电感耦合等离子体发射光谱法和火焰原子吸收光谱法连续测定化探样品中12个元素

建立了地质化探样品中不同含量和检出限要求的12个元素的连续测定方法。样品经一次取样,用盐酸-氢氟酸-硝酸-高氯酸溶样,电感耦合等离子体发射光谱法测定铜、铅、锌、钴、镍、镉、锶、钡、钒、锰后,加碘化钾-甲基异丁基甲酮萃取分离,火焰原子吸收光谱法测定银、镉。银、镉的相对标准偏差(RSD,n=12)分别为6.5%、4.7%。与现行分析方法相比,建立的方法灵敏度和精密度高、准确度好,降低了生产成本,缩短了检测时间,尤其适合大量化探样品的测定。     

快速程序升温-石墨炉原子吸收光谱法测定地质样品中痕量镉

建立了快速程序升温-石墨炉原子吸收光谱测定地质样品中痕量镉的分析方法.样品用硝酸-氢氟酸-高氯酸进行前处理,为提高分析效率,改进了石墨炉升温程序,省去了常规方法中的灰化步骤,使测定镉的程序升温时间由常规的90～100 s降至24 s,工作效率显著提高.方法检出限为0.011 μg/g,加标回收率为93.5%～106.0...     

铁锰氧化物在碱性条件下对镉的吸附特征研究

实验研究了不同的pH值、初始离子浓度、矿物用量、温度以及时间等因素对针铁矿和软锰矿吸附镉的影响。结果表明:在pH值从酸性到近中性的范围内,两种氧化矿物对镉的吸附量增加较快,然后在碱性条件下吸附量保持着最大值;反应前后两种氧化矿物溶液的pH值均有不同程度的变化,其中针铁矿和软锰矿的临界pH值分别为8和6.5;两种矿物对镉的吸附在6 h左右达到了吸附平衡,吸附等温线都较好地符合Freundlich等温方程式;随着两种氧化物用量的增加,其吸附量也有增加;室温下,针铁矿和软锰矿对镉的吸附效果较好。     

常见绿松石品种特征及充填处理的鉴定

总结了我国市场上大量常见的不同产地的天然绿松石的特征,同时对比我国市场常见的充填处理绿松石的特征,研究了天然与充填处理绿松石的一般鉴别特征,发现处理绿松石的颜色深浅、颜色分布、包裹体、外观与天然绿松石均有较大的区别。还利用红外光谱对天然的和充填处理的绿松石进行了测试,发现充填处理绿松石在1 735、1 600、1 500 cm^-1附近可见吸收峰,表明绿松石内部充填了人工类树脂,可作为鉴定充填处理绿松石的有力证据。     

水汽吸收和下垫面发射率对晴空大气红外窗区遥感影响的综合分析

从数学上探讨了晴空大气红外窗区通道遥感陆面特性水汽吸收和陆面发射率的综合影响。首先,基于辐射传输方程推导出大气水汽含量和陆面发射率(ε)引起红外窗区通道遥感陆面亮温(Tg)变化的数学表达式,指出红外辐射在传输过程中水汽吸收衰减的影响主要是引起大气透过率的变化;分析了在高温高湿和低温干燥等不同地区,红外窗区通道的大气透过率所受到的不同程度的衰减,以及水汽吸收衰减和陆面发射率对不同的红外窗区通道的影响。此外,还建立了一个红外窗区通道遥感陆面温度与地面亮温差ΔT=(Ts-Tg,imax)与水汽含量变化Δq和陆面发射率ε的二元多项式拟合方程,进一步分析大气水汽含量和陆面发射率对不同的红外窗区通道遥感的影响;指出红外短波窗区通道不但受太阳辐射污染严重,而且受陆面发射率变化的影响激烈,特别是在寒冷干燥的亚北极冬季。最后强调,为了精确地反演陆面温度,最好采用热红外窗区通道;必须考虑大气订正,特别是在高温高湿区;同时应该考虑陆面发射率等因子的作用。     

Differential absorption measurements of mesospheric and lower thermospheric electron densities using the Buckland Park MF radar

The differential absorption experiment (DAE) was first proposed in the 1950s for the estimation of mesospheric and lower thermospheric electron density using MF/HF radars. The technique was used extensively until the late 1970s, when interest in the technique declined, due to experimental limitations and questions regarding the assumptions of the technique. This paper describes the application of the DAE within the online observations of the Buckland Park MF (BPMF) radar. The experimental limitations of the technique for the BPMF radar are discussed, with particular attention paid to effects of complex gain differences between receiving channels used to decompose the linearly received signals into circular components. Hourly and monthly averaged midday DAE electron densities are presented, revealing good agreement with IRI model estimates. Monthly averaged midnight DAE electron densities are also presented, revealing good qualitative agreement with the IRI model estimates.     

基于吸收滤波技术的储层气水性质识别方法

目前,人们主要从岩性、物性、电性、弹性阻抗等角度,对储层中气水的性质进行预测,然而成功率却并非很高.其实,从频率或能量响应的角度出发,或许能提高气水识别的成功率.由于频率是物质的固有属性,地震波经过含气或含水的储层后,在不同的频段将有不同的响应特征,但在原始地震剖面上却很不容易发现.利用基于ARMA模型时间序列分析方法和Prony信号分析理论的吸收滤波技术,结合测井、岩石物理、地质、地震等资料,分析含气储层和含水储层的不同吸收衰减特征和响应差异.由此可以实现气水性质的有效识别,最终达到直观、快捷的预测优质含气储层的目的.将该技术应用到气水裂缝理论模型的试算和川西坳陷深层须家河组气藏的含气性识别中,均获得了良好的应用效果.     

Evaporation Process in Soil Surface Containing Calcic Nodules on the Northern Loess Plateau of China by Simulated Experiments

Soil containing calcic nodules is widely present on the northern Loess Plateau of China owing to soil genesis under local climate conditions. In most studies, little attention is payed to the effect of calcic nodules on soil evaporation and ecoenvironment, resulting in inaccurate evaporation estimation in this kind of soil and further improper field water management measures and irrigation effects. In this paper, soil column experiments were conducted in order to investigate evaporation process in soil containing calcic nodules and the effect of calcic nodules on soil evaporation was determined. The results indicated that evaporation reduction was positively related to calcic nodule content (CNC = mass of calcic nodules/total mass), and could be estimated by the experiential equation: E_soil = E₀ (1 – 0.4 CNC) (E_soil = actual evaporation, E₀ = theory evaporation in soil without calcic nodules). When CNC was below 0.2, the impact could be neglected. While, as CNC exceeded 0.2, the impact needed to be considered during soil evaporation estimation. As CNC reached 0.5, soil evaporation could be reduced by 7.5 mm, accounting for around 10% of the total soil water. Water balance calculation in soil columns showed that water absorbed by calcic nodules was partially available to evaporation. Water available to evaporation was positively related to CNC, and this water could not exceed 63% of the water absorbed by calcic nodules. Generally, evaporation behavior was dominated by calcic nodule quantity and its water absorption. These results provide new ideas for irrigation measures in arid areas of the globe.     

石墨炉原子吸收光谱法测定镁基合金中的铍和镍

采用石墨炉原子吸收光谱法测定镁基合金中的铍和镍.研究并校正了基体对待测元素的影响.方法简单、快速.对含铍11.4×10^-6、镍9.25×10^-6的样品11份测定,相对标准偏差分别为3.5%、4.3%,铍、镍回收率分别为98.8%、97.5%.