Untersuchung der Sorptionseigenschaften des Kationenaustauschers KB-2M mit Makronetzstruktur zur Abtrennung von Zinkionen aus Ab- und Spülwässern

Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn²⁺-ions from sewage and rinsing water.     

Ein kompetitiver Immunoassay zur Bestimmung des Herbizids Fluazifop in Trink- und Grundwasser

A Competitive Immunoassay for the Determination of the Herbicide Fluazifop in Drinking Water and Groundwater A competitive solid-phase enzyme immunoassay using rabbit polyclonal antibodies was developed for the detection of the herbicide fluazifop [(RS)-2-[4-(5-trifluoromethyl-2-pyridyloxy)phenoxy]propionic acid] in drinking water and groundwater. Present regulatory limits for drinking water in Germany were taken as the critical level. The carrier protein was bovine serum albumin; horseradish peroxidase was used as marker enzyme with 3,3′,5,5′-tetramethylbenzidine as substrate. A high concentration of high-affinity antibodies in the serum, optimization of test conditions (antibody and enzyme tracer concentration, incubation time etc.), and very low cross reactivities to substances of similar structures led to a highly sensitive and specific ELISA with a detection limit below 0.1 μg/L for fluazifop as free acid. On testing the suitability of the assay's use as a screening test with one hundred drinking-water samples, the three samples which had been spiked in the laboratory were recognized as positive with respect to their fluazifop content. Confirmation by gas chromatography-mass spectrometry showed the test results of two other samples to be false positive. False negative results did not appear. The concentration was in the detection limit region of 0.1 μg/L.     

Geometric form of Haiyuan fault zone in the crustal interior and dynamics implications

The deep seismic reflection data on profile HY2 are reprocessed by the method of simultaneous inversion of velocity distribution and interface position. By the travel-time inversion with the data of the diving wave Pg and fault plane reflection wave, we determine the geometric form and velocity of Haiyuan fault zone interior and surrounding rock down to 10 km depth. The measured data show that the amplitudes have strong attenuation in the range of stake number 37–39 km, suggesting the fault zone has considerable width in the crustal interior. The results of this paper indicate that to the north of the fault zone the crystalline basement interface upheaves gradually from southwest to northeast and becomes shallow gradually towards northeast, and that to the south of the fault zone, within the basin between Xihua and Nanhua mountains, the folded basement becomes shallow gradually towards southwest. The obliquity of the fault zone is about 70° above the 3 km depth, about 60° in the range of the 3–10 km depths. From the results of this paper and other various citations, we believe that Haiyuan fault zone is in steep state from the Earth’s surface to the depth of 10 km. Foundation item: Joint Seismological Science Foundation of China (201001) and State Key Basic Research Development and Programming Project (95-13-02-02). Contribution No. RCEG200308, Exploration Geophysical Center, China Earthquake Administration.     

Field vibration mitigation by honeycomb WIB for pile foundations of a high-speed train viaduct

Environmental vibrations from recent high-speed trains are becoming a special concern in the civil and environmental engineering field since they can give detrimental effects to residents, sensitive equipments and high-tech production facilities in the vicinity of train tacks. Herein, aiming at the vibration mitigation for a specific high-tech industrial area, the low-frequency vibrations from a train viaduct are targeted over an anticipated range. A theoretically designed innovative countermeasure, called honeycomb wave impeding barrier (WIB) for a wave impeding barrier, is introduced and its effects are investigated by computer simulation. The present WIB is based on the wave dispersion phenomenon that can modulate the incoming wavelengths into the shorter wavelengths, creating an apparent wave cut-off characteristic in the wave field across WIB installation area. The shorter wavelengths are further impeded due to the impedance ratio of the WIB walls and in-fill materials and absorbed by the in-fills more. The three-dimensional FEM simulation demonstrates a dramatic reduction effect that is difficult to achieve by conventional measures.     

Are open fractures necessarily aligned with maximum horizontal stress?

Fluid flow in fractured rock is an increasingly central issue in recovering water and hydrocarbon supplies and geothermal energy, in predicting flow of pollutants underground, in engineering structures, and in understanding large-scale crustal behaviour. Conventional wisdom assumes that fluids prefer to flow along fractures oriented parallel or nearly parallel to modern-day maximum horizontal compressive stress, or S_Hmax. The reasoning is that these fractures have the lowest normal stresses across them and therefore provide the least resistance to flow. For example, this view governs how geophysicists design and interpret seismic experiments to probe fracture fluid pathways in the deep subsurface. Contrary to these widely held views, here we use core, stress measurement, and fluid flow data to show that S_Hmax does not necessarily coincide with the direction of open natural fractures in the subsurface (>3 km depth). Consequently, in situ stress direction cannot be considered to predict or control the direction of maximum permeability in rock. Where effective stress is compressive and fractures are expected to be closed, chemical alteration dictates location of open conduits, either preserving or destroying fracture flow pathways no matter their orientation.     

