中国东南沿海中-新生代玄武岩微量元素和Nd-Sr-Pb同位素研究

本文对中国东南沿海不含幔源包体的中生代玄武岩和含幔源包体的新生代玄武岩进行了微量元素和Nd-Sr-Pb同位素对比研究。中生代玄武岩呈Ta、Nb和Hf负异常,低Ce/Pb、Nb/U比值和高La/Nb比值,与岛弧火山岩和陆壳岩石的微量元素特征相类似,说明在岩浆生成和上升过程中,幔源组分受到了陆壳组分的混染。新生代玄武岩呈Ta、Nb正异常和Pb负异常,高Ce/Pb、Nb/U比值和低La/Nb比值,与海岛玄武岩(OIB)相类似,Nd-Sr同位素成分与夏威夷玄武岩类似,因而它们未受明显的陆壳混染。143Nd/144Nd与206Pb/204Pb之间的负相关关系和87Sr/86Sr与206Pb/204Pb之间的正相关关系说明本区新生代玄武岩起源于中等亏损程度的软流圈地幔,并与EMII富集地幔组分发生了混合。     

全球增暖的另一可能原因初探

太阳是地球流体(大气和海洋等)运动的最终能量源,地球环境,尤其是气候的变化不能不与太阳活动有关.目前,普遍将全球增暖归结为温室气体含量增加所导致的温室效应的加剧,这无疑是有一定依据和有道理的.但从科学上来讲,人类活动所引起温室气体增加的影响,并非是唯一原因.基于已有的一些研究结果,从太阳活动的观点所进行的初步分析表明,太阳活动也可能是引起近世纪全球增暖的另一个重要原因.太阳活动的影响主要包括太阳辐射的直接影响和引发地磁场变化的间接影响两个方面,地球磁场的变化将可通过动力过程和热力过程而影响大气环流和气候的变化.     

云南祥云马厂箐斑岩微量元素与稀土元素特征

马厂箐斑岩体与铜、钼、金等多金属矿成矿关系密切.斑岩体微量元素与稀土元素显示斑岩体物质来源具有壳幔混合特征.     

Trace elements in alluvia of the upper Vistula as indicators of palaeohydrology

In the Vistula valley near Góra, at the northern foreland of the Carpathians Mountains, there are young alluvia deposited in the historical period. These alluvia are difficult to date precisely because of the lack of organic interbedded material. In the Vistula drainage basin upstream of Góra since the second half of 18th century small centres of metal, textile, motor, and petrochemical industries have been developed. Concentrations of trace elements such as: Cr, Mn, Co, Ni, Cu, Zn, Cd, Pb, and of some macroelements were used as indicators of the age of different alluvial fills. The main part of the Vistula valley floor was built up by sediment accumulation before the development of industry but after the medieval phase of rural colonization of the Carpathians. Deposits filling the abandoned channels dissecting the valley floor have an increased content of some trace elements and deposits date from the second half of the 18th century, when the first foundries and blacksmith's shops were developed. A drastic increase of concentration of the most abundant trace elements in the youngest alluvial fill indicates that the fill dates from the last decade of rapid industrial development.     

中国能源领域温室气体排放现状及减排对策研究

自工业革命以来,随着化石燃料的广泛应用,能源领域的温室气体排放逐渐成为其主要的人为排放源,能源、环境和经济发展之间的矛盾也日益成为各国政府共同关注的焦点。如何有效地进行能源活动中温室气体的减排已经成为涉及环境、经济、政治、外交等多方面的全球性科学问题。文章对中国能源开发利用现状和主要温室气体二氧化碳(CO₂)、甲烷(CH₄)、氧化亚氮(N₂O)能源排放源进行了简要分析,并对适合中国国情的温室气体减排与能源可持续开发与利用"双赢",实现"发展型减排"的有效途径进行了初步的探讨。     

美国退出《巴黎协定》对全球温室气体排放的影响

现有研究表明美国退出《巴黎协定》将会在2025年导致其国内排放增加约1.2 Gt CO₂-eq,然而美国退出《巴黎协定》对全球气候治理的影响不仅限于此,还包括资金效应、政治效应,以及惯性效应等对全球排放的间接和长期影响。本文通过构建体现不同效应的全球温室气体排放情景,分析了美国退出《巴黎协定》后对全球温室气体排放可能造成的不同影响。结果表明,美国退出《巴黎协定》的自身效应、资金效应、对伞形国家的政治效应和对发展中国家的政治效应,将分别导致全球2030年的年温室气体净排放量(扣除碳汇吸收量后的温室气体排放量)上升2.0、1.0、1.0和1.9 Gt CO₂-eq,并导致全球2015—2100年的累计排放量分别上升246.9、145.3、102.0和270.2 Gt CO₂-eq。为防止美国退出《巴黎协定》的不利影响进一步扩大,中国应积极引领全球气候治理制度的建设与发展,与各国紧密合作全面平衡地推进《巴黎协定》的落实和实施。     

