GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.     

SPATIAL DISTRIBUTION OF NUTRIENTS OF SHALLOW LAKE IN THE ZHALONG WETLAND

1 INTRODUCTIONNitrogen and phosphorus in the water are the nu-trients limited in natural wetlands,which seriously in-fluence on the ecosystem production and the biodiver-sity(Mitsch,Grosselin,2000).Nitrogen and phos-phorus recycles have been interrupted b…     

Factors controlling the spatial and temporal variability of dust emissions

New field measurement techniques are allowing researchers to better understand how surficial properties affect the temporal and spatial variability of dust emissions. In this paper we review the current understanding of the dust emission process and present new field measurements that examine how three surface properties： roughness, crust strength, and temporal changes of surface properties affect dust emissions. These data were collected using three unique measurement systems developed by our team. Roughness exerts considerable control on the entrainment threshold and emissions of dust from a surface. We have carried out a series of experiments designed to quantify roughness effects on aeolian sediment entrainment and transport in a shear stress partitioning framework. Our results show that the model of Raupach et al. （1993） provides very good agreement with available data to predict the amount of shearing stress on the intervening surface among roughness elements, relatively independent of their size and distribution. However, element size affects the aeolian sediment transport process beyond that attributable only to the reduction of surface shear stress caused by the roughness. Additional interactions of the elements with the saltation cloud appear to reduce the transport efficiency and potentially dust emissions as well. The effect of crust strength on dust emissions was assessed using a newly-developed pin penetrometer, which can measure crust strength in-situ. Previous researchers suggested that variation in crust strength even within a small area could lead to considerable spatial variability in dust emissions. Our measurements showed that crust strength is highly variable over a scale of centimeters. This variability may help to explain some of the observed scatter in field measurements of dust emissions for what appear to be homogeneous surfaces. Variability of dust emissions in time and space was also evaluated using a new instrument, the Portable In-Situ Wind Erosion Lab （PI-SWERL） developed to measure dust emissions from soil surfaces.     

A Connectivity Index for Discrete Fracture Networks

Connectivity is an important measure for assessing flow transport in rock, especially through fractures. In this paper, rock fracture systems are modelled by a discrete fracture model simulated by a marked point process. A connectivity index is then introduced to quantify the connectivity between any two points in space. Monte Carlo simulation is used to evaluate the connectivity index for stationary cases and relationships between the connectivity index and the parameters of the discrete fracture model are analysed. The average number of intersections per fracture, X_f, and the fracture intensity, P12 (P32), are calculated and the relationships between these parameters and the connectivity index are investigated, concluding that X_f is the more suitable parameter for the classification of rock mass flow properties. The relationships between the connectivity index and the percolation state of the fractured medium are also discussed. An edge correction is briefly discussed and a practical example is used to demonstrate the method of computing the connectivity index.     

侵蚀红壤植被恢复后土壤呼吸日动态及日呼吸速率测定方法比较

采用密闭室红外气体分析仪法(IRGA法)观测了中亚热带红壤侵蚀裸地植被恢复后不同季节土壤呼吸速率的日动态变化,并比较了IRGA法与碱吸收法(AA法)测定的土壤呼吸速率.结果表明:侵蚀裸地植被恢复后土壤呼吸速率日动态呈单峰曲线,与土壤温度的昼夜变化基本一致,最高值一般出现在午后13∶00~17∶00,最低值出现在凌晨3∶00~7∶00;植被恢复显著提高了土壤日呼吸速率,但明显降低了土壤呼吸速率日变化幅度;马尾松林对土壤呼吸速率日变化幅度降低程度高于板栗园和百喜草地,且对夏季的降低程度影响最大.而IRGA法和AA法测定的土壤呼吸速率具有显著的幂函数关系,AA法测定的土壤呼吸速率为IRGA法的27.5%~218%,平均为76.2%.当土壤呼吸速率较低时,AA法比IRGA法高估了土壤呼吸速率;反之,AA法则低估了土壤呼吸速率.     

