Mineralogy, geochemistry, and Nd isotope composition of the Rainbow hydrothermal field, Mid-Atlantic Ridge

Petrological, geochemical, and Nd isotopic analyses have been carried out on rock samples from the Rainbow vent field to assess the evolution of the hydrothermal system. The Rainbow vent field is an ultramafic-hosted hydrothermal system located on the Mid-Atlantic Ridge characterized by vigorous high-temperature venting (∼365°C) and unique chemical composition of fluids: high chlorinity, low pH and very high Fe, and rare earth element (REE) contents (Douville et al., Chemical Geology 184:37–48, 2002). Serpentinization has occurred under a low-temperature (<270°C) retrograde regime, later overprinted by a higher temperature sulfide mineralization event. Retrograde serpentinization reactions alone cannot reproduce the reported heat and specific chemical features of Rainbow hydrothermal fluids. The following units were identified within the deposit: (1) nonmineralized serpentinite, (2) mineralized serpentinite—stockwork, (3) steatite, (4) semimassive sulfides, and (5) massive sulfides, which include Cu-rich massive sulfides (up to 28wt% Cu) and Zn-rich massive sulfide chimneys (up to 5wt% Zn). Sulfide mineralization has produced significant changes in the sulfide-bearing rocks including enrichment in transition metals (Cu, Zn, Fe, and Co) and light REE, increase in the Co/Ni ratios comparable to those of mafic Cu-rich volcanic-hosted massive sulfide deposits and different ¹⁴³Nd/¹⁴⁴Nd isotope ratios. Vent fluid chemistry data are indicative of acidic, reducing, and high temperature conditions at the subseafloor reaction zone where fluids undergo phase separation most likely under subcritical conditions (boiling). An explanation for the high chlorinity is not straightforward unless mixing with high salinity brine or direct contribution from a magmatic Cl-rich aqueous fluid is considered. This study adds new data, which, combined with the current knowledge of the Rainbow vent field, brings compelling evidence for the presence, at depth, of a magmatic body, most likely gabbroic, which provides heat and metals to the system. Co/Ni ratios proved to be good tools used to discriminate between rock units, degree of sulfide mineralization, and positioning within the hydrothermal system. Deeper units have Co/Ni <1 and subsurface and surface units have Co/Ni >1.     

大气CO2浓度升高对土壤中不同粒级碳的影响

不同粒级土壤中的碳有着不同的周转规律，在高CO2浓度条件下，它们含量的变化将在一定程度上反映土壤碳是累积还是减少，对明确土壤碳的变化趋势有重要意义．采用田间培养试验初步模拟研究在高CO2浓度条件下土壤不同粒级碳的分布．结果表明，加入秸秆培养1年，由于CO2浓度升高的原因导致在低氮（LN）、常规氮（NN）和高氮（HN）水平下土壤中碳分别增加0．01、1．10、1．22g／kg，表现为粒级〈53μm土壤颗粒中碳分别增加1．53、2．19、2．70g／kg．粒级〈53μmm土壤颗粒碳量的增加，主要是由于其重量分配百分数显著增加36．2％，碳浓度增加5．4％；粒级〉250μm和250～53μm土壤颗粒部分虽然其碳浓度分别增加20．8％和17．3％（P〈0．05），怛由于重量分配百分数分别显著降低22．8％和36．1％，结果碳量降低．试验表明高CO2浓度导致不同粒级土壤的分配及碳浓度的变化；高氮施肥水平下有增加土壤碳量特别是小粒级土壤碳量的趋势．     

Centennial to millennial geomagnetic secular variation

A time-varying spherical harmonic model of the palaeomagnetic field for 0–7 ka is used to investigate large-scale global geomagnetic secular variation on centennial to millennial scales. We study dipole moment evolution over the past 7 kyr, and estimate its rate of change using the Gauss coefficients of degree 1 (dipole coefficients) from the CALS7K.2 field model and by two alternative methods that confirm the robustness of the predicted variations. All methods show substantial dipole moment variation on timescales ranging from centennial to millennial. The dipole moment from CALS7K.2 has the best resolution and is able to resolve the general decrease in dipole moment seen in historical observations since about 1830. The currently observed rate of dipole decay is underestimated by CALS7K.2, but is still not extraordinarily strong in comparison to the rates of change shown by the model over the whole 7 kyr interval. Truly continuous phases of dipole decrease or increase are decadal to centennial in length rather than longer-term features. The general large-scale secular variation shows substantial changes in power in higher spherical harmonic degrees on similar timescales to the dipole. Comparisons are made between statistical variations calculated directly from CALS7K.2 and longer-term palaeosecular variation models: CALS7K.2 has lower overall variance in the dipole and quadrupole terms, but exhibits an imbalance between dispersion in   g ¹₂  and   h ¹₂  , suggestive of long-term non-zonal structure in the secular variations.     

