消油剂处理120#燃料油对海水青鳉(Oryzias melastigma)胚胎抗氧化酶活性影响的研究

以海水青鳉(Oryzias melastigma)胚胎为研究对象,比较了120#燃料油分散液(water-accommodated fractions,WAFs)与乳化液(biologically enhanced water-accommodated fractions,BE-WAFs)的急性毒性效应,并研究了不同浓度(40、100、250 mg/L)下WAFs、BE-WAFs对胚胎内超氧化物歧化酶(SOD)、过氧化氢酶(CAT)、谷胱甘肽硫转移酶(GST)活性的影响。结果表明:在受到石油烃的氧化胁迫后,海水青鳉胚胎内3种抗氧化酶活性变化明显。随着石油烃浓度的升高和暴露时间的延长,3种酶表现出程度不同的诱导效应和抑制效应。其中受石油烃污染影响最为明显的为SOD酶;而GST酶则对消油剂单独暴露表现较为敏感。实验证明,海水青鳉体内SOD酶活性对石油烃污染反应最为敏感,适合作为监测石油烃污染程度的生物标志物。     

Oil shale resources in China and their utilization

The unconventional oil and gas resources presented in oil shales have meant these potential sources of hydrocarbons,which has become a research focus. China contains abundant oil shale resources,ranking fourth in the world,with ca. 7 254. 48 × 10~8 t within 24 provinces,including 48 basins and 81 oil shale deposits. About 48% of the total oil shale resources are concentrated in the eastern resource region,with a further 22% in the central resource region. 65% of the total quantity of oil shale resources is present at depths of 0-500 m,with 17% of the total resources being defined as high-quality oil shales yielding more than 10% oil by weight.Chinese oil shale resources are generally hosted by Mesozoic sediments that account for 78% of the total resources. In terms of the geographical distribution of these resources,some 45% are located in plain regions,and different oil shale basins have various characteristics. The oil shale resources in China represent a highly prospective future source of hydrocarbons. These resources having potential use not only in power generation and oil refining but also in agriculture,metal and chemical productions,and environmental protection.     

榆树林油田扶杨油层沉积岩地球化学特征及地质意义

三肇凹陷榆树林油田扶杨油层中泥岩、粉砂岩和砂岩样品主量元素和微量元素地球化学分析表明,多数主量元素含量中等,与全球平均大陆上地壳(UCC)相比,Fe_2O_3、MgO、CaO、Na_2O含量较低,而TiO_2、Al_2O_3、K_2O、MnO含量均略高;样品中的相容元素(V、Cr、Co、Ni等)含量均低于澳大利亚后太古宙页岩(PAAS)和UCC;稀土元素总量为102×10~(-6)~276×10~(-6),平均为188×10~(-6),与PAAS表现出相似的球粒陨石标准化曲线,显示了相似的物源和构造背景。元素间的相关性分析显示大部分元素与SiO_2负相关而与Al_2O_3正相关,说明大部分元素受到黏土矿物吸附作用的影响,石英与长石矿物对这些元素表现出一定的稀释效应。根据主元素物源判别方程图和Th-Hf-Co图投影及La/Hf、(Gd/Yb)N值,扶杨油层物源主要来自后太古宙长英质火山岩,可能卷入了部分再循环沉积岩。通过一系列的构造背景判别图解分析,表明扶杨油层沉积时以大陆岛弧环境为主。在对油层组进行了纵向古气候分析后,认为FI油层组沉积时处于一个构造活动强、干旱的环境中,所形成的沉积岩储层物性更好,是油气勘探开发的重点层位。     

3500m岩心钻探装备在油气井勘查中的示范应用

3500 m岩心钻探装备（YDX—6型钻机）是我国自主研发的深部矿产资源勘查技术装备,采用N级口径钻深可达3500 m,其最大特点是采用长油缸钻进和起下钻。本文主要介绍了该钻机在油气井勘查中生产试验情况,同时对矿区地层、钻孔结构、钻进过程、钻进效果、遇到的主要问题及解决办法等进行了介绍。     

