The NO2 Absorption Spectrum. IV: The 200–400 nm Region at 220 K

Previous experiments in the 400–500 nm region (Coquart et al., 1995) have been extended to the 200–400 nm region to determine the absorption cross-sections of NO₂ at 220 K. The NO₂ and N₂O₄ cross-sections are obtained simultaneously from a calculation applied to the data resulting from measurements at low pressures. A comparison between the NO₂ cross-sections at 220 K and at ambient temperature shows that the low temperature cross-sections are generally lower, except in the region of the absorption peaks. Comparisons are also made with previous data at temperature close to 220 K.     

天然热释光测量方法在地质找矿中的应用

天然热释光测量方法是近几年发展起来的寻找隐伏铀矿体的方法。同时也是一种新的地质研究手段。经多种类型铀矿床的试验结果表明,该方法能有效地发现埋深几十米至二百多米深的盲矿体。此外,还可划分复式岩体不同侵入期和确定其侵入时代;区分产铀岩体与非产铀岩体;划分硅化带中各期石英岩的先后活动序次,进而确定与矿化有关的断裂带及各种热液铀矿脉的成矿时代。     

原子吸收光谱同时测定多元素的研究

本文着重从提高原子吸收光谱分析的效率出发,利用等离子体光源和光谱仪以替代目前原子吸收光谱分析所用的空心阴极灯和单色器系统,对多种元素进行同时测定。选用了Ca、Mg、Fe、Mn等四个元素进行实验,结果良好。此外,对这种方法的特点以及在实际工作中的应用等方面也作了简要叙述。     

硅酸钡铜的光吸收谱和EPR谱

本文报道水热合成硅酸钡铜(BaCuSi_4O_(10))的光吸收谱和EPR谱。EPR测量表明,在硅酸钡铜中,Cu~(2 )离子位置有轴对称性。在这种对称性下,一般只能观察到三条Cu~(2 )离子的吸收谱带,但在BaCuSi_4O_(10)的吸收谱中却观察到了四条。这一矛盾用~2Eg激发态的动态Jahn-Teller效应来解释。本文提出的~2Eg和~2A_1g能级的相对次序与文献[2]的相反,文中对这一问题作了详细的分析。跃迁频率和g因子的计算值在实验误差范围内与观测值一致。     

Near UV absorption spectra and photolysis products of difunctional organic nitrates: Possible importance as NO x reservoirs

Difunctional organic nitrates are important products of the atmospheric reaction of NO₃ radicals with unsaturated hydrocarbons about which relatively little is known. In a continuation of the investigation of the atmospheric chemistry of such compounds, the UV absorption spectra of the following organic dinitrates and keto nitrates have been quantitively measured in the gas phase at 298±2 K and atmospheric pressure: 1,2-propandiol dinitrate, CH₃CH(ONO₂)CH₂(ONO₂); 1,2-butandiol dinitrate, CH₃CH₂CH(ONO₂)CH₂(ONO₂); 2,3-butandiol dinitrate, CH₃CH(ONO₂)CH(ONO₂)CH₃;cis 1,4-dinitrooxy-2-butene, CH₂(ONO₂)CH=CHCH₂(ONO₂); 3,4-dinitrooxy-1-butene, CH₂(ONO₂CH(ONO₂)CH=CH₂; -nitrooxy acetone, CH₃COCH₂(ONO₂); 1-nitrooxy-2-butanone, CH₃CH₂COCH₂(ONO₂); 3-nitrooxy-2-butanone, CH₃CH(ONO₂)COCH₃.Although the UV spectra of the nitrates are all very similar in shape those of the keto nitrates are red-shifted compared to the dinitrates and in the spectral range of atmospheric interest (>290 nm) their absorption cross-sections are approximately a factor of 5 higher. The cross-sections of the dinitrates are a factor of 2 higher than those reported in the literature for the corresponding alkyl mononitrates.The UV absorption cross-sections of the difunctional nitrates were used in combination with solar actinic flux data to estimate photolysis frequencies and consequently atmospheric lifetimes for these compounds. The results indicate that for the saturated difunctional nitrates studied in this work photolysis will generally be somewhat some important than reaction with OH radicals as an atmospheric removal process. However, for unsaturated nitrates loss due to reaction with OH will dominate over photolysis as an atmospheric sink.Preliminary FT-IR analyses of the photolysis products of -nitrooxy acetone, 3-nitrooxy-2-butanone and 2,3-butandiol dinitrate using both mercury and fluorescent lamps indicate that NO₂ is released in the primary step. The further reactions of the radicals thus produced result in the formation of CO, aldehydes and PAN. The possible significance of the results for difunctional organic nitrate as reservoirs for reactive odd nitrogen NO _y in the atmosphere, especially during the night, is briefly discussed.     

膨胀土壤标准吸湿含水率及其试验方法

提出了土壤标准吸湿含水率的概念，说明了其物理意义，并给出了试验标准。通过试验结果可以看出，土壤标准吸湿含水率与膨胀土的蒙脱石含量、阳离子交换量、比表面积之间是线性相关的，反映了膨胀土的本质属性。土壤标准吸湿含水率不仅在膨胀土的分类中，而且在细粒材料的表面物理性质方面具有很大的应用前景。     

利用13X沸石分子筛净化含Pb~(2+)废水的实验研究

采用静态间歇法 ,实验研究了含Pb2 +废水的 pH值及吸附时间对 13X沸石分子筛吸附Pb2 +性能的影响 ,得出了最佳去除效果的优化条件为 :废水的 pH值接近中性 ,吸附时间 10min。通过吸附实验 ,确定了在Pb2 +初始浓度为 2 0mg/L的条件下 ,13X沸石对Pb2 +的吸附量为 2 1 4 2mg/g ,即每克沸石净化含Pb2 +废水的最大体积量约为 75 0mL。解析实验表明 ,加入沉淀剂 ,浓缩洗脱液中的Pb2 +即以PbS的形式生成沉淀 ,为回收金属铅提供了可能 ;13X沸石在循环使用 5次的条件下 ,对废水中Pb2 +的吸附率仍高达 98% ,重复使用性能良好。经处理后的净化水中Pb2 +的浓度小于 0 4mg/L ,显著低于国家废水排放标准GB8978 88的指标 ( 1 0mg/L)。 13X沸石对Pb2 +的主要吸附形式是离子交换和表面络合反应。     

利用高铁砂岩质煤矸石制备瓷质砖的研究

以湖北黄石高铁砂岩质煤矸石为主要原料，进行了制备瓷质砖的实验研究，并对不同配方、不同烧成温度瓷坯的吸水率、断裂模数等进行了测试分析。各项性能指标的综合分析表明，产品的吸水率低于0．3％，断裂模数高于35MPa，符合国家有关质量标准，颜色呈浅红-暗红-紫砂系列，其中煤矸石最高配比可达80％。     

原子吸收光谱法及其应用

综述了原子吸收光谱法的原理、测定技术、特点、联用、进展及其在各个领域中的应用。     

P—E5000原子吸收光谱仪的维修及零部件国产化

用实例介绍了对P－E5000原子吸收光谱仪的某些部件的替代和电路的改动，以及钨灯电路故障的维修。通过零部件的替代，使仪器得到及时维修，并且降低了成本。