Analyses of trace elements on quartz surfaces in sulfidic mine tailings from Kristineberg (Sweden) a few years after remediation

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) has been applied to determine the elemental composition of the surface layer, as well as of the first interior layer, of quartz grains from the mine tailings from Kristineberg (northern Sweden) in order to determine concentration gradients between these two layers. The quartz grains were collected from the oxidized and unoxidized zones within the tailings. The aim of this study is to assess the role of quartz surfaces as sites for the attenuation of solutes from the mine-tailings porewater. Concentrations of Cu, Ag, Sb, Pb and Bi are highest near the surface of each grain and decrease towards the interior. The surface concentration of Cu, Zn and Pb is more pronounced within the unoxidized than within the oxidized zone of the tailings. Cu exhibits a distinct concentration peak at the surface of the quartz grains below the pre-remediation oxidation front. For Zn and Ce the trend of high surface concentration is less pronounced than for Cu or Pb. Silver, Bi and As are preferably adsorbed within the uppermost layers of the oxidized zone where the pH is as high as 6.2. The conversion of intensity signals of the elements to concentration values in ppm was done by using external standards (NIST silicate glass).     

塔里木与扬子新元古代热-构造事件特征、序列和时代——扬子与塔里木连接(YZ-TAR)假设

淄博市大武水源地是中国北方罕见的特大型岩溶-裂隙地下水水源地,地下水开采量为52×10~4m~3/d。为了对岩溶地下水进行有效监测,需要建立最优的地下水监测网。文中在对岩溶地下水流系统分析的基础上,建立了地下水流系统确定性-随机性数学模型,运用有限元与卡尔曼滤波耦合的模拟递推算法,对大武水源地地下水监测网进行了优化设计,结果显示:现有地下水位动态监测网难以达到监测目标,最优地下水位监测网由14个监测井,每月监测一次的监测频率组成,比现有地下水位监测网减少了2个监测井。     

Conceptual model about the interaction between El Ni(n)o/ Southern Oscillation and Quasi-Biennial Oscillation in far west equatorial Pacific

Interaction between the Quasi-Biennial Oscillation in far west equatorial Pacific (QBOWP) and the El Nino/Southern Oscillation (ENSO) is studied using a new conceptual model. In this conceptual model, the QBOWP effects on ENSO are achieved through two ways: (1) the oceanic Kelvin wave along equatorial Pacific, and (2) the Atmospheric Walker Circulation anomaly, while ENSO effects on QBOWP can be accomplished by the atmospheric Walker Circulation anomaly. Diagnosis analysis of the model results shows that the Atmospheric bridge (Walker circulation) plays a more important role in interaction between the ENSO and QBOWP than the oceanic bridge (oceanic Kelvin wave along equatorial Pacific); It is found that by the interaction of the ENSO and QBOWP, a free ENSO oscillation with 3-5 years period could be substituted by a oscillation with the quasi-biennial period, and the dominant period of SST anomaly and wind anomaly in the far west equatorial Pacific tends to be prolonged with enhanced ENSO forcing. Generally, the multi-period variability in the coupled Atmosphere-Ocean System in the Tropical Pacific can be achieved through the interaction between ENSO and QBOWP.     

电感耦合等离子体发射光谱法测定键合用硅铝丝中硅铁铜

采用电感耦合等离子体发射光谱法测定硅铝丝（Al—1％Si）中Si及杂质元素Fe和Cu。确定了最少取样量和样品溶解方法，优化了元素分析谱线和仪器的测量条件。实验表明，方法的加标回收率为99％～1叭％，相对标准偏差（n=6）低于1．4％，Si、Fe、Cu的检出限分别为8．5、1．0和0．4μg／L。该方法应用于快速测定键合硅铝丝中的各种元素，结果满意。     

微波消解-等离子体发射光谱法同时测定水中硅铁钠

讨论使用电感耦合等离子体发射光谱法测定水样中si、Fe、Na时，四种水样前处理方法对测试结果的影响。提出采用HNO3^-HF体系微波消解、H3BO3掩蔽HF的方法前处理水样，用等离子体发射光谱法可同时准确快速地测定水中Si、Fe、Na三种元素的含量。5次测定的相对标准偏差小于4％，加标回收率为89．2％-106％。     

