基于概率分析的渗流计算方法及应用

以随机理论为基础,把岩土体渗透系数视为随机变量。根据渗透系数的概率分布,把岩土体视为按概率分布的不同渗透系数介质的混合体,不同渗透系数介质对渗流场产生贡献的大小由其概率的大小来确定。在确定岩土体渗透系数后,通过渗流方程就可求出不同渗透系数作用下区域内的水头分布和断面流量,再根据渗透系数的概率大小进行叠加,求出整个区域内的水头分布和断面流量。工程实例表明,该方法较确定性有限元法误差小,可作为渗流计算的又一方法用于渗流分析。     

室内模拟试验确定横向扩散系数的研究--以吉林市第二松花江某江段为例

确定河流横向扩散系数的主要方法有经验公式法和河流示踪试验法.以室内模拟试验求横向扩散系数的方法是一种新的尝试,采用几何相似原理,通过不同流量、流速条件下的室内模拟试验,计算出与河流相应条件下的横向扩散系数,所得结果(0.086 m2/s)与同条件下现场分析计算的结果(0.079～0.088 m2/s)基本一致.模拟试验不仅克服了野外条件下示踪剂投放和测试条件的不便,还能够更好地研究不同水动力条件下污染物的扩散运移规律.     

烷基酚的油水分配系数影响因素研究

烷基酚是一类由酚类化合物烷基化后产生的化合物,与其他非烃化合物相比,更易溶于水.文章通过不同温度(25℃、45℃和65℃)、 不同盐水浓度(4000 mg/L、6000 mg/L和8000 mg/L)和不同原油类型(X37、X45和X61)的三组油水分配实验,研究了烷基酚在油水两相间的分配特征,确定了烷基酚分配系数的变...     

济南四大泉群水化学特征及其成因分析

为明晰济南四大泉群水化学动态变化特征及成因,利用离子比例系数、PHREEQC模拟以及氢氧同位素反演等方法分析各泉群水化学成分特征及其形成过程。研究表明：（1）四大泉群阳离子Ca2+为优势离子,阴离子HCO3-为优势离子;（2）潭西泉和珍珠泉水化学类型稳定,而趵突泉和黑虎泉由HCO3—Ca型变为HCO3·SO4—Ca型;（3）四大泉群受地表水、寒武系凤山组-奥陶系岩溶水以及寒武系张夏组岩溶水混合补给,其中趵突泉、黑虎泉接受寒武系凤山组-奥陶系岩溶水补给占比略大,而潭西泉、珍珠泉接受寒武系张夏组岩溶水补给占比略大;黑虎泉滞留时间最短,循环交替强烈;（4）水岩相互作用强弱程度导致泉群水化学成分差异,溶解沉淀作用强度整体大于阳离子交换作用。趵突泉阳离子交换作用强度最弱,黑虎泉伴随有去白云化作用,潭西泉和珍珠泉水化学作用及强度类似,进一步印证潭西泉和珍珠泉有相同的补给来源及运移机制。该研究成果对水资源合理利用和岩溶大泉的保护具有重要意义。     

安阳矿区双全井田岩性结构与煤体变形的关系

煤体变形程度控制着煤与瓦斯突出和煤层气的可开发性,煤体结构空间展布预测是人们长期关注的焦点。以岩体力学和分形几何学基本理论为指导,以安阳矿区双全井田为例,通过计算岩体强度因子和分形维数,系统探讨了岩性结构对煤体变形的影响。研究表明,岩体强度因子和分形维数与断层和测井曲线判识的煤体结构之间存在密切关系:低强度因子和分形维数区,煤体易发生韧性变形,软煤发育;高强度因子和分形维数区,煤体(和岩体)以脆性变形为主,以断层发育为特征。这一结论为井田构造发育特征和软煤空间展布所证实。岩体力学和分形几何学的引入,为煤体结构空间展布区域预测提供了一种新途径。     

Modeling on adsorption–desorption of trace metals to suspended particle matter in the Changjiang Estuary

