盐湖相低熟油脂肪酸的组成与分布特征

对泌阳凹陷碱性盐湖相、舞阳凹陷盐湖相、襄城凹陷膏盐湖相、南阳凹陷淡水湖相低熟油脂肪酸组成和分布特征进行了分析与研究。结果表明这些不同盐湖相的低熟原油的脂肪酸为丰度不同的饱和正构酸、不饱和正构酸、少量异构酸、类异戊二烯酸及脂肪酸乙酯系列化合物。脂肪酸的组成和分布反映了原始有机质的来源。     

汤原断陷断裂构造特征及其对油气成藏的控制作用

汤原断陷是典型的受断裂控制的陆相盆地。盆地内断裂极为发育。断裂的发育主要有 Ｎ Ｅ向和 Ｎ Ｗ － Ｎ Ｗ Ｗ 方向,断裂的分布具有东西分带,南北分群的特征。按断裂的成因类型可划分出７ 种类型。断裂对油气生成、运聚及成藏的控制作用主要表现在：基底大断裂控制了烃源岩的展布,主干断裂控制了圈闭的形成和分布,断裂为油气运移提供了通道作用,断裂的封闭性为油气的聚集成藏提供了遮挡条件。     

测井资料在碳酸盐岩洞—裂缝型储层产能评价中的应用

介绍了一种基于测井资料来预测双孔结构碳酸盐岩储层产能的新方法。首先根据碳酸盐岩剖面中双孔结构储层的地质和测井特征,提取与储层产能密切相关的多个测井和地质参数,考虑到这些参数与产能的非线性相关关系以及产能数据的变化特点,采用BP神经网络技术建立其储层产能的预测模型,由此处理了轮南地区的多口井测井资料。所预测的储层段产能与试油产能较为一致,效果良好。     

Improved approaches to ecotoxicity testing of petroleum products

Crude oils produced in the North West shelf of Western Australia are highly volatile, a characteristic not shared by most of the Northern Hemisphere crude oils on which internationally accepted toxicity test protocols were developed. Because of this volatility and some other factors, the LC50 and EC50 values obtained from acute toxicity tests will be significantly affected by the changes of toxicant concentration in test solutions during the period of exposure. To address these issues all steps of a standard protocol for crude oil toxicity testing have been revised. A systematic study has been performed on factors which affect petroleum hydrocarbon solubilisation in aqueous systems during test solution preparations. The influence of mixing time, agitation energy and volume/interface ratio on a hydrocarbon concentration in a water-soluble fraction (WSF) was studied for heavy, medium and light crude oils. A study of the sensitivity of marine unicellular algae to WSF of crude oils was conducted with Isochrysis sp., Nannochloropsis-like sp. and Nitzchia closterium. Total concentrations of hydrocarbons dissolved in test solutions were estimated by UV-spectrometry and GC/FID chemical analyses. When the toxicant concentration decreased during the exposure period, the EC50 values derived from initial or final concentrations either underestimate or overestimate toxicity, respectively. Therefore, weighted average concentrations (WAC) calculated for the whole test period were recommended for expressing hydrocarbon concentrations in test solutions of crude oils. Toxicity indices calculated from WAC of total hydrocarbons for different crude oils can be compared regardless of the rates of hydrocarbon loss.     

Hydrocarbon degraders from tropical marine environments

Analysis of 20 samples of marine mud and water around Mumbai resulted in the isolation of 17 bacteria and yeasts all of which were able to degrade more than 10% of the supplied crude oil. The yeasts strains were important degraders of the aliphatic fraction of crude. All the isolated yeasts belonged to the genus Candida. Using biochemical tests these were identified as Candida parapsilosis, C. albicans, C. guilliermondii, Yarrowia lipolytica, C. tropicalis and C. intermedia. Y. lipolytica was the best degrader utilizing 78% of the aliphatic fraction of Bombay High crude oil. None of these isolates degraded the aromatic or ashphaltene fractions. All the isolates required aeration, nitrogen and phosphate supplementation for optimal degradation. Four out of the six yeasts are human pathogens.     

