Column Amounts of ClONO2, HCl, HNO3, and HF from Ground-Based FTIR Measurements Made Near Kiruna, Sweden, in Late Winter 1994

During SESAME phase I ground-based FTIR measurements were performed atEsrange near Kiruna, Sweden, from 28 January to 26 March 1994. Zenith columnamounts of ClONO₂, HCl, HF, HNO₃,O₃, N₂O, CH₄, and CFC-12 werederived from solar absorption spectra. Time series of ClONO₂and HCl indicate a chlorine activation at the end of January and around 1March. On 1 March a very low amount of HCl of 2.09times; 10¹⁵molec. cm^-2 was detected, probably caused by a second chlorineactivation phase starting from an already decreased amount of HCl. The ratioof column amounts of HCl to ClONO₂ decreased inside the vortexfrom about 1 in January to 0.4 in late March compared to values of about 2outside the vortex. Although the Arctic stratosphere was rather warm in winter1993/94 and PSCs occurred seldom, chlorine partitioning into its reservoirspecies HCl and ClONO₂ changed during that winter andClONO₂ is the major chlorine reservoir at the end of thewinter as in cold winters like 1991/92 and 1994/95.     

火焰原子吸收法间接测定磷矿中氯

火焰原子吸收法间接测定磷矿中氯达刘生１云南个旧市化肥厂中心化验室个旧６６１４１１目前磷矿中Ｃｌ－含量的测定多采用浊度法、氯离子选择电极法及离子色谱法。本文采用火焰原子吸收法来间接测定磷矿中Ｃｌ－，即在试样溶液中加入定量的Ａｇ＋，试样中Ｃｌ－与Ａｇ＋生...     

铋的原子吸收光谱分析进展

文章对１９８５年以来用原子吸收光谱法测定Ｂｉ的情况进行了综述，着重介绍了用氢化物发生法、石墨炉法和火焰法测Ｂｉ时，为了提高灵敏度所采用的各种氢化物发生装置及根据不同试样所使用的各种分离富集手段。主要参考文献１０１篇。     

电吸附找矿方法寻找隐伏金矿床的研究

电吸附找矿方法是指对采集的样品在室内特别装置中通电，并用吸附体吸附试样中电运移元素，通过这些元素所形成的异常来发现矿体的一种方法，该方法是依据野外地电提取方法的理论发展起来的，具有设备简单，成本低，工效效率高，工作条件及质量容易控制等优点。     

伊利石层间钾释放的远红外光谱研究

本文介绍了新近研究层间交换的远红外方法，并用该方法研究了金砂伊早石层间交换的性质，随着温度的升高，伊利石的远红外谱段从１０８ｃｍ＾－１向低波数方向偏移，３００Ｃ时为１０７ｃｍ＾－１，５００℃时为１０００ｃｍ＾－１，７００℃时为９８ｃｍ＾－１，同时，伊利石的释钾程度也伴随着增加，远红外谱同释放钾的能力有一清楚对比，因此可以用远红外方法预言伊利石释钾的能力，最后，利用量子化学计算的ＰＭ３方法首次从理论     

Surface chemical analysis in coal preparation research: complementary information from XPS and ToF-SIMS

The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface.     

碳酸盐岩的反射光谱特征的研究及应用

在室内对新疆塔里木盆地西北缘柯坪地区碳酸盐岩的反射光谱进行了测量。分析结果表明：碳酸盐岩的特征吸收谱带位于２３００～２３５０ｎｍ，随着碳酸盐岩中Ｍｇ２＋含量的增加，其特征吸收谱带的中心波长位置具有向短波长方向移动的特点；同时，随着碳酸盐岩中碳酸盐矿物含量的增加，其特征吸收谱带的深度（Ｄ）也有增大的趋势，并且岩石的平均反射率（Ｒ）也随着增高。根据这些特征可以判定碳酸盐岩的岩石类型及碳酸盐矿物的相对含量     

An experimental study on seismic responses of multifunctional vibration‐absorption reinforced concrete megaframe structures

Two models are tested on a shake‐table. One of the models is a normal reinforced concrete megaframe structure and the other is a multifunctional vibration‐absorption reinforced concrete megaframe structure in which the laminated rubber bearings are placed between the major frame and the minor frames. Two earthquake motions (the El Centro wave and the Taft wave) are used during the test. This paper presents the dynamic characteristic, the seismic responses and the failure mechanism of these two models under varying peak acceleration levels for each of the earthquake motions. The test results demonstrate that the aseismic behavior of a multifunctional vibration‐absorption reinforced concrete megaframe structure is much better than that of a normal reinforced concrete megaframe structure. Copyright © 2003 John Wiley & Sons, Ltd.     

A comparative study on the illite crystallinity and the clay mineral reflectance spectral index for subdividing the very low-grade metamorphic belt along the Lizhou-Hekou geological section in the Youjiang sedimentary basin, Guangxi, China

To examine the application potential of hyperspectral remote sensing techniques in classifying very low-grade metamorphic belts, the composition of clay minerals and the cyrstallinity of illite from mudstones were measured using XRD and VIS-SWIR (400-2500 nm) reflectance spectroscopy. Based on the illite cyrstallinity, Kubler Index (KI), the Early Triassic LuoLou Group and the Middle Triassic lower Baifeng Formation were classified as the lower Epizone with KI△2θ° ranging from 0.22 to 0.25, the upper Baifeng Formation as upper anchizone with KI△2θ°ranging from 0.26 to 0.33, and the Hekou Formation as lower anchizone with KI△2θ° ranging from 0.38 to 0.40. According to a KI△2θ° value of 0.43, it is possible that there may exist a local diagenetic zone in the upper strata. The illite cyrstallinity Kubler index and the metamorphic grade increase from the bottom to the top of the stratigraphic sequence. The metamorphic grade boundaries nearly match the stratigraphic boundaries, indicating a burial metamorphism nature for the stratigraphic sequence. From the bottom to the top of the sequence, the spectral absorption band center of clay minerals from fresh rocks is around 2200 nm. The absorption band centers change towards shorter wavelengths: the Luolou Group being at 2220 nm, the Baifeng Formation at 2217-2213 nm, the lower member of the Hekou Formation at 2214-2206 nm, and the upper member of the Hekou Formation at 2205-2197 nm. The spectral absorption band center of illite shows the same change pattern. These results indicate that very low-grade metamorphic belts can be subdivided using spectral indices of clay minerals, which are measured by using field portable spectroradiometers. However, it may not work well with satellite and airborne sensors.     

石墨炉原子吸收分光光度法测定土壤样品中痕量镉

研究了土壤样品中痕量镉的石墨炉原子吸收分光光度法测定最佳条件以及磷酸二氢铵与硝酸镁作基体改进剂对测定镉的基体改进效应，并比较了两种试样分解体系。方法检出限为0.01pg／L，精密度(RSD，n=8)为3．29％-7．69％，经国家一级标准物质分析验证，结果与标准值符合。