The uptake and release of trace metals (Cu, Ni, Zn, Cd, and Co) in estuaries are studied using river and sea end-member waters and suspended particulate matter (SPM) collected from the Changjiang Estuary, China. The kinetics of adsorption and desorption were studied in terms of environmental factors (pH, SPM loading, and salinity) and metal concentrations. The uptake of the metals studied onto SPM occurred mostly within 10 h and reached an asymptotic value within 40 h in the Changjiang Estuary. As low pH river water flows into the high pH seawater and the water become more alkaline as it approaches to the seaside of estuary, metals adsorb more on SPM in higher pH water, thus, particulate phase transport of metal become increasingly important in the seaward side of the estuary. The percentage of adsorption recovery and the distribution coefficients for trace metals remained to be relatively invariable and a significant reduction only occurred in very high concentrations of metals (>0.1 mg L⁻¹). The general effect of salinity on metal behavior was to decrease the degree of adsorption of Cu, Zn, Cd, Co, and Ni onto SPM but to increase their adsorption equilibrium pH. The adsorption–desorption kinetics of trace metals were further investigated using Kurbatov adsorption model. The model appears to be most useful for the metals showing the conservative behavior during mixing of river and seawater in the estuary. Our work demonstrates that dissolved concentration of trace metals in estuary can be modeled based on the metal concentration in SPM, pH and salinity using a Kurbatov adsorption model assuming the natural SPM as a simple surfaced molecule.     

Changes in hydrogeological properties of the River Choushui alluvial fan aquifer due to the 1999 Chi-Chi earthquake, Taiwan

Changes in hydrogeological properties of the River Choushui alluvial fan aquifer before and after the 1999 Chi-Chi earthquake, Taiwan, have been identified using pumping tests. Three wells, SH2, YL2 and SC2, located in a compressional zone with high coseismic groundwater levels, were tested. The threshold of the aquifer deformation with respect to transmissivity (T) is greater than that with respect to storage coefficient (S). Decreases in the post-earthquake S are approximately 60% at SH2 and SC2, indicating aquifer compression after the Chi-Chi earthquake. Changes in the post-earthquake T range from 61% increase to 0.8% decrease. Moreover, results from anisotropy analysis of T at SC2 further illustrate that normal stresses induced by the Chi-Chi earthquake have consolidated soil particles. Soil particles dilated laterally after the earthquake, resulting in an increase of the equivalent T. The changes in hydrogeological properties have a considerable influence on spatiotemporal fluid pressure and horizontal groundwater movement, resulting in different amounts of drawdown during post-earthquake pumping.     

钱二块铀矿床采铀注液结垢趋势的理论分析与预测

用离子系数矩阵法对钱二块铀矿床地浸采铀试验注液中存在的独立离子反应进行了确定,由溶度积规则及反应平衡原理,借助Matlab编程,估算出了钱二块铀矿床地浸采铀试验注液可能会生成的沉淀物种类及数量,为防治结垢提供了一定的理论依据.     

救荒野豌豆对污染土壤中Cd的富集特征

研究了Cd单一和Cd、Zn复合污染对救荒野豌豆(Vicia Sativa L)生长及吸收富集重金属元素Cd的影响.以武汉市郊某蔬菜基地的农田土为试验土壤,分别加入5种质量分数的Cd(5,20,50,100,200 mg/kg),Zn的添加质量分数为150 mg/kg,模拟污染土壤进行盆栽试验,每盆移栽生长一致、数量相同的植株幼苗.结果表明:植株根、茎、叶、豆中的w(Cd)随着土壤中w(Cd)的增加而增加,且根＞茎＞叶＞豆.当土壤中的w(Cd)=5 mg/kg时,根部的富集系数达到了17.18.但是,随着w(Cd)的增加,富集系数逐渐减小.在Cd、Zn复合污染的情况下,植物对Cd、Zn的吸收存在着协同效应,尤其是根部对镉的吸收有显著的提高.救荒野豌豆不仅能在高含量的镉污染土壤中正常生长,而且其根部的w(Cd)要远远大于地上部分,说明它是一种镉的排异植物.     

某地下空间承压含水层抽水试验及成果分析

由于地下水突涌风险,地下空间在施工作业中有必要通过抽水试验确定承压含水层的水文地质参数。依据勘察报告的初步评价,基坑开挖15.5m时,场地内第⑦1层承压含水层有可能产生突涌,为确保工程安全施工,需开挖前进行承压含水层抽水试验,取得场地承压含水层水文地质参数及降水引起的沉降特征,为地下空间设计和施工提供可靠依据。本次布设抽水井、观测井、分层沉降标组、孔隙水压力观测孔及地面沉降观测点,依据抽水试验技术要求获取渗透系数、抽水影响半径等相关水文地质参数。最后,针对工程场地内承压水情况及特点进行分析,提出基坑开挖时的承压水降压建议方案。