一个气候系统模式FGCM0对东亚副热带西风急流季节变化的模拟

对IAP/LASG气候系统模式试验版(FGCM0)模拟对流层上层东亚副热带西风急流季节变化的能力进行评估, 分析FGCM0模拟的东亚副热带西风急流季节变化与NCEP/NCAR再分析资料的差异及其与对流层大气南北温差的关系.结果表明, FGCM0模拟的冬季和夏季西风急流垂直结构、水平结构和季节变化与NCEP/NCAR再分析资料基本一致, 但FGCM0模拟的东亚副热带西风急流在高原附近地区冬季和夏季都偏强, 沿115°E中国大陆地区上空模拟的急流强度冬季偏弱, 夏季明显偏强.夏季FGCM0模拟的急流中心位于高原东北部的40°N附近地区, 强度偏强, 位置偏东, 而此时NCEP/NCAR再分析资料中的急流中心却位于高原北侧.此外, FGCM0模拟的急流在5月份的北移和8月份的最北位置上与NCEP/NCAR再分析资料差异较大.分析副热带西风急流与对流层南北温差的季节变化发现, 急流出现的位置总是对应着对流层南北温度差较大区域, 与再分析资料相比, FGCM0模拟的温度差在冬季基本一致, 夏季差异较大.与降水的模拟相联系发现, FGCM0模拟得到的与实际不一致的偏西偏北的强降水中心与200 hPa上的东亚副热带急流位置和强度不合理具有密切关系.相关分析表明, 冬季西风急流强度与日本南部海区的感热通量、夏季与青藏高原地区的地面感热通量有明显的正相关关系, 而FGCM0能够较好地模拟冬季西风急流强度与地面感热通量之间的相关关系, 但模拟夏季青藏高原地区感热通量和副热带西风急流之间相关关系的能力相对较差, 夏季西风急流强度与OLR之间却有一定的关系.由于与强降水区相联系的OLR低值区对应着较大的对流凝结加热, 再加上模式中位于青藏高原东南部较大的地面感热加热, 增强了对流层的南北向温度差, 进而影响东亚副热带急流强度和位置.因此, FGCM0模拟的夏季副热带急流位置和强度偏差与高原附近地区的地面感热加热、大气射出长波辐射等的模拟偏差具有密切的关系.     

浅谈地下水流模拟中河流的处理方法

本文分析了河水与地下水不同作用形式下的补排关系,给出了河流在地下水流模拟中的两种处理方法.根据河流与地下水的相互作用规律将其概化为四种边界条件,并给出了在不同边界条件中河水与地下水交换量的计算公式,初步建立了河水与地下水的解析耦合模型.     

Geological factors influencing the concentration of trace elements in the Philippi peatland, eastern Macedonia, Greece

Six peat samples obtained from the Holocene and the Weichselian of the Philippi peat deposit, eastern Macedonia, Greece, were analyzed for 48 trace elements by Inductively Coupled Plasma–Mass Spectrometry (ICP–MS). The ash contents of these samples were also determined. Most of the trace elements are associated with the minerals in the peat, while Ge, Mo, Pb, Se, Ta, Tl, U, and W display a greater affinity with the organic matter. Compared with crustal averages (Clarke concentrations), the Philippi peat is enriched in some elements (Ag, As, Au, Cd, Mo, Se, Te, U, and W) because of the respective mineralizations in the area. The Philippi peat is also enriched in Cr, Cu, Mo, Pb, Sc, Sn, T, V, Y, and Zn in comparison with typical fen peats, as well as in As, Cr, Mo, Se, and U in comparison with typical coals. Climatic and hydrogeological conditions strongly influenced the peat-forming environment resulting in a differentiation between Holocene and Weichselian peat. Generally, the Holocene peat contains lower concentrations of trace elements in the northern and southern part of the fen, than the Weichselian one. The opposite trend is observed in the fen area close to the western basin margins.     

Accelerating the convergence of coupled geomechanical‐reservoir simulations

The pressure variations during the production of petroleum reservoir induce stress changes in and around the reservoir. Such changes of the stress state can induce marked deformation of geological structures for stress sensitive reservoirs as chalk or unconsolidated sand reservoirs. The compaction of those reservoirs during depletion affects the pressure field and so the reservoir productivity. Therefore, the evaluation of the geomechanical effects requires to solve in a coupling way the geomechanical problem and the reservoir multiphase fluid flow problem. In this paper, we formulate the coupled geomechanical‐reservoir problem as a non‐linear fixed point problem and improve the resolution of the coupling problem by comparing in terms of robustness and convergence different algorithms. We study two accelerated algorithms which are much more robust and faster than the conventional staggered algorithm and we conclude that they should be used for the iterative resolution of coupled reservoir‐geomechanical problem. Copyright © 2006 John Wiley & Sons, Ltd.