萃淋树脂吸附法测金

对萃淋树脂在酸性介质中吸附解脱金及相关体系的条件选择，以及萃淋树脂在生产方面的应用前景进行了实验研究。结果表明，萃淋树脂在稀王水介质中能较好地吸附金，用硫脲解脱金简便完全，检测限达0．002μg／g，吸附率达100％，解脱率99．8％。     

Parameterization of the Absorption of the H_2O Continuum,CO_2,O_2,and Other Trace Gases in the Fu-Liou Solar Radiation Program

The absorption properties of the water vapor continuum and a number of weak bands for H2O, O2, CO2, CO, N2O, CH4, and O3 in the solar spectrum are incorporated into the Fu-Liou radiation parameterization program by using the correlated k-distribution method (CKD) for the sorting of absorption lines. The overlap absorption of the H2O lines and the H2O continuum (2500-14500 cm-1) are treated by taking the two gases as a single-mixture gas in transmittance calculations. Furthermore, in order to optimize the computation efforts, CO2 and CH4 in the spectral region 2850-5250 cm-1 are taken as a new single-mixture gas as well. For overlap involving other absorption lines in the Fu-Liou spectral bands, the authors adopt the multiplication rule for transmittance computations under which the absorption spectra for two gases are assumed to be uncorrelated. Compared to the line-by-line (LBL) computation, it is shown that the errors in fluxes introduced by these two approaches within the context of the CKD method are small and less than 0.48% for the H2O line and continuum in the 2500-14500 cm-1 solar spectral region, -1% for H2O (line) H2O (continuum) CO2 CH4 in the spectral region 2850-5250 cm-1, and -1.5% for H2O (line) H2O (continuum) O2 in the 7700-14500 cm-1 spectral region. Analysis also demonstrates that the multiplication rule over a spectral interval as wide as 6800 cm-1 can produce acceptable errors with a maximum percentage value of about 2% in reference to the LBL calculation. Addition of the preceding gases increases the absorption of solar radiation under all sky conditions. For clear sky, the increase in instantaneous solar absorption is about 9%-13% (~12 W m~2) among which the H2O continuum produces the largest increase, while the contributions from O2 and CO2 rank second and third, respectively. In cloudy sky, the addition of absorption amounts to about 6-9 W m-2. The new, improved program with the incorporation of the preceding gases produces a smaller solar absorption in clouds due to the reduced solar flux reaching the cloud top.     

The Effects of Line-Wing Cutoff in LBL Integration on Radiation Calculations

There are three basic methods in radiative transfer calculations, i.e., line-by-line (LBL) integration, correlated k-distribution method, and band model. The LBL integration is the most accurate of all, in which, there are two quadrature algorithms named in this paper as integration by lines and by sampling "points when calculating atmospheric transmittance in the considered wavenumber region. Because the LBL integration is the most expensive of all, it is necessary and important to save calculation time but increase calculation speed when it is put into use in the daily operation in atmospheric remote sensing and atmospheric sounding. A simplified LBL method is given in this paper on the basis of integration by lines, which increases computational speed greatly with keeping the same accuracy. Then, we discuss the effects of different cutoff schemes on atmospheric absorption coefficient, transmittance, and cooling rate under both of accurate and simplified LBL methods in detail. There are four cutoff schemes described in this paper, i.e., CUTOFFs 1, 2, 3, and 4. It is shown by this numerical study that the way to cut off spectral line-wing has a great effect on the accuracy and speed of radiative calculations. The relative errors of the calculated absorption coefficients for CUTOFF 2 are the largest under different pressures, while for CUTOFF 1, they are less than 2% at most of sampling points and for CUTOFFs 3 or 4, they are ahnost less than 5% in the calculated spectral region, however, the calculation time is reduced greatly. We find in this study that the transmittance in the lower atmosphere is not sensitive to different LBL methods and different cutoff schemes. Whereas for the higher atmosphere, the differences of transmittance results between CUTOFF 2 and each of other three cutoff schemes are the biggest of all no matter for the accurate LBL or for the simplified LBL integrations. By comparison, the best and optimized cutoff scheme is given in this paper finally.     