Distribution of trace metals in the Odra River system: Water–suspended matter–sediments

Extensive investigations of trace metals concentrations in water, suspended particulate matter (SPM) and bottom sediments of the whole Odra River system were carried out over the years 1997–2000. The vertical distribution of selected metals and their mobility were also studied in the sediment cores from upper and middle river sections. Significant levels of metal contamination were found. Median concentrations (Cd, Pb, Cu, Zn and As) in the SPM and sediments were (mg kg⁻¹) 7.1 and 8.9 Cd, 128 and 146 Pb, 81 and 119 Cu, 1198 and 1204 Zn, 48 and 54 As, respectively. The highest metal pollution of the Odra River solids was found with cadmium, zinc, lead and arsenic, showing high similarity in their frequency distributions in both SPM and sediments. Cd, Zn and As appear to be of particular concern because of the high levels, that appear to be bioavailable, and their high mobility. The exchangeable and carbonate chemical forms of Cd and Zn reached up to 50% of their total amount. Besides the determination of total metal concentration, the metal chemical forms in river solids were investigated. The results of very wide studies of the Odra River system through 4 years suggest that metal pollution decreased, especially for Zn, Pb and Cu. Among all metals studied in the Odra River sediments, substantial reductions of Cd contamination were observed neither in the period after ’97 flood, nor if compared with the earlier results obtained before ’97. No essential differences of the metal contents were observed among the samples for the same river compartment, from the same locality, taken within the five sampling campaigns. The pattern of spatial and vertical metal distributions in the river solids indicates that a variety of sources might be responsible for the contamination; very intensive, historical and current mining and smelting activities probably are the most important ones.     

Green''''s functions for uniformly distributed loads acting on an inclined line in a poroelastic layered site

Based on one type of practical Biot's equation and the dynamic-stiffness matrices of a poroelastic soil layer and half-space, Green's functions were derived for uniformly distributed loads acting on an inclined line in a poroelastic layered site. This analysis overcomes significant problems in wave scattering due to local soil conditions and dynamic soil-structure interaction. The Green's functions can be reduced to the case of an elastic layered site developed by Wolf in 1985. Parametric studies are then carried out through two example problems.     

Temporal and spatial variations in water flow and sediment load in Narmada River Basin, India: natural and man-made factors

The Narmada River flows through the Deccan volcanics and transports water and sediments to the adjacent Arabian Sea. In a first-ever attempt, spatial and temporal (annual, seasonal, monthly and daily) variations in water discharge and sediment loads of Narmada River and its tributaries and the probable causes for these variations are discussed. The study has been carried out with data from twenty-two years of daily water discharge at nineteen locations and sediment concentrations data at fourteen locations in the entire Narmada River Basin. Water flow in the river is a major factor influencing sediment loads in the river. The monsoon season, which accounts for 85 to 95% of total annual rainfall in the basin, is the main source of water flow in the river. Almost 85 to 98% of annual sediment loads in the river are transported during the monsoon season (June to November). The average annual sediment flux to the Arabian Sea at Garudeshwar (farthest downstream location) is 34.29×10⁶ t year⁻¹ with a water discharge of 23.57 km³ year⁻¹. These numbers are the latest and revised estimates for Narmada River. Water flow in the river is influenced by rainfall, catchment area and groundwater inputs, whereas rainfall intensity, geology/soil characteristics of the catchment area and presence of reservoirs/dams play a major role in sediment discharge. The largest dam in the basin, namely Sardar Sarovar Dam, traps almost 60–80% of sediments carried by the river before it reaches the Arabian Sea.     

南水北调地下水回补对潮白河冲洪积扇中上部地表形变响应及控制因素

2014年南水进京后,持续开展地下水回补对于遏制和减缓地面沉降发展起到重要作用,但地下水回升由此带来的不同区域、不同层位的地面沉降与回弹机制及其控制因素尚不明确。深入探讨和研究回补时间、回补量、回补地点与水位及地表形变之间的关系,了解地表形变发生机理和识别主控因素,为后续如何科学回补,发挥最大化水资源回补效益、对地面沉降防治和超采区治理具有极其重要意义。本文以潮白河冲洪积扇中上部区域为例,采用永久散射体差分干涉测量（PS InSAR）技术获取研究区地面沉降形变信息,并结合区域分层地下水位动态变化、分层沉降变化等多手段进行耦合,查明研究区地表形变与多因素之间的响应与控制因素。结果表明:南水持续回补导致区域地面沉降减缓,并在牛栏山地区出现地表抬升,抬升范围也随着水位上升逐渐向中下游扩展,2022年最大回弹速率达46.9 mm/a;地表形变具有明显的受断裂所控制的第四系沉积差异特性,以黄庄—高丽营断裂、顺义断裂和南口—孙河断裂所分割的后沙峪凹陷范围内变化明显大于其他地区;地下水位变幅与富水性差异决定水位上升范围与响应变化,而沉积构造作用所造成第四系沉积差异在地下水流向上具有一定控制作用。结果为地面沉降防控和机理研究提供理论和科学依据,同时也为后续开展地下水科学回补和方案优化提供指导和借鉴。