr、Ni、Pb等元素的基准值相对偏高,Cd、Cr、Pb、Cu、Ni元素的背景值相对较高。As、Cd、Cr、Ni、Hg、Pb等存在于Ⅲ级及Ⅲ类以上土壤,是主要致污因子。典型金矿污染区内浅层地下水和玉米籽实中均检出超标重金属元素,影响浅层地下水环境质量的主要指标是Pb。达到Ⅲ类及以上水质标准的采样点数占研究区总采样点数的3.47%;玉米中的Cd含量相对较高。表层酸性、弱酸性土壤占土壤总面积的55.29%,土壤酸化趋势明显。随着土壤酸化程度的加深和范围扩大,导致土壤耕作层可给性营养元素的损失及某些毒性元素(Cd、Pb等)的释出和活化,提高了土壤中主要污染因子Cd、Hg、Ni、Pb、As等重金属的活化迁移能力;富含有机质的土壤中有利于对Cu、Zn、Pb、Cd的吸收,固重金属元素于土壤中,降低了土壤重金属污染的环境风险水平。研究结果为土壤修复、降低土壤重金属毒性提供了重要的科学依据。     

Provisional Elemental Values for IAEA‐Sewage Sludge by Instrumental Neutron Activation Analysis

The International Atomic Energy Agency (IAEA) organised a proficiency test (PT), IAEA‐CU‐2010‐02, for the determination of elements in sewage sludge. The PT sample was analysed by semi‐absolute standardless k₀‐instrumental neutron activation analysis (k₀‐INAA). Results for seven elements (As, Co, Cr, Fe, Hg, Se, Zn) were submitted to the IAEA by our laboratory. All of our results were scored ‘acceptable’ by the ‘result evaluation criteria’ adopted by the IAEA. The same analytical methodology produced quantitative results for twenty‐six additional elements. In total, thirty‐six elements were determined with uncertainty varying from 4 to 11%. This paper presents the provisional mass fractions of twenty‐six additional elements (Ag, Al, Br, Ca, Ce, Cl, Dy, Eu, Ga, Hf, I, K, La, Mg, Mn, Na, Rb, Sb, Sc, Sm, Ta, Tb, Th, V, U, W) not reported by the IAEA. The analytical methodology was discussed with important sources of spectral, nuclear and fission‐product interferences. It was shown that the important components of uncertainties were the k₀ factor, Q₀ factor, detector efficiency, mass and counting statistics. The methodology was validated by analysing the IAEA‐S7 reference material.