利用ARGO资料改进海洋资料同化和海洋模式中的物理过程

国际ARGO计划的实施每年将可提供多达 10万个剖面 (0～ 2 0 0 0m水深 )的海水温度和盐度资料 ,这些资料的获取无疑将会大大促进海洋和大气科学的发展 ,使人们加深对海洋过程的了解 ,揭示海 气相互作用的机理 ,为长期天气预报和短期气候预测提供模式初始场 ,提高长期天气预报和短期气候预测的能力。如何利用这些资料开展研究工作以及在实际业务中应用这些资料是目前大气和海洋科学界的一个前沿课题。本研究将ARGO浮标资料引入了国家气候中心的NCC GODAS同化系统 ,结果分析表明 ,同化ARGO资料后所得到的海温场在三大洋中不仅在温度数值的大小 ,而且在分布形式方面都与观测场具有较好的一致性 ,可以很好地反映出观测到的冬季和夏季海温的分布形式以及海温的季节变化特征和异常特征。本研究还应用最新的ARGO海洋观测资料 ,通过建立新的热带西太平洋次表层海温参数化方案 ,改进了Zebiak Cane(1987)海洋模式 (ZC模式 ) ,克服了ZC模式几乎没有模拟赤道西太平洋表层和次表层海温变化能力的缺陷。在ZC模式中引用新的次表层海温参数化方案后 ,在赤道西太平洋不仅次表层海温的模拟得到了改善 ,对海面温度异常的模拟也有了较大的改进 ,不仅模拟出了赤道西太平洋表层和次表层海温异常的年际变化特征 ,也模拟出了与观     

Relationships between Interannual and Intraseasonal Variations of the Asian-Western Pacific Summer Monsoon Hindcasted by BCC_CSM1.1（m）

Using hindcasts of the Beijing Climate Center Climate System Model, the relationships between interannual variability （IAV） and intraseasonal variability （ISV） of the Asian-western Pacific summer monsoon are diagnosed. Predictions show reasonable skill with respect to some basic characteristics of the ISV and IAV of the western North Pacific summer monsoon （WNPSM） and the Indian summer monsoon （ISM）. However, the links between the seasonally averaged ISV （SAISV） and seasonal mean of ISM are overestimated by the model. This deficiency may be partially attributable to the overestimated frequency of long breaks and underestimated frequency of long active spells of ISV in normal ISM years, although the model is capable of capturing the impact of ISV on the seasonal mean by its shift in the probability of phases. Furthermore, the interannual relationships of seasonal mean, SAISV, and seasonally averaged long-wave variability （SALWV; i.e., the part with periods longer than the intraseasonal scale） of the WNPSM and ISM with SST and low-level circulation are examined. The observed seasonal mean, SAISV, and SALWV show similar correlation patterns with SST and atmospheric circulation, but with different details. However, the model presents these correlation distributions with unrealistically small differences among different scales, and it somewhat overestimates the teleconnection between monsoon and tropical central-eastern Pacific SST for the ISM, but underestimates it for the WNPSM, the latter of which is partially related to the too-rapid decrease in the impact of E1 Nifio-Southern Oscillation with forecast time in the model.     

西天山特克斯达坂库勒萨依序列埃达克岩的确立及钼找矿意义

库勒萨依序列斑岩体δ平均3.05,属于钙碱性系列岛弧浅成岩。 SiO₂含量为57.06％~70.74％,高Al₂O₃、Na₂O、Sr和相对富集LREE,低MgO、Y、Yb,强烈亏损HREE。Na₂O/K₂O＞1,Sr/Y平均57.67,正Eu异常,因而具有典型O型埃达克岩特征。库勒萨依序列斑岩体与Mo异常套合好,已发现钼矿体,找矿前景良好。该埃达克岩的确立,对深化西天山区域成矿规律和指导今后找矿具有借鉴和指导意义。     