房产测绘平面图系统的实现研究

随着城市规划管理的不断发展．使得城市房产测绘单位采用大型空间数据库管理测绘平面图资料成为必然。通过建立房产测绘平面图系统，可以有效地解决数据标准不一致．图数不能互访，测绘各部门无法协调一致等问题，充分发挥网络功能，提升整个城市的房产管理水平．达到房产管理和房产服务一体化的目标。本文详细论述了房产测绘平面图系统的概念、设计原则和系统功能．在南京数字房产共享平台的建设中得到了实现．并取得了良好的效果。     

相对湿度对气溶胶辐射特性和辐射强迫的影响

采用已有的气溶胶折射指数等资料 ,计算了在不同的相对湿度条件下硫酸盐气溶胶的辐射特性。结合两种不同化学输送模式 (CTM )的模拟结果及LASGGOALS/AGCM模式 ,模拟估算了考虑相对湿度影响后全球硫酸盐气溶胶的辐射强迫。结果表明 :(1)随着相对湿度的增加 ,硫酸盐气溶胶的质量消光效率因子在短波波段有所减小 ,单次散射反照率仅在长波波段有所增加 ,不对称因子在整个波段均有所增加 ;(2 )用两个CTM资料模拟辐射强迫的结果相差较大 ,其全球平均辐射强迫分别为 - 0 .2 6 8和 - 0 .816W/m2 ;(3)在考虑相对湿度的影响后 ,硫酸盐气溶胶辐射强迫的分布类型与相应干粒子的强迫分布类型基本相同 ,但全球平均的强迫值减少了 6 %左右。     

静压预制桩工程性状研究──以河南某电厂技改工程为例

以河南某电厂技改工程为例 ,根据现场检测结果 ,探讨了影响静压预制桩沉桩深度成因 ,分析了静压桩承载力的分布规律。研究结果证明静压桩的沉桩深度和承载力与地基土的性状密切相关。对于河南某电厂技改工程场地 ,尽管桩端进入砂较小深度 ,却可以在桩端平面附近良好土层的作用下提供较大的端阻力。     

南水北调中线工程上第三系膨胀性硬粘土的工程地质特性研究

上第三系硬粘土在中国东部新生代沉积盆地具有广泛的分布 ,因其性质复杂而成为中国区域性特殊岩土研究的重要对象。纵贯于南阳盆地和华北盆地西缘的南水北调中线工程长距离地开挖在不同的上第三系硬粘土中。本文在对南阳盆地、方城宝丰、邯郸永年三渠段上百个原状样的物质组成、物理性质、物化性质、膨胀性和收缩性、强度特性系统测试分析的基础上 ,总结了各类硬粘土的工程地质特性及其形成机理和变化规律 ,并根据不同湿度、围压状态下的试验结果分析了硬粘土的工程环境效应 ,这对于认识上第三系硬粘土在开挖运营条件下的变形破坏机理有着重要的理论和实际意义。     

准噶尔盆地西北缘侏罗系储层

准噶尔盆地西北缘侏罗系陆相碎屑岩储层的岩性差异较大，岩性对物性的控制作用明显。储层的孔隙类型多样，不同类型的孔隙在发育规模、丰度及有效性方面都存在显差异，次生溶蚀孔隙、原生粒间孔隙和残余粒间孔隙是最重要的有效孔隙类型。储层渗透率与孔隙度之间存在较好的半对数相关关系。通过设置一定的孔隙度和渗透率参数界线，对储层储集性能进行评价，将侏罗系储层的孔渗性能划分为5个级别，可与当前流行的砂岩储层孔渗性能分级相对应。通过对大量压汞参数样本的聚类分析，将储层的孔隙结构划分为4个类型。通过各类参数统计及曲线形态对比，对孔隙结构类型进行了定量结合定性的优劣评价。最后，结合孔渗性能级别、储集空间类型、孔隙结构类型、岩性等特征，对准噶尔盆地西北缘侏罗系储层进行了综合分类评价。