Dissolved trace elements in river water: spatial distribution and the influencing factor, a study for the Pearl River Delta Economic Zone, China

Twenty-nine water samples were collected from different river channels of the Pearl River Delta Economic Zone, China. An inductively coupled plasma-mass spectromonitor (ICP-MS) was used to measure concentrations of the trace elements in these samples. The results suggest that the average concentrations of rare earth elements in river water show an increasing trend from the West River, the North River, the rivers of the Pearl River Delta, and the Shenzhen River to the East River. Relatively high concentrations of heavy metals appear in the East River, the rivers of the Pearl River Delta and the Shenzhen River, while the West River and the North River have relatively low heavy metal concentrations. Trace element concentrations in samples collected near urban or industrial areas are much higher than those of samples collected from distant areas, away from urban and industrial areas. After natural conditions, human activities have significant influence on the trace element concentrations in river water. This trace element concentration’s spatial distribution in the river water from the Pearl River Delta Economic Zone is actually an integrated effect of natural conditions and human activity.     

Vertical distribution and water solubility of phosphorus and heavy metals in sediments of the St. Lucie Estuary, South Florida, USA

Accumulation and distribution of heavy metals and phosphorus in sediments impact water quality. There has been an increasing concern regarding fish health in the St. Lucie Estuary, which is related to increased inputs of nutrients and metals in recent decades. To investigate vertical changes of contaminants (P, Cd, Cr, Co, Cu, Ni, Pb, Zn, and Mn) in sediments of the St. Lucie Estuary in South Florida, 117 layer samples from six of the 210 to 420 cm depth cores were analyzed for their total and water-soluble P and heavy metals, clay, total Fe, Al, K, Ca, Mg, Na, and pH. Principal component analysis (PCA) was used in two sets of analytical data (total and water-soluble contaminant concentrations) to document changes of contaminants in each core of sediments. The PCA of total contaminants and minerals resulted in two factors (principal components). The first and second factors accounted for 61.7 and 17.2 % of the total variation in all variables, and contrast indicators associated with contaminants of P, Cd, Co, Cr, Ni, Pb, Zn, and Mn and accumulation of Fe and Al oxides, respectively. The first factor could be used for overall assessment of P and heavy metal contamination, and was higher in the upper 45–90 cm than the lower depths of each core. The concentrations of P and heavy metals in the surface layers of sediments significantly increased, as compared with those in the sediments deeper than 45–90 cm. The PCA of water-soluble contaminants developed two factors. The second factor (Cu–P) was higher in the upper than the lower depths of the sediment, whereas the highest score of the first factor (Cd–Co–Cr–Ni–Pb–Zn–Mn) occurred below 100 cm. The water-soluble Cu and P concentrations were mainly dependent on their total concentrations in the sediments, whereas the water-soluble Cd, Co, Cr, Ni, Pb, Zn, and Mn concentrations were mainly controlled by pH.     

华南地区晚二叠和晚三叠世煤中稀土元素特征研究

在华南地区贵州六盘水、江西乐平、露庆和湖北黄石矿区晚二叠和晚三叠世煤层的稀土元素ICP—MS分析数据的基础上，系统研究了研究区煤中稀土元素的含萤分布特征、赋存特征、配分模式以及地质控制因素。含量分布表明晚二叠世稀土元素含量总体高于晚三叠世；煤中稀土元素与灰分成正相关关系，部分煤样品由于有富稀土元素的重矿物组合的存在而出现稀土元素的异常高值；同一矿区、同一时代煤中稀土元素的配分模式具有一定的相似性，而不同地区同一时代和同一地区不同时代煤中稀土元素的配分模式具有较大差异；煤的沉积环境，煤中无机矿物组成以及海水的影响是控制煤中稀土元素含量和配分模式的主要地质因素。     