大湾铀矿田铀-镭平衡系数及迁移富集特征研究

从分析大湾铀矿田各矿床(点)的铀镭平衡系数变化特征出发,结合放射性同位素比值特征分析铀镭迁移富集行为,指出了各矿床(点)氧化带的深度,以了解各铀矿床(点)潜在的工业价值.     

考虑滑脱效应和温度场的煤层气渗流数值模拟

由于煤层气的解吸热效应,煤层气的运移过程是一个非等温过程。因此,温度场对煤层气渗流有着重要的影响。前人在研究煤层气渗流规律的研究中并没有同时考虑滑脱效应和温度场因素的影响,而在实际的深部开采中综合考虑滑脱效应和温度场的影响对研究深部煤层气运移规律有着重要的意义。因此本文建立了考虑滑脱效应及温度场的煤层气渗流数学模型,利用有限元数值方法研究了考虑滑脱效应和温度场耦合的煤层气运移规律;研究了考虑滑脱效应和温度场对压力场分布的影响;对考虑滑脱效应及温度场因素的煤层气产量进行了预测。得出了随着温度的升高煤储层的压力在降低,温度的升高对煤层气的产量有着负面的影响这一重要结论。     

库车坳陷侏罗系煤成气动力学模拟研究

应用黄金管—高压釜封闭体系热模拟实验与GC、GC-IRMS分析技术,结合KINETICS专用软件,对库车坳陷侏罗系煤成气进行了动力学模拟研究。库车坳陷侏罗系煤具有高的产气性,在高演化阶段主要产甲烷气;侏罗系煤热解气甲烷碳同位素为-36‰～-25‰,乙烷碳同位素为-28‰～-16‰;甲烷、C2-C5气态烃的生成活化能分别为(47～64k)calm/ol、(55～72k)calm/ol,频率因子各为5.265×1013s-1、5.388×1018s-1。在此基础上,进一步探讨了克拉2气田天然气的成因。研究认为,克拉2气田天然气属阶段捕获的煤成气,主要聚集了5～1Ma时期的天然气,其成熟度Ro分布范围为1.3%～2.5%。     

PDC钻头在寺河煤矿瓦斯预抽放钻井中的应用

在寺河矿区一期瓦斯地面预抽放钻井施工中，使用传统的镶齿三牙轮钻头钻进，钻进速度低，仅为2.0m／h，且井斜不易控制、钻头寿命短、成本较高。通过对寺河煤矿地层特征的分析，在二期工程施工中，9#煤以上地层优选六翼内凹式PDC钻头钻进，采取一定技术措施并合理调整钻压、转速及泵量等钻进参数，钻速可达7．0m/h，井斜也得到有效控制，降低了钻井成本。     

USB总线与CAN总线协议转换器设计

现场总线(F ield bus)是将自动控制系统中底层的现场控制器和现场智能仪表设备互连的实时控制通讯网络,是5C(Computer,Control,Commun ication,CRT,Change)技术相结合的产物。CAN(Control Area Network)总线是现场总线的一种,广泛应用于汽车行业、机械工业、家用电器、传感器等领域,已经形成国际标准,是被公认的几种最有前途的现场总线之一。提出了一种通过计算机USB接口实现现场总线CAN与计算机(服务器)之间通信的方案。具体介绍了使用USB总线接口芯片CH372和独立的CAN控制器SJA1000实现的硬件电路设计方法、本地端软件的编写方法,给出了主要程序模块的流程。     

油气化探数据库系统

建立油气化探数据库是油气化探信息资源共享、科学管理、宏观决策的基础和依据,是油气化探数据处理及异常评价的基础。本系统采用动态自适应结构,收集、录入了几十年来我国油气化探数据,可以完成油气化探数据登录、管理、浏览、检索、报表、数据预处理。文章中论述了油气化探数据库的结构、特点及功能,反映了油气化探数据库研究领域的新进展和研究水平。