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141.
氯化钠存在下氯化亚锡—罗丹明B—水体系浮选分离铱 总被引:5,自引:1,他引:5
研究了Ir(Ⅲ)在NaCl存在下SnCl2-罗丹明B-水体系中的浮选行为,在1.0mol/L HCl介质中,Ir(Ⅲ)与Pd,Pt,Rh,Au同时被浮选,Ir(Ⅲ)的浮选率为99.2%,并与常见贱金属离子分离,被浮选分离的Ir可采用原子吸收法测定,结果与火试金分离富集法相符。精密度试验,相对标准偏差(RSD,n=5)<3%。 相似文献
142.
微量元素在植物光谱中的响应机理研究 总被引:26,自引:0,他引:26
微量元素与植物光谱特征的研究是光学遥感定量化研究的重要内容之一。本研究利用高光谱地面光谱仪(GER)在湖南黔阳地区不同地质地球化学背景下的同一垂直剖面上分别测量了岩石、土壤植物(林灌草)的反射光谱曲线和植物叶片的8种微量元素含量。通过研究微量元素Fe,Mn,Cu,Zn,Co,Cr,Mo,B与植物(包括林灌草)反射光谱间的相关性研究发现Co的含量与植物光谱绿区(0.56μm附近)反射率存在强的负相关,Mn,B,Mo和Zn分别在可见光、近红外、短波红外存在较好的相关性和光谱响应。 相似文献
143.
Steve Dury Brian Turner Bill Foley Ian Wallis 《International Journal of Applied Earth Observation and Geoinformation》2001,3(4):328
In this study we assess the feasibility of remotely measuring canopy biochemistry, and thus the potential for conducting large-scale mapping of habitat quality. A number of studies have found nutrient composition of eucalypt foliage to be a major determinant of the distribution of folivorous marsupials. More recently it has been demonstrated that a specific group of secondary plant chemicals, the diformylphloroglucinols (DFPs), are the most important feeding deterrents, and are thus vital determinants of habitat quality. We report on the use of laboratory spectroscopy to attempt to identify one such DFP, sideroxylonal-A, in the foliage of Eucalyptus melliodora, one of the few eucalypt species browsed by folivorous marsupials. Reflectance spectra were obtained for freeze-dried, ground leaves using near infrared spectroscopy (NIRS) and for both oven-dried and fresh whole leaves using a laboratory-based (FieldSpec) spectroradiometer. Modified partial least squares (MPLS) regression was used to develop calibration equations for sideroxylonal-A concentration based on the reflectance spectra transformed as both the first and second difference of absorbance (Log 1/R). The predictive ability of the calibration equations was assessed using the standard error of calibration statistic (SECV). Coefficients of determination (r2) were highest for the ground leaf spectra (0.98), followed by the fresh leaf and dry leaf spectra (0.94 and 0.87, respectively). When applied to independent validation sub-sets, sideroxylonal-A was most accurately predicted from the ground leaf spectra (r2 = 0.94), followed by the dry leaf and fresh leaf spectra (0.72 and 0.53, respectively). Two spectral regions, centred on 674 nm and 1394 nm, were found to be highly correlated with sideroxylonal-A concentration for each of the three spectral data sets studied. Results from this study suggest that calibration equations derived from modified partial least squares regression may be used to predict sideroxylonal-A concentration, and hence leaf palatability, of Eucalyptus melliodora trees, thereby indicating that the remote estimation of habitat quality of eucalypt forests for marsupial folivores is feasible. 相似文献
144.
145.
不同石墨炉技术对钒原子化信号的影响 总被引:2,自引:0,他引:2
研究了钒元素在不同石墨炉技术、不同类型石墨管中的原子吸收曲线,探讨了产生这些差异的根本原因。 相似文献
146.
Flux-energy spectra of precipitating electrons are derived from electron density profiles measured by the EISCAT radar during auroral absorption events in the morning/noon local-time sector. The inversion technique uses effective recombination coefficient profiles computed on the basis of a previously validated theoretical model of the lower ionosphere. It is shown that flux-energy spectra for the energy range 30–200 keV are in reasonable agreement with those derived for the same events using trapped flux-energy spectra from geosynchronous satellite data and a model for diffusion of trapped electrons into the loss cone by scattering on whistler waves. During individual events, strongly varying precipitating fluxes are found to be due primarily to varying pitch-angle diffusion. 相似文献
147.
The effectiveness of tuned mass dampers (TMD) in vibration control of buildings was investigated under moderate ground shaking caused by long‐distance earthquakes with frequency contents resembling the 1985 Mexico City (SCT) or the 1995 Bangkok ground motion. The elastic–perfectly plastic material behaviour was assumed for the main structure, with linear TMDs employed by virtue of their simplicity and robustness. The accumulated hysteretic energy dissipation affected by TMD was examined, and the ratio of the hysteretic energy absorption in the structure with TMD to that without it is proposed to be used, in conjunction with the peak displacement ratio, as a supplementary TMD performance index since it gives an indication of the accumulated damage induced in the inelastic structures. For the ground motions considered, TMD would be effective in reducing the hysteretic energy absorption demand in the critical storeys for buildings in the 1.8–2.8 s range. The consequence is reduction in damage of the buildings which would otherwise suffer heavy damage in the absence of TMD, resulting in economical restorability in the damage control limit state. This is of practical significance in view of the current trend toward performance‐based design. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
148.
