Parameterization of the Absorption of the H_2O Continuum,CO_2,O_2,and Other Trace Gases in the Fu-Liou Solar Radiation Program

The absorption properties of the water vapor continuum and a number of weak bands for H2O, O2, CO2, CO, N2O, CH4, and O3 in the solar spectrum are incorporated into the Fu-Liou radiation parameterization program by using the correlated k-distribution method (CKD) for the sorting of absorption lines. The overlap absorption of the H2O lines and the H2O continuum (2500-14500 cm-1) are treated by taking the two gases as a single-mixture gas in transmittance calculations. Furthermore, in order to optimize the computation efforts, CO2 and CH4 in the spectral region 2850-5250 cm-1 are taken as a new single-mixture gas as well. For overlap involving other absorption lines in the Fu-Liou spectral bands, the authors adopt the multiplication rule for transmittance computations under which the absorption spectra for two gases are assumed to be uncorrelated. Compared to the line-by-line (LBL) computation, it is shown that the errors in fluxes introduced by these two approaches within the context of the CKD method are small and less than 0.48% for the H2O line and continuum in the 2500-14500 cm-1 solar spectral region, -1% for H2O (line) H2O (continuum) CO2 CH4 in the spectral region 2850-5250 cm-1, and -1.5% for H2O (line) H2O (continuum) O2 in the 7700-14500 cm-1 spectral region. Analysis also demonstrates that the multiplication rule over a spectral interval as wide as 6800 cm-1 can produce acceptable errors with a maximum percentage value of about 2% in reference to the LBL calculation. Addition of the preceding gases increases the absorption of solar radiation under all sky conditions. For clear sky, the increase in instantaneous solar absorption is about 9%-13% (~12 W m~2) among which the H2O continuum produces the largest increase, while the contributions from O2 and CO2 rank second and third, respectively. In cloudy sky, the addition of absorption amounts to about 6-9 W m-2. The new, improved program with the incorporation of the preceding gases produces a smaller solar absorption in clouds due to the reduced solar flux reaching the cloud top.     

IAP AGCM中短波辐射方案的改进研究II·短波辐射方案的改进

在Version 2的基础上,对短波辐射方案进行进一步的改进:引入了新增非灰体气体吸收效应、冰晶粒子形状效应和尺度效应以及云的不均匀性效应(称为Version 3)。数值模拟试验结果表明:Version 3能更好地模拟出全球冬、夏季的降水场、海平面气压场及地表气温场的主要分布特征,并且能相当准确地反映出这几个场的季节性变化特征。Version 3对这3个场的模拟能力明显优于原版本(Version 1)。此外,它对东亚地区的季风降雨具有很好的模拟能力,能较好地反映东亚区域降水的季节性变化。可见,Version 3为进一步研究云-辐射相互作用提供了很好的模式基础。本工作还清楚地表明,模式的进一步发展必须进行对相关物理过程中各个因子的更精确刻画,只有这样,模式才能得到更好的模拟能力。     

The Effects of Line-Wing Cutoff in LBL Integration on Radiation Calculations

There are three basic methods in radiative transfer calculations, i.e., line-by-line (LBL) integration, correlated k-distribution method, and band model. The LBL integration is the most accurate of all, in which, there are two quadrature algorithms named in this paper as integration by lines and by sampling "points when calculating atmospheric transmittance in the considered wavenumber region. Because the LBL integration is the most expensive of all, it is necessary and important to save calculation time but increase calculation speed when it is put into use in the daily operation in atmospheric remote sensing and atmospheric sounding. A simplified LBL method is given in this paper on the basis of integration by lines, which increases computational speed greatly with keeping the same accuracy. Then, we discuss the effects of different cutoff schemes on atmospheric absorption coefficient, transmittance, and cooling rate under both of accurate and simplified LBL methods in detail. There are four cutoff schemes described in this paper, i.e., CUTOFFs 1, 2, 3, and 4. It is shown by this numerical study that the way to cut off spectral line-wing has a great effect on the accuracy and speed of radiative calculations. The relative errors of the calculated absorption coefficients for CUTOFF 2 are the largest under different pressures, while for CUTOFF 1, they are less than 2% at most of sampling points and for CUTOFFs 3 or 4, they are ahnost less than 5% in the calculated spectral region, however, the calculation time is reduced greatly. We find in this study that the transmittance in the lower atmosphere is not sensitive to different LBL methods and different cutoff schemes. Whereas for the higher atmosphere, the differences of transmittance results between CUTOFF 2 and each of other three cutoff schemes are the biggest of all no matter for the accurate LBL or for the simplified LBL integrations. By comparison, the best and optimized cutoff scheme is given in this paper finally.     