荧光分析法在油气化探中的应用

荧光光谱法是分析芳烃的灵敏、快速、高效的方法,通过样品的同步荧光光谱和三维荧光光谱特征,可以进行油气属性的判断;区别油气信息和煤信息,区分油气信息和泥浆污染信息,提高钻井预测的准确度。某些情况下,可以用简单、便捷的同步荧光光谱取代三维荧光光谱分析,达到事半功倍的效果。     

临清坳陷德南洼陷含油气性的流体包裹体分析

应用流体包裹体观察和激光拉曼探针等微观技术对临清坳陷东北部的德南洼陷流体包裹体特征及成分、压力等物理化学条件的研究表明,研究区共有6种类型的包裹体:单相盐水包裹体、富液相包裹体、富气相包裹体、含液态CO2三相包裹体、富液态烃有机包裹体、富气态烃有机包裹体,其中富液态烃有机包裹体的均一温度为100～140°C的较多.包裹体的液相成分主要为H2O和Cl-,气相成分主要为CO2、CH4以及微量的C2H6等,包裹体成分研究结果表明在古近系和新近系中主要为未成熟-低成熟的液态烃流体活动;在古生界及部分上部层段中主要为成熟、高成熟的气态烃流体活动.根据盐水溶液包裹体的均一温度和冷冻温度计算得出研究区的流体压力为10～95 MPa,其中,在烃类流体大量排出运移时期经历过压力由突破到释放的过程;初步评价了区内的油气有利远景区.     

利用铀油关系寻找可地浸砂岩型铀矿

可地浸砂岩型铀矿多数赋存于产油气盆地,并与油气关系十分密切。本文通过对可地浸砂岩型铀矿的成因分类、与油气藏的关系及与气藏异同点的分析对比,总结了几种典型油气藏上方的放射性异常模式。以二连盆地可地浸砂岩型铀矿与油气藏的客观相伴关系为例,在鄂尔多斯盆地进行了应用试验,取得了一定效果。因此,利用铀油相伴关系,在油气勘探中注意寻找铀矿(化)床,在铀矿(化)床周围的有利构造部位加强油气勘探是十分重要的。     

古亚洲与特提斯交汇带盆地群油气资源潜力

古亚洲与特提斯构造交汇带盆地群发育石炭系、侏罗系(中下统)、白垩系(下统)等多套烃源岩,具有厚度大、分布广、有机质丰度高的特点.石炭系烃源岩有机质进入成熟-过成熟热演化阶段,侏罗系烃源岩有机质已进入大量生油阶段,白垩系烃源岩也处于生油高峰,具有良好的油气成藏的物质基础;区内储集岩发育,石炭-二叠系储集层以低孔隙度、低渗透率为特征,石炭系储集层主要为潮坪-泻湖相沉积的碎屑岩,二叠系储集层为一套河流相粗碎屑岩;侏罗-白垩系储集层物性相对较好,以中孔、中渗,或中孔、高渗为特征,为以河流-三角洲沉积砂体;在石炭-二叠系、中新生代地层中均见到了不同级别的油气显示或获工业油流.存在3种不同的生储盖组合,即①自生自储式组合.②下生上储的间隔式组合.③潜山型组合.预测油气资源量36.85亿t,目前已发现的油气储量仅为1亿t,具较大的勘探潜力.     

利用核磁共振技术对丘陵油田低渗储层可动油的研究

为了定量评价储层可动油饱和度及渗流能力,应用核磁共振技术对丘陵油田40块岩心的可动油饱和度进行了定量测试.研究表明,丘陵油田低渗透储层可动油饱和度值的分布范围是4.8%~56.7%,平均值为33.4%.可动油饱和度高低与岩心孔隙度、渗透率及驱油效率呈正相关关系.各类储层可动油饱和度差异较大,储层沉积微相及物性决定了可动油饱和度和渗流能力的大小.