柴达木盆地西部地区咸化湖盆天然气地球化学特征及成因类型判识指标——以古近系—新近系为例

根据天然气地球化学基本理论,对柴达木盆地西部（柴西）地区天然气的地球化学特征进行分析。测试和收集该地区18个油气田及含油气构造的83个天然气样品,分析其组分和C同位素数据,结果显示,该区天然气以烃类气体为主,烃类含量介于79.24%~99.81%之间,天然气比重介于0.72~1.36之间,天然气干燥系数（C1/C2+）介于1.04~617.8之间,甲烷C同位素值介于-51.4‰~-24.2‰之间,乙烷C同位素值介于-34.2‰~-17.4‰之间。在此基础上,对该区不同构造带的天然气成因类型进行研究。研究结果表明,柴达木盆地西部地区天然气类型可划分为腐泥型气、腐殖型气、混合气3类,柴西北部天然气主要为腐泥型气和混合气,少量腐殖型气;柴西南部主要为腐泥型气,少量混合气。同时,建立了天然气成因类型的判识指标,对该区的天然气地球化学特征有了较为深入的认识,对今后的天然气勘探具有指导意义。     

热带西太平洋热状况年代际和年际变化特征分析

采用谐波分析和EOF分析方法,对比研究了暖池区域表层热状况(海表温度距平SST'表征)和浅层热状况(热含量距平HS'和次表层海温距平ST'表征)在1月和7月的年代际、年际尺度时空特征.分析结果表明:⑴不同季节的年代际、年际尺度SST'和HS'都存在两个显著模态,HS'1月的年代际、年际尺度结构最简单,而SST'7月的年代际和1月年际结构最复杂;⑵ 1970年代末和1980年代初发生的年代际跃变HS'晚于SST', 且SST'(HS')呈增温(减少)趋势;⑶ HS'的年际异常与ENSO关系密切,而SST'与ENSO关系不显著.     

Formation of Fe-oxyhydroxides from the East Pacific Rise near latitude 13°N:Evidence from mineralogical and geochemical data

The mineralogical and geochemical characteristics of Fe-oxyhydroxide samples from one dredge station (long. 103°54.48'W, lat. 12°42.30'N, water depth 2655 m) on the East Pacific Rise near lat 13°N were analyzed by XRD, ICP-AES, and ICP-MS. Most Fe-oxyhydroxides are amorphous, with a few sphalerite microlites. In comparison with Fe-oxyhydroxides from other fields, the variable ranges in the chemical composition of Fe-oxyhydroxide samples are very narrow; their Fe, Si, and Mn contents were 39.90%, 8.92%, and 1.59%, respectively; they have high Cu (0.88%―1.85%) and Co (65×10?6―704×10?6) contents, and contain Co Cu Zn Ni> 1.01%. The trace-element (As, Co, Ni, Cu, Zn, Ba, Sr) and major-element (Fe, Ca, Al, Mg) contents of these samples are in the range of hydrothermal sulfide from the East Pacific Rise near 13°N, reflecting that this type of Fe-oxyhydroxide constitutes a secondary oxidation product of hydrothermal sulfide. The Fe-oxyhydroxide samples from one dredge station on the East Pacific Rise near 13°N are lower in ΣREE (5.44×10?6―17.01×10?6), with a distinct negative Ce anomaly (0.12 ― 0.28). The Fe-oxyhydroxide samples have similar chondrite-normalized rare-earth-element (REE) patterns to that of seawater, and they are very different from the REE composition characteristics of hydrothermal plume particles and hydrothermal fluids, showing that the REEs of Fe-oxyhydroxide are a major constituent of seawater and that the Fe-oxyhydroxides can become a sink of REE from seawater. The quick settling of hydrothermal plume particles resulted in the lower REE content and higher Mn content of these Fe-oxyhydroxides, which are captured in part of the V and P from seawater by adsorption. The Fe-oxyhydroxides from one dredge station on the East Pacific Rise near 13°N were formed by secondary oxidation in a low temperature, oxygenated environment. In comparison with the elemental (Zn, Cd, Pb, Fe, Co, Cu) average content of hydrothermal sulfide samples from the East Pacific Rise near 13°N, the Zn, Cd, and Pb contents of the Fe-oxyhydroxides are lower, and their Fe, Co, and Cu contents are higher.     