The NO2 absorption spectrum. III: The 200–300 nm region at ambient temperature

Absorption cross-section measurements of NO₂ performed in our laboratory have been extended to the 200–300 nm region at ambient temperature. Low pressures have been used, limiting the effects of the dimer N₂O₄ which has an absorption cross-section from one to two orders of magnitude larger than that of NO₂ in this region. The results have been compared to those of previous authors and are now available for atmospheric purposes at 0.01 nm intervals.Unité de Recherche Associée au CNRS.     

A comparative study on the illite crystallinity and the clay mineral reflectance spectral index for subdividing the very low-grade metamorphic belt along the Lizhou-Hekou geological section in the Youjiang sedimentary basin, Guangxi, China

To examine the application potential of hyperspectral remote sensing techniques in classifying very low-grade metamorphic belts, the composition of clay minerals and the cyrstallinity of illite from mudstones were measured using XRD and VIS-SWIR (400-2500 nm) reflectance spectroscopy. Based on the illite cyrstallinity, Kubler Index (KI), the Early Triassic LuoLou Group and the Middle Triassic lower Baifeng Formation were classified as the lower Epizone with KI△2θ° ranging from 0.22 to 0.25, the upper Baifeng Formation as upper anchizone with KI△2θ°ranging from 0.26 to 0.33, and the Hekou Formation as lower anchizone with KI△2θ° ranging from 0.38 to 0.40. According to a KI△2θ° value of 0.43, it is possible that there may exist a local diagenetic zone in the upper strata. The illite cyrstallinity Kubler index and the metamorphic grade increase from the bottom to the top of the stratigraphic sequence. The metamorphic grade boundaries nearly match the stratigraphic boundaries, indicating a burial metamorphism nature for the stratigraphic sequence. From the bottom to the top of the sequence, the spectral absorption band center of clay minerals from fresh rocks is around 2200 nm. The absorption band centers change towards shorter wavelengths: the Luolou Group being at 2220 nm, the Baifeng Formation at 2217-2213 nm, the lower member of the Hekou Formation at 2214-2206 nm, and the upper member of the Hekou Formation at 2205-2197 nm. The spectral absorption band center of illite shows the same change pattern. These results indicate that very low-grade metamorphic belts can be subdivided using spectral indices of clay minerals, which are measured by using field portable spectroradiometers. However, it may not work well with satellite and airborne sensors.     

An experimental study on seismic responses of multifunctional vibration‐absorption reinforced concrete megaframe structures

Two models are tested on a shake‐table. One of the models is a normal reinforced concrete megaframe structure and the other is a multifunctional vibration‐absorption reinforced concrete megaframe structure in which the laminated rubber bearings are placed between the major frame and the minor frames. Two earthquake motions (the El Centro wave and the Taft wave) are used during the test. This paper presents the dynamic characteristic, the seismic responses and the failure mechanism of these two models under varying peak acceleration levels for each of the earthquake motions. The test results demonstrate that the aseismic behavior of a multifunctional vibration‐absorption reinforced concrete megaframe structure is much better than that of a normal reinforced concrete megaframe structure. Copyright © 2003 John Wiley & Sons, Ltd.     

A new occurrence of retrogressed eclogite from the Sanbagawa belt of southwest Japan and its significance