植被的微波散射与吸收特征

被动微波遥感中大尺度像元内植被种类多种多样并且分布不均匀，较低频率下像元尺度内的植被影响可以根据单个散射体的散射与衰减特性获得。本文讨论了任意朝向的各类植被散射体的计算问题。其中叶片和针叶的散射采用了一般化Rayleigh-Gans计算；杆的散射采用了无限长近似理论。关于各类散射体的衰减，本文比较了散射系数和吸收系数之和，与前向散射定理的结果，并对前向定理的适用性进行了讨论。     

模拟扰动条件下太湖表层沉积物磷行为的研究

利用恒温震荡器构筑的模拟扰动环境,研究了太湖水－沉积物界的磷释放和吸附行为。结果表明：表层沉积物的磷酸盐释放作用在模拟扰动条件下并不十分明显,在低强度的扰动条件下未观察到释放现象,模拟高强度扰动后,出现一个相对较强的释放过程,最大释放时沉积物上覆水浓度约为低强度扰动时的3倍,最大释放时间（Tmax)可能受磷酸盐形态分布的不同而有所差异,相比较而言,磷酸盐的吸附作用表现得十分明显迅速,沉积物上覆水磷酸盐浓度在0．5h后分别0229mg/L和l0.215mg／L下降为0．05mg/L和0.013mg/L,可以看出当上覆水磷酸盐浓度较高时,吸附作用的强度远大于释放作用,在25℃,模拟中等强度（100rpm)的模拟扰动条件下,当初始磷酸盐浓度为1．01mg/L时,梅梁湾和五里湖的表层沉积物吸附容量分别为每克千重吸附0．04mg和0.050mg磷酸盐,这种较高的吸附能力对浅水湖泊的磷酸盐缓冲作用能起到积极作用。     

与发射线区成协的类星体CIV吸收系统研究(Ⅱ)统计研究(1)

本文是系列文章的第二篇,我们在文(1)建立的均匀无偏的CIV吸收线样本的基础上,对该样本进行了统计检验和分析,结果支持成协系统的出现频率比非成协系统有明显的过超.而这种过超现象几乎和类星体的射电性质无关.但不同射电性质的类星体成协吸收出现频率随z_(em)的变化不尽相同.这种随z_(em)的变化可能反映了各种类星体,特别是射电类星体与环境相互作用的演化效应.但我们的样本中高红移射电类星体较少,因此非常需要获得更大的高红移射电类星体样本,以检验我们的结果.     

X射线粉晶衍射法分析磷化膜不同成分衍射强度比

利用X射线粉晶衍射法对金属板材及其磷化膜进行全谱和区段扫描,在确定镀膜中存在Zn2Fe(PO4)2.4H2O和Zn3(PO4)2.4H2O物相的基础上,求出Zn2Fe(PO4)2.4H2O的(100)和Zn3(PO4)2.4H2O的(020)衍射峰的计数强度,计算出样品磷化膜的磷比,从而判断出磷酸盐配比是否达到工艺要求。     

Pressure dependence of color of natural uvarovite: the barochromic effect

The electronic absorption spectra of natural uvarovite containing 62 mole% of the Cr³⁺ end-member were studied at pressures between 10⁻⁴ and ca. 13 GPa using DAC techniques combined with microscope spectrometric device. With increasing pressure, a barochromic effect with change from green to red color of the garnet specimen was observed. This change could be interpreted on the basis of the spectra and the data points derived in an ICE color card. The evaluation of crystal field data from the spectra showed that 10Dq of chromium increases on pressure while the Racah parameter B, and thus the nature of the chemical bond of Cr–O does not change significantly.     

Thermoluminescence, electron paramagnetic resonance and optical absorption in natural and synthetic rhodonite crystals

Thermoluminescence, electron paramagnetic resonance and optical absorption properties of rhodonite, a natural silicate mineral, have been investigated and compared to those of synthetic crystal, pure and doped. The TL peaks grow linearly for radiation dose up to 4 kGy, and then saturate. In all the synthetic samples, 140 and 340°C TL peaks are observed; the difference occurs in their relative intensities, but only 340°C peak grows strongly for high doses. Al₂O₃ and Al₂O₃ + CaO-doped synthetic samples presented several decades intenser TL compared to that of synthetic samples doped with other impurities. A heating rate of 4°C/s has been used in all the TL readings. The EPR spectrum of natural rhodonite mineral has only one huge signal around g = 2.0 with width extending from 1,000 to 6,000 G. This is due to Mn dipolar interaction, a fact proved by numerical calculation based on Van Vleck dipolar broadening expression. The optical absorption spectrum is rich in absorption bands in near-UV, visible and near-IR intervals. Several bands in the region from 540 to 340 nm are interpreted as being due to Mn³⁺ in distorted octahedral environment. A broad and intense band around 1,040 nm is due to Fe²⁺. It decays under heating up to 900°C. At this temperature it is reduced by 80% of its original intensity. The pink, natural rhodonite, heated in air starts becoming black at approximately 600°C.