三江盆地前进坳陷油气地质调查新进展

随着东北大型含油气沉积盆地油气勘探难度越来越大,老油田开发程度已进入中后期,亟需新的油气区接替。三江盆地作为松辽盆地外围7个一级远景盆地之一,具有较大的油气勘探潜力。最近在三江盆地前进坳陷开展了一系列油气地质调查工作,在中生界泥页岩、晚古生界暗色泥岩地层及硅质岩生烃潜力方面取得了新的进展与认识,对评价该区油气资源潜力、进行下一步油气勘探工作具有重要意义。     

新疆三塘湖盆地上石炭统近源凝灰岩致密油藏形成条件

三塘湖盆地上石炭统烃源岩是火山喷发环境下形成的,烃源岩往往与厚度不等的凝灰岩交互出现,但凝灰岩致密储层的厚度和物性差异较大,源储关系较复杂,因而近源凝灰岩致密油藏的形成需要特定的条件。为了认识三塘湖盆地上石炭统近源凝灰岩致密油藏的形成条件,以典型致密油藏M36为例,综合运用岩心、薄片、测录井、地球化学测试等资料,对成藏要素进行解剖,建立上石炭统凝灰岩致密储层及烃源岩有效性的评价标准,并总结出近源致密油藏成藏模式。结果表明,储层孔隙度大于5%、对应渗透率大于0.07×10-3μm2的凝灰岩可以作为有效储层;烃源岩有机碳含量在4.0%以上,对应生烃潜量大于10%,且Ro大于0.8%的高炭泥岩、暗色泥岩为优质烃源岩;较好的储层、优质的烃源岩和互层型源储配置关系是近源凝灰岩致密油藏的形成条件。     

中亚陆间区南带上古生界构造和油气远景(代序)

安加拉-阿尔丹和华北-塔里木两大克拉通之间地壳相对活动性的地区,地质界多称为中亚陆间区,其南带大部分在中国境内。近年来,中国开始把其上古生界作为油气新区、新领域。多数人认为,其在晚古生代已形成过渡型地壳区,其中有许多地块已逐步拼合,在其上发育裂谷型沉积地质体,未受到区域变质,若干实体变形微弱并被上覆层掩盖而得到保存。源于上古生界的油气既可赋存在其内,也可运聚于中生界或基岩内,在其西段已发现了大中型油气田群。但其整体地质研究程度偏低,仍有许多重大区域地质、油气地质问题存在歧见。针对其近年来的进展、存在的问题和油气远景评价作了概括性的评论。     

基于无机成因的油气勘查概念模型(BRCF)

基于超基性岩蛇纹石化成油理论,根据构造条件和沉积条件,提出了石油勘查概念模型——"BRCF"模型:B代表侵入地壳超基性岩;R代表储油层;C代表盖层;F代表深大断裂。运用该模型分析了波斯湾地区油气田和中国典型油气田油气成藏规律,并预测了中国大陆油气勘查靶区。     

Results of magnetotelluric surveyon reference geophysical profiles of the Karaton-Sarkamys block in Kazakhstan

A digital geoelectric model of the Karaton-Sarkamys block located in the southern (Kazakhstan) part of the Caspian Depression has been developed on the basis of processing and interpretation of magnetotelluric sounding data. Geoelectric sections and structural maps of geoelectric layers have been constructed. It has been shown that magnetotelluric sounding combined with seismic and GIS data can be efficiently used to obtain additional information on the lithologic and reservoir properties of petroleum plays.     

Phenanthrene biomarkers in the organic matter of Precambrian and Phanerozoic deposits and in the oils of the Siberian Platform

The composition and distribution of phenanthrenes (polyaromatic compounds) have been studied in chloroform extracts from dispersed organic matter (OM) of clayey, siliceous, carbonate, and terrigenous rocks of different ages and facies and from some oils of the Siberian Platform. Phenanthrenes have been analyzed by gas chromatography-mass spectrometry. High contents of 1,7,8-trimethylphenanthrene and 1,1,7,8-tetramethyl-1,2,3,4-tetrahydrophenanthrene are present in the OM of Vendian and Cambrian carbonate-shale deposits and in ancient oils of the Nepa-Botuobiya and Anabar anteclises. The OM of Permian continental deposits and oils of the Vilyui syneclise is dominated by 1-methyl-7-isopropylphenanthrene (retene). A triangular diagram for identification of the types of original OM of rocks and classification of genetically related oils has been constructed based on the assessment of phenanthrene biomarker distribution. Putative pathways of the formation of phenanthrene biomarkers are discussed.