Geochronology and geochemistry of the Hekoulinchang Sn-Pb-Zn-Ag polymetallic deposit (73240 t) in Heilongjiang Province,China

The Hekoulinchang Sn-Pb-Zn-Ag polymetallic deposit(20000 t Sn at 0.27%,236 t Ag at 122.89 g/t,15000 t Pb at 0.84%,and 38000 t Zn at 1.43%)is located in the Wandashan Terrane of the easternmost segment of the Central Asian Orogenic Belt.The timing of Sn-Pb-Zn-Ag polymetallic mineralization remains unclear due to a lack of precise isotope dating directly conducted on ore minerals.The authors herein report that the LA-ICP-MS U-Pb ages of cassiterite and zircon from the granite porphyry in the Hekoulinchang Sn-Pb-Zn-Ag polymetallic deposit are 101.4±7.9 Ma and 115.4±1.0 Ma,respectively,indicating that Sn mineralization and magmatism occurred during the Early Cretaceous.The granite porphyry belongs to the subalkaline series peraluminous I-type granites that are depleted in Nb,Ta,and Ti and enriched in Rb,Th,U,and Pb.TheεHf(t)values of the granite porphyry range from 0.9 to 7.4,with an average of about 5.6 and two-stage model ages(T_DM2)of 705–1116 Ma,with an average age of 819 Ma.The ε_Nd(t)values of the apatites are–1.60–0.45,with an average of–0.9,and two-stage model ages(T_DM2)of 872–1040 Ma,with an average age of 983 Ma.The Nd-Hf isotope data indicate that the magma may have been derived from the partial melting of juvenile crustal material.     

西秦岭大店沟金矿成矿流体演化及矿床成因

大店沟金矿是西秦岭成矿带近年来新发现的中型金矿床,金矿体赋存在下古生界丹凤群木其滩组绢云绿泥石英片岩中,叠加在北东东向脆韧性剪切带中的脆性构造为成矿结构面。在总结控矿地质特征的基础上,通过开展系统的流体包裹体、稳定同位素地球化学研究及成矿流体演化、矿床成因探讨,认为成矿期共分半自形黄铁矿、它形粒状黄铁矿、石英多金属硫化物和碳酸盐-黄铁矿4个成矿阶段,其中它形黄铁矿阶段和石英多金属硫化物阶段为最主要成矿阶段。流体包裹体类型以水溶液包裹体、CO₂三相包裹体和纯CO₂包裹体为主,成矿温度集中在120~256 ℃之间,成矿流体盐度为4.03%~15.27%。H-O同位素研究显示成矿热液主要为变质水混合大气降水,S同位素组成特征表明成矿物质来自深源;流体不混溶和沸腾作用是金沉淀的主要机制,矿床成因类型为造山型金矿。通过成矿结构面舒缓波状特征规律总结,判断成矿流体沿成矿结构面自南西深部向北东浅部运移、沉淀,形成分段富集矿化。     

滇中北部昆阳群凝灰岩SHRIMP锆石U-Pb年龄及其地层学意义

滇中昆阳群一直是华南前寒武纪地质研究的热点之一,其地层序列、时代与区域对比长期存在争议。通过对滇中易门县小街乡普家村-岔河水库剖面禄表组2个凝灰岩样品进行SHRIMP锆石U-Pb定年,获得禄表组凝灰岩的锆石206Pb/238U年龄为878.5±4.7Ma和878.0±4.0Ma,首次证实禄表组的形成时代为新元古代中期。禄表组凝灰岩SHRIMP锆石U-Pb年龄的获得,有利于正确认识昆阳群的划属关系,并为西南地区青白口纪地层格架的建立和对比提供可靠的年代学依据。     

Structural improvement of age-hardened gypsum-treated bauxite red mud waste using readily decomposable phyto-organics

Several years (7) after incidental lithification by added gypsum, the effect of crushing and phyto-organics on some physical properties of red mud wastes (RMW) was examined under laboratory conditions. It was hypothesized that mechanically breaking up the hardened masses would increase their permeability. However, on the contrary, crushing these rock-hard masses into <2-mm particles did not increase permeability. A phyto-organic treatment on the other hand greatly improved permeability of the crushed entities such that infiltration rates increased from 0 to 10 cm/h. After 24 weeks of incubation, the structure of the newly formed phyto-organically treated gypsum-hardened RMW aggregates was also substantially improved over that of the controls, as a >3-fold increase in resistance to disintegration during wet sieving was exhibited by the phyto-organically treated samples. The increase in water infiltration by combining crushing with phyto-organic applications was ascribed to a decrease in particle dispersion, creating more stable clay clusters, which in turn stabilized channels and pores. Conversely, it was concluded that the singular crushing of gypsum-hardened bauxite waste in the waste dumps is potentially wasteful and ineffective.