Electrokinetic Removal of Petroleum Hydrocarbon from Residual Clayey Soil Following a Washing Process

This study investigates total petroleum hydrocarbon (TPH) removal from residual clayey soil, after a washing procedure, using an electrokinetic process. Eight electrokinetic experiments were carried out to investigate the characteristics of TPH removal. When 0.1 M MgSO₄ or 0.1 M NaOH was used as an electrolyte, the electric current rapidly increased within the first 100 or 200 h, respectively. A negatively charged soil surface resulted in a more negative zeta potential and greater electroosmotic flow toward the cathode. Therefore, the accumulated electroosmotic flow (EOF) when using 0.1 M NaOH as the anolyte‐purging solution was higher than when using 0.1 M MgSO₄. Although the energy consumption for the two purging solutions was similar, the efficiencies of TPH removal when 0.1 M MgSO₄ and 0.1 M NaOH with surfactant were used were 0 and 39%, respectively, because the electroosmotic flow rate increased with TPH removal efficiency. When 5% isopropyl alcohol (IPA) was used as a circulation solution, the electric current increased but the TPH removal was similar to that using water. In terms of energy consumption, the use of a surfactant‐enhanced electrokinetic process with NaOH as electrolyte was effective in removing TPHs from low‐permeability soil.     

马村站自512井水汞异常分析

2006年7月4日河北省文安县发生了ML5．5级地震,震前震中西南200km的石家庄马村站自512井水汞3月15日～5月15日出现了短期高值异常,6月3日出现了高值突跳异常。本文分析研究了文安地震前水汞的异常变化,以及1999年水汞观测以来的异常变化特征。分析认为,震前小马村水汞的异常变化幅度较大,异常特征明显,前兆意义显著。     

Total mercury in terrestrial systems (air-soil-plant-water) at the mining region of San Joaquín,Queretaro, Mexico

Deficient management of cinnabar mining left the San Joaquín region with high concentrations of mercury in its soils (2.4 – 4164 mg kg^-1). Numerous cinnabar mines have contributed to the dispersion of mercury into agricultural (0.5 –314 mg kg^-1) and forest (0.2 – 69 mg kg^-1) soils. Sediments are a natural means of transportation for mercury, causing its spreading, especially in areas near mine entrances (0.6 – 687 mg kg^-1). The nearness of maize crops to mines favors mercury accumulation in the different plant structures, such as roots, stems, leaves, and grain (0.04 – 8.2 mg kg^-1); these being related to mercury volatilization and accumulation in soils. Mercury vapor present in the settlements could indicate a constant volatilization from lands and soils (22 – 153 ng m^-3). The mercury levels found in the soils, in maize grain, and in the air resulted greater than the standards reported by the Official Mexican Norm (NOM) and the World Health Organization (WHO). Mercury in rainwater is due mainly to the presence of suspended atmospheric particles, later deposited on the surface (1.5 – 339 μg |^-1). Mercury dissolution was found in the drinking water (10 – 170 ng |^-1), with concentrations below those established by the NOM and the WHO. The contamination existing in the San Joaquín region does not reach the levels of the world’s greatest mercury producers: Almaden (Spain) and Idrija (Slovenia). It is, however, like that found in other important second degree world producers such as Guizhou (China). The population of San Joaquín, as well as its surrounding environment, are constantly exposed to mercury contamination, thus making a long term monitoring necessary to determine its effects, especially to people.     

利用日本GPS网探测2011年Tohoku海啸引发的电离层扰动

海平面的海啸波会产生大气重力波进而引发电离层扰动.本文利用日本GPS总电子含量数据来探测2011年3月11日Tohoku海啸引发的电离层扰动.观测结果表明,在日本上空的电离层中存在两种重力波信号,分别由海平面的海啸波以及地震破裂过程产生.地震产生的电离层重力波分布在震中周围（包括海洋上空以及远离海洋的区域）,而海啸引发的电离层重力波主要分布在海洋上空.地震产生的电离层重力波具有不同的水平速度,包括约210 m·s^-1以及170 m·s^-1,其频率为1.5 mHz;而海啸引发的电离层重力波水平速度快于前者,约为280 m·s^-1,其频率为1.0 mHz.此外,海啸引发电离层重力波与海平面上的海啸波有相似的水平速度、方向、运行时间、波形以及频率等传播特征.本文的研究将电离层中的海啸信号与地震信号区分开来,进一步确认电离层对海啸波的敏感性.