The incorporation of hydrogen (deuterium) into the coesite structure was investigated at pressures from 3.1 to 7.5 GPa and
temperatures of 700, 800, and 1100 °C. Hydrogen could only be incorporated into the coesite structure at pressures greater
5.0 GPa and 1100 °C . No correlation between the concentration of trace elements such as Al and B and the hydrogen content
was observed based on ion probe analysis (1335 ± 16 H ppm and 17 ± 1 Al ppm at 7.5 GPa, 1100 °C). The FTIR spectra show three
relatively intense bands at 3575, 3516, and 3459 cm−1 (ν1 to ν3, respectively) and two very weak bands at 3296 and 3210 cm−1 (ν4 and ν5, respectively). The band at 3516 cm−1 is strongly asymmetric and can be resolved into two bands, 3528 (ν2a) and 3508 (ν2b) cm−1, with nearly identical areas. Polarized infrared absorption spectra of coesite single-crystal slabs, cut parallel to (0 1
0) and (1 0 0), were collected to locate the OH dipoles in the structure and to calibrate the IR spectroscopy for quantitative
analysis of OH in coesite (ɛ
i
,tot=190 000 ± 30 000 l mol−1
H2O cm−2). The polarized spectra revealed a strong pleochroism of the OH bands. High-pressure FTIR spectra at pressures up to 8 GPa
were performed in a diamond-anvil cell to gain further insight into incorporation mechanism of OH in coesite. The peak positions
of the ν1, ν2, and ν3 bands decrease linearly with pressure. The mode Grüneisen parameters for ν1, ν2, and ν3 are −0.074, −0.144 and −0.398, respectively. There is a linear increase of the pressure derivatives with band position which
follows the trend proposed by Hofmeister et al. (1999). The full widths at half maximum (FWHM) of the ν1, ν2, and ν3 bands increase from 35, 21, and 28 cm−1 in the spectra at ambient conditions to 71, 68, and 105 in the 8 GPa spectra, respectively. On the basis of these results,
a model for the incorporation of hydrogen in coesite was developed: the OH defects are introduced into the structure by the
substitution Si4+(Si2)+4O2−= [4]□(Si2) + 4OH−, which gives rise to four vibrations, ν1, ν2a, ν2b, and ν3. Because the OH(D)-bearing samples do contain traces of Al and B, the bands ν4 and ν5 may be coupled to Al and/or B substitution.
Received: 19 December 2000 / Accepted: 23 April 2001 相似文献
149.
Tobelite (NH4) Al2 [AlSi3O10] (OH)2, the ammonium analogue of muscovite, and its deuterated form ND4-tobelite (ND4) Al2 [AlSi3O10] (OD)2 have been synthesised at 600?°C and 200 and 500 Mpa using a well homogenised, stoichiometric SiO2-Al2O3 oxide mix with Al2O3 in excess of 5 mol% and a 25% NH3 solution whose relative abundance was such that the amount of NH4 + stoichiometrically available was in excess of 50%. Characterisation of both tobelite and ND4-tobelite using IR-spectroscopy, Rietveld refinement of X-ray powder diffraction data, and electron microprobe analysis indicate that, similar to K+ in muscovite, the NH4 + or ND4 + molecule occupies the interlayer site. IR absorption bands caused by NH4 + and ND4 + can be explained, to a very good approximation, on the basis of Td symmetry. Nevertheless, substantial line broadening and the occurrence of shoulders indicate a deviation from ideal Td symmetry. However, even at 77?K, no discrete splitting of the degenerate states could be confirmed. The OH stretching frequencies observed for synthetic tobelite are quite similar to those for muscovite, indicating that the replacement of K+ by NH4 + has no effect. The low FWHH of the OH bands indicate that the hydroxyl groups are well ordered within the structure. Rietveld refinement of tobelite and ND4-tobelite indicates that all samples synthesised consist of the 3 different mica polytypes which are typical of muscovite – namely 1M (C2/m), 2M 1 (C2/c) and 2M 2 (C2/c). Tobelite and ND4-tobelite synthesised at 500 Mpa principally contain the 1M polytype, whereas the principle polytype for ND4-tobelite synthesised at 200 Mpa, is 2M 2. Rietveld refinement of X-ray diffraction spectra for tobelite synthesised at 200 Mpa was problematic due to the very broad FWHH of the X-ray peaks indicating poor crystallinity. In comparision to synthetic muscovite, the cell dimensions observed for tobelite and its deuterated analogue are quite similar except for the lattice constant c. Due to the larger radius of NH4 + or ND4 + compared to K+ cation, the c-direction is expanded form 10.275 Å in muscovite to approximately 10.540 Å in tobelite and ND4-tobelite. 相似文献
150.
Short-wave infrared reflectance spectra obtained from a Portable Infrared Mineral Analyser (PIMA) have been used to define alteration zones adjacent to base metal sulfide ore bodies at the Elura Mine, Cobar, Australia. The spectroscopic work identified white mica (sericite), chlorite and carbonates of hydrothermal origin in the alteration zones associated with the ore bodies. Weathering, alteration and ore zones can be discriminated by variations in the intensity and wavelength of relevant absorption features. Hydrothermal alteration is classified into four principal types, namely sericitic, silicic, chloritic and carbonate alteration. The first three types comprise overprinting hydrothermal assemblages of quartz, sericite, chlorite, ankerite, siderite, calcite and sulfides developed in strongly altered metasiltstone and slate of Early Devonian age, adjacent to the zinc–lead–silver mineralisation. An extensive zone of carbonate alteration, manifested as porphyroblasts of siderite in the host metasediments, is recognised beyond the zones of strong alteration. Spectral analysis is consistent with the mineralogical data obtained from XRD and XRF analyses and defines the limits of the alteration zones to distances of about 80 m around the ore bodies. The study demonstrates the potential for spectral analysis to assist with drill hole logging and the identification of alteration zones as part of mineral exploration and development programs. 相似文献