Natural gas generation model and its response in accumulated fluids in the Yinggehai basin

The generation of natural gases is much more complicated in comparison with liquid petro-leum in that natural gases could be generated from both humic and sapropelic organic matter at different stages and that natural gases could be organic and inorganic …     

Defining the geochemical baseline: a case of Hong Kong soils

A geochemical baseline provides the means to distinguish between the pedogenic origin and the anthropogenic origin of the trace element in the environmental compartments. We collected 271 soil samples representative of different parent rocks and soil types from the whole territory of Hong Kong and analyzed the composition of clay mineralogy and the contents of 15 chemical elements (Fe, Cd, As, etc.) for these samples. The baseline was predicted with the method of the normalization procedure combined with the relative cumulative frequency curve. The result indicated that Fe was the best reference element for the normalization procedure among the five potential reference elements (Fe, Al, Sc, Ti, and Mn), followed by Sc and Ti. A poor correlation was found between Sc, Ti, and Cu. The predicted baseline was much lower than the A-value of the Dutch List used usually in screening the polluted soil of Hong Kong, implying that the extent of heavy metal pollution might have been underestimated with respect to local lands. We also applied the cluster analysis to distinguish the geochemical associations of the trace elements due to its importance to the baseline. Approximately three major associations including the Fe–Mn-oxides related, Al oxides or Al-bearing-clay-mineralogy related and sulfide- related associations were observed from the dendrogram.     

太湖梅梁湾温室气体(CO2,CH4和N2O)浓度的昼夜变化及其控制因素

营养盐载荷增加、富营养化以及全球增温等对湖泊温室气体的影响目前认识还很有限,原因之一在于对湖泊温室气体产生的动力过程了解不够深入,缺少高时间分辨率的现场观测数据。为了解决这一问题,在富营养的太湖梅梁湾水体,每一小时收集一个样品,直接分析N2 O和CH4饱和度、CO2分压(pCO2)以及其他地球化学参数。在7月份的观测中,N2 O和CH4显示出显著的昼夜变化规律。相关性分析表明,有机质降解是调节湖泊N2 O和CH4变化的重要因素之一。虽然人为活动是控制湖泊温室气体大规模变化的主要因素,但沉积物-水界面的生物地球化学过程对温室气体浓度在短时间尺度上的变化有着重要的影响。研究结果揭示了湖泊温室气体除了受人为活动影响外,湖泊自身的生物地球化学过程也是重要的调控因素之一。     

Seep mounds on the Southern Vøring Plateau (offshore Norway)

Multidisciplinary study of seep-related structures on Southern Vøring Plateau has been performed during several UNESCO/IOC TTR cruises on R/V Professor Logachev. High-resolution sidescan sonar and subbottom profiler data suggest that most of the studied fluid discharge structures have a positive relief at their central part surrounded by depression. Our data shows that the present day fluid activity is concentrated on the top of these “seep mounds”. Number of high hydrocarbon (HC) gas saturated sediment cores and 5 cores with gas hydrate presence have been recovered from these structures. δ¹³C of methane (between −68 and −94.6‰ VPDB) and dry composition of the gas points to its biogenic origin. The sulfate depletion generally occurs within the upper 30–200 cm bsf and usually coincides with an increase of methane concentration. Pore water δ¹⁸O ranges from 0.29 to 1.14‰ showing an overall gradual increase from bottom water values (δ¹⁸O ∼ 0.35‰). Although no obvious evidence of fluid seepage was observed during the TV surveys, coring data revealed a broad distribution of living Pogonophora and bacterial colonies on sea bottom inside seep structures. These evidences point to ongoing fluid activity (continuous seepage of methane) through these structures. From other side, considerable number and variety of chemosynthetic macro fauna with complete absence of living species suggest that present day level of fluid activity is significantly lower than it was in past. Dead and subfossil fauna recovered from various seep sites consist of solemyid (Acharax sp.), thyasirid and vesicomyid (cf. Calyptogena sp.) bivalves belonging to chemosymbiotic families. Significant variations in δ¹³C (−31.6‰ to −59.2‰) and δ¹⁸O (0.42‰ and 6.4‰) of methane-derived carbonates collected from these structures most probably related to changes in gas composition and bottom water temperature between periods of their precipitation. This led us to ideas that: (1) seep activity on the Southern Vøring Plateau was started with large input of the deep thermogenic gas and gradually decries in time with increasing of biogenic constituent; (2) authigenic carbonate precipitation started at the near normal deep sea environments with bottom water temperature around +5 °C and continues with gradual cooling up to negative temperatures recording at present time.