The present paper reports, for the first time, the occurrence of an omphacite‐bearing mafic schist from the Asemi‐gawa region of the Sanbagawa belt (southwest Japan). The mafic schist occurs as thin layers within pelitic schist of the albite–biotite zone. Omphacite in the mafic schist only occurs as inclusions in garnet, and albite is the major Na phase in the matrix, suggesting that the mafic schist represents highly retrogressed eclogite. Garnet grains in the sample show prograde‐type compositional zoning with no textural or compositional break, and contain mineral inclusions of omphacite, quartz, glaucophane, barroisite/hornblende, epidote and titanite. In addition to the petrographic observations, Raman spectroscopy and focused ion beam system–transmission electron microscope analyses were used for identification of omphacite in the sample. The omphacite in the sample shows a strong Raman peak at 678 cm^?1, and concomitant Raman peaks are all consistent with those of the reference omphacite Raman spectrum. The selected area electron diffraction pattern of the omphacite is compatible with the common P2/n omphacite structure. Quartz inclusions in the mafic schist preserve high residual pressure values of Δω₁ > 8.5 cm^?1, corresponding to the eclogite facies conditions. The combination of Raman geothermobarometries and garnet–clinopyroxene geothermometry gives peak pressure–temperature (P–T) conditions of 1.7–2.0 GPa and 440–540 °C for the mafic schist. The peak P–T values are comparable to those of the schistose eclogitic rocks in other Sanbagawa eclogite units of Shikoku. These findings along with previous age constraints suggest that most of the Sanbagawa schistose eclogites and associated metasedimentary rocks share similar simple P–T histories along the Late Cretaceous subduction zone.     

Combining two filter paper‐based analytical methods to monitor temporal variations in the geochemical properties of fluvial suspended particulate matter

Many of the commonly used analytical techniques for assessing the properties of fluvial suspended particulate matter (SPM) are neither cost effective nor time efficient, making them prohibitive to long‐term high‐resolution monitoring. We present an in‐depth methodology utilizing two types of spectroscopy which, when combined with automatic water samplers, can generate accurate, high‐temporal resolution SPM geochemistry data, inexpensively and semi‐destructively, directly from sediment covered filter papers. A combined X‐ray fluorescence spectroscopy and diffuse reflectance infrared Fourier transform spectroscopy approach is developed to estimate concentrations for a range of elements (Al, Ca, Ce, Fe, K, Mg, Mn, Na, P, Si, Ti) and compounds (organic carbon, Al_dithionate, Al_oxalate, Fe_dithionate, and Fe_oxalate) within SPM trapped on quartz fibre filters at masses as low as 3 mg. Calibration models with small prediction errors are derived, along with mass correction factor models to account for variations in retained SPM mass. Spectral pre‐processing methods are shown to enhance the reproducibility of results for some compounds, and the importance of filter paper selection and homogeneous sample preparation in minimizing spectral interference is emphasized. The geochemical signal from sediment covered filter papers is demonstrated to be time stable enabling samples to be stored for several weeks prior to analysis. Example results obtained during a heavy precipitation event in October 2012 demonstrate the methodology presented here has considerable potential to be utilized for high‐resolution monitoring of SPM geochemistry under a range of in‐stream hydrological conditions. Copyright © 2013 John Wiley & Sons, Ltd.     

夏季新安江水库(千岛湖)颗粒物吸收光谱特征分析

通过对2013年夏季新安江水库(千岛湖)53个站点悬浮颗粒物的吸收光谱进行研究,系统分析了总颗粒物吸收系数ap(λ)、非藻类颗粒物吸收系数ad(λ)和浮游藻类光谱吸收系数aph(λ)的变化规律以及影响因素.结果表明:总颗粒物吸收除西北河流区上游段外,其他各站点均呈现出明显的浮游藻类吸收特性,反映新安江水库总颗粒物中浮游藻类贡献较高.全库ap(440)在0.068 ～0.629 m-1之间变化,西北河流区总颗粒物吸收系数显著大于其他水域,而湖泊区与西南河流区则显著小于其他水域.非藻类颗粒物吸收光谱随着波长增加大致呈现出指数函数衰减的规律,其光谱斜率Sd均值为8.52±1.62μm-1,存在显著的空间差异,但整体偏低,与新安江水库无机颗粒物含量低有关.ad (440)与浮游藻类色素浓度存在显著的线性相关,表明夏季新安江水库非藻类颗粒物可能主要来源于浮游藻类降解.浮游藻类的光谱吸收在440和675 nm附近有明显的吸收峰.aph(440)和aph(675)存在显著的空间差异,其与浮游藻类色素浓度存在极显著的正线性关系,而与总悬浮颗粒物浓度相关性较弱.     

Sorption of Eu~(3+) onto nano-size silica-water interfaces

A large amount of nuclear wastes has been pro-duced due to nuclear weapon development and nuclear electricity generation. One possible resolution for the disposal of the nuclear wastes is to seal them in an underground repository, which requires detailed knowledge on the mobility, chemical behavior and immobilization of radionuclides in underground water. In addition, toxic heavy metals are extensively present in ground and underground water, how to immobilize and remedy these toxic heavy meta…