     

含碳结构对龙门山断层带电导率影响的实验探索

碳是影响岩石电导率大小的一个重要因素,可能是造成龙门山断层带电导率异常的重要原因之一.为了研究不同的碳含量、矿物颗粒粒径与碳晶体结构对断层带电导率的影响,在干燥、常温、0.2~300 MPa的压力条件下实验研究了人工模拟断层泥样品（石英粉末与含碳粉末混合的样品,简称模拟样品）和采自映秀-北川断层八角庙剖面的天然断层岩样品（简称天然样品）的电导率.实验结果显示,当模拟样品中的含碳粉末连通时,电导率与碳体积率的关系符合逾渗理论模型;而含碳粉末未连通时,电导率随总孔隙度降低而指数性升高.同时模拟样品的电导率也随石英颗粒粒径的变化而发生改变.相比于模拟样品中的含碳粉末主要分布于石英颗粒支撑的孔隙中,天然样品中的碳则主要以碳膜的形式赋存在颗粒边缘,导致碳体积率相同的条件下,模拟样品的电导率小于天然样品.此外,天然样品的电导率（ < 9×10^-4 S·m^-1）也要小于野外大地电磁探测的结果（0.03~0.1 S·m^-1）.在今后的实验中还需要考虑在动态摩擦条件下对含有完整含碳结构的天然样品进行电导率的实验研究.

     

水汞观测资料对比分析

通过聊古一井井水中汞量的测定及对比观测试验,找到了影响数据内在质量的干扰因素,提出了浓硫酸、蒸馏水是干扰因素的主要来源,进行空白样的测定是排除干扰,提高观测资料内在质量的重要方法.     

壤中气汞测量在活断层研究中的应用

利用JM—3型数字金膜测汞仪对渭河盆地活动断层进行壤中气汞测量,取得了初步结果。认为,壤中气汞异常与活动断层存在着密切的关系,通过测汞寻找隐伏活动断层,判定断层活动性是可行的。     

福州市大气汞含量及变化特征分析

在福州市采集了10个点位共356件大气样品,测试结果表明,福州市大气汞含量35.82~586.11 ng/m3,各点平均值89.86~168.24 ng/m3,总平均111.9 ng/m3,大气汞含量空间变化特征表明高含量点与地热活动带在空间上相吻合。     

The use of GPS arrays in detecting shock-acoustic waves generated during rocket launchings

This paper is concerned with the parameters of shock-acoustic waves (SAW) generated during rocket launchings. We have developed the interferometric method for determining SAW parameters (including angular characteristics of the wave vector, and the SAW phase velocity, as well as the direction towards the source) using GPS-arrays. Contrary to the conventional radio-probing techniques, the proposed method provides an estimate of SAW parameters without a priori information about the site and time of a rocket launching. The application of the method is illustrated by a case study of ionospheric effects from launchings of rockets PROTON, SOYUZ and SPACE SHUTTLE from Baikonur and Kennedy Space Center cosmodromes in 1998–2000. In spite of a difference of rocket characteristics, the ionospheric response for all launchings had the character of an N-wave corresponding to the form of a shock wave. The SAW period T is 270–360 s, and the amplitude exceeds the standard deviation of total electron content background fluctuations in this range of periods under quiet and moderate geomagnetic conditions by factors of 2–5 as a minimum. The angle of elevation of the SAW wave vector varies from 30° to 60°, and the SAW phase velocity (900–1200 m/s) approaches the sound velocity at heights of the ionospheric F-region maximum. The position of the SAW source, inferred by neglecting refraction corrections, corresponds to the segment of the rockets path at a distance no less than 200–900 km from the launch pad, and to the rocket flying altitude no less than 100 km. Our data are consistent with the existing view that SAW are generated during a nearly horizontal flight of the rocket with its engine in operation in the acceleration segment of the path at 100–130 km altitudes in the lower atmosphere.     

RTK配合全站仪在数字化测图中的应用

本文主要叙述了RTK配合全站仪进行数字化测图的可行性,介绍了RTK的系统组成、工作原理,并对RTK配合全站仪联合测图的作业流程进行了一系列论述;指出了RTK与全站仪联合进行数字化测图是一种高速度、高效率的新方法.