藏南地区金和锑矿床(点)类型及其时空分布特征

本文首次对藏南地区金和锑矿床(点)地质特征、成因类型和空间分布特点进行了总结，对金和锑成矿作用与中新生代构造一岩浆活动的关系进行了论证，对区域地壳演化过程中金和锑成矿动力学机制进行了讨论。该区的金和锑矿床(点)可按容矿围岩划分为：①变质岩为主要容矿围岩矿床(点)，包括金和金一锑矿床(点)；②沉积岩为主要容矿围岩矿床(点)，包括金、锑、金一锑和锑多金属矿床(点)；③火山岩为主要容矿围岩矿床(点)，以金一银矿床为代表。根据金和锑矿床(点)空间分布特点和地质特点，将本区划分为4个矿化集中区：拉昂错一马攸木一帕羊金矿化集中区(A)，然勒金和锑矿化集中区(B)，洛扎一措美锑矿化集中区(C)和邛多江金一锑矿化集中区(D)。各矿化集中区内大多数金和锑矿床(点)与燕山晚期～喜马拉雅早期富碱火成岩具密切时空分布关系，它们是古板块对接碰撞期和碰撞期后大规模构造一岩浆活动的产物。近东西向挤压性和南北向张性断裂交汇部位以及富碱火成岩发育区是寻找金和锑矿床(点)的有利场所。     

青藏高原北羌塘地区晚三叠世地层展布和沉积型式

北羌塘盆地地处拉竹龙-金沙江缝合带和双湖构造混杂岩带之间,自北向南可划分出5个沉积相带/岩石地层单位：以砂泥质复理石-洋岛、岛弧型火山岩-大理岩岩石组合沉积为特征的若拉岗日群,以深水复理石盆地相沉积为特征的藏夏河组,以深水暗色细碎屑岩盆地相沉积为特征的结扎群,以开阔台地相/缓坡相碳酸盐岩沉积为特征的菊花山组,以三角洲相含煤碎屑岩系沉积为特征的土门格拉群.晚三叠世北羌塘盆地显示为南缓北陡的箕状沉积格局,盆地内充填物为南薄北厚的楔形沉积体,且双物源、沉降中心和沉积中心不一致,表明其具有前陆盆地的一系列沉积特征.     

绕坝渗流地下水位的时空分布模型研究

许多大坝的失事是由于高地下水位引起坝肩失稳所致。绕坝渗流是影响坝肩高地下水位的主要因素。为此通常将大坝基础防渗帷幕延伸到坝肩岸坡内一定距离,以减小绕坝渗流影响。而防渗帷幕运行性态随时间变化,为了评价坝肩防渗帷幕和地下水位的运行性态,首先分析了地下水位观测资料和水位、降水、温度、时效等时空影响因素及其表达式,随后基于岸坡地下水位观测资料,利用最小二乘法建立了大坝岸坡地下水位的时空分布模型。通过比较模型剩余标准差和测点的剩余标准差,可以确定坝肩地下水位的异常测点,分析岸坡防渗薄弱部位,掌握坝肩岸坡渗流场时空分布规律,监控绕坝渗流的性态。     

GIS叠置图层方差分量的极大似然估计

针对GIS叠置中的同名点,以维希特分布密度为似然函数,提出了各图层方差分量的极大似然估计方法。该方法不依赖残差,不需要迭代就能估计未知参数和方差分量。     

西北地区不同类型云的时空分布及其与降水的关系

利用1983年7月～2001年9月国际卫星云气候计划ISCCP D2的月平均资料，对西北不同区域不同类型云的云量和云水路径的时空分布及其与降水的关系进行了研究。结果表明:高原气候区是各种云出现最多的地区，特别是积状云的云量明显高于其他两区，但这些云的云水路径值低；西北地区大多数云云量的高值区出现在天山山区、北疆地区、陕西东南部和青藏高原的部分地区。高云和部分中云云量空间分布特征与降水有着较好的一致性:沿着天山—昆仑山—祁连山一带以及陕南和／或陇南地区是高值区，低值区在塔里木盆地—内蒙古西部戈壁沙漠—黄土高原西北部一带；绝大多数云类春夏季节云量维持较高，秋冬季节云量较少。云水路径值较大的层状云类的云量多寡与降水多寡相一致；积状云类和层积云类云量多少与降水没有一定的关系，在降水偏少时，这类云的云量大多与降水正常时相近，有些云的云量甚至比降水偏多时还要多。