环境样品中痕量元素的化学形态分析Ⅰ．分析技术在化学形态分析中的应用

文章介绍了形态分析的基本概念,常用的联用分析技术,如气相色谱原子吸收光谱、气相色谱原子荧光光谱、气相色谱微波诱导等离子体原子发射光谱、气相色谱电感耦合等离子体质谱、高效液相色谱电感耦合等离子体质谱等在环境样品(水、土壤、沉积物)中痕量元素化学形态(价态、金属有机化合物等)分析中的应用,土壤和沉积物中污染元素的顺序提取步骤,以形态分析发展动态。引用文献72篇。     

土壤中钙形态的连续浸提方法

通过改进的连续浸提技术，把土壤钙的赋存形态划分为5个类型：水溶态、交换态、酸溶态、有机结合态及残渣态，用原子吸收光谱法测定各形态钙含量及总钙量，各形态钙的加和值与测得的总钙量基本相符，且各形态钙8次浸提的相对标准偏差基本在10％以内。探讨了改进的连续浸提方法提取条件（包括浸提剂、水土比、提取时间、离心速率及离心时间等）对提取效果的影响。结果表明，土壤中各形态钙可以满足生态地球化学土壤样品评价需要。     

生物迁移思想的起源与发展

生物迁移命题是由达尔文(1859)提出来的。他在《物种起源)一书中认为,一个物种只能有一个起源中心;在条件允许的前提下,它会从这个中心迁移到力所能及的地区。然而,当布克曼(1922)的"迁移炮弹"理论问世之后,迁移研究几乎陷于停顿状态差不多50年。李四光是在"迁移炮弹"阴影下,依然坚持迁移观点的少数科学家之一。越来越多的事实证明了达尔文迁移思想的强大生命力。屡见不鲜的化石"穿时"现象和时代差异,大量的生物地理新资料,使人们从不可知论的桎梏中逐渐解脱出来。特别是80年代以来,由于地壳运动理论研究的新需求,以及大陆漂移和海水进退规程研究的新进展,掀起了重新认识迁移的高潮。作者依据自己的积累和前人的研究成果认为,迁移的研究方法可概括为:最低层位的地理追索方法、演化程序的地理追索方法和相应环境的追索方法。迁移如同演化,在达尔文力的全弥漫作用(All pervadins action)下时刻在进行着。迁移与其说是生物自身的一种能力,倒不如说是环境给予的一种机会。迁移造就并维系着丰富多彩的自然生态系统。迁移研究必将发展而形成一门新的学科--古生物迁移学(Palaeobiomigratology)。生物迁移思想是与地质力学的诞生和发展共存的。李四光(1927,1928)在研究海水进退规程时,曾列举了伴随海水南北方向的运动,生物作相应迁移的许多事实。生物迁移和海水运动,是性质完全不同的两种运动,其间必然存在着一个联系两者的中间环节;这个环节被李四光(1962)暗示为气候的变化,或两者共同导源于地球自转的不均衡。      

BOOK REVIEWS

Book Reviewed in this article: Introduction to Climatology for the Tropics . J. O. Ayoade. Conservation and Management of Natural Resources in the United States . Charles F. Bennett. The Keeping of Animals: Adaptation and Social Relations in Livestock Producing Communities . Riva Berleant-Schiller and Eugenia Shanklin, ed. The Evolution of Geographic Thought in America: A Kentucky Root Wilford A. Bladen and Pradyumna P. Karan, eds. Latin America: Geographical Perspectives , 2nd ed. Harold Blakemore and Clifford T. Smith, ed. The Rural Real Estate Market. Department of Geography Publication Series, No. 18 . Chris Bryant. Urban Geomorphology in Drylands . R. U. Cooke, D. Brunsden, J. C. Doornkamp, and D. K. C. Jones with contributions by J. Griffiths, P. Knott, R. Potter, and R. Russell. Italian Geography, 1960–1980. Meeting of the Status of the Geographic Research in Italy, 1960–1980. Treated under the auspices of Consiglio Nazionale delle Ricerche and organized by Istituto di Geografia Umana della Facoltà di Lettere e Filosofia dell'Università degli Studi di Milano , Giacomo Corna Pellecrini and Carlo Brusa, eds. The Changing Fenland . H. C. Darby. The Future for the City Centre . R. L. Davies and A. G. Champion, eds. Saudi Arabia, Energy, Developmental Planning, and Industrialization . Ragaei El Mallakh, Dorothea H. El Mallakh, eds. For We Are Sold, I and My People: Women and Industry in Mexico's Frontier . Maria Patricia Fernández-Kelly. The Great Lakes Forest: An Environmental and Social History . Susan L. Flader, ed. Regional Transformation and Industrial Revolution: A Geography of the Yorkshire Woolen Industry . Derek Gregory Crime in City Politics . Anne Heinz, Herbert Jacob and Robert L. Lineberry, eds. Revitalizing Cities . H. Briavel Holcomb and Robert A. Beauregard. Cartographic Relief Presentation . Eduard Imhof. H. J. Steward, Trans. Soviet Union: A Geographical Survey . S. V. Kalesnik and V. F. Pavlenko, ed. Cognition and Environment . Stephen Kaplan and Rachel Kaplan. Environmental Protection: The International Dimension . David A. Kay and Harold K. Jacobsen, eds. Mathematical Programming Methods for Geographers and Planners , James Killen. Gentrification Amid Urban Decline: Strategies for America's Older Cities . Michael H. Lang. The North Atlantic Sulphur System . Risto Laulajainen. The Jerusalem Cathedra: Studies in the History, Archaeology, Geography and Ethnography of the Land of Israel, Vol. 2 . Lee I. Levine ed. Jerusalem and Detroit: Recreation Planning and Management . Stanely R. Lieber and Daniel R. Fesenmaier, eds. Heartland and Hinterland: A Geography of Canada . L. D. McCann, ed. Scarborough Where We Live: The Residential Districts of Minneapolis and St. Paul . Judith A. Martin and David A. Lanegran. California: The Geography of Diversity . Crane S. Miller and Richard S. Hyslop. Palo Alto The Dilemma of Amazonian Development . Emilio F. Moran, ed. Boulder Nuclear Waste: Socioeconomic Dimensions of Long-Term Storage . Steve H. Murdock, F. Larry Leistritz, and Rita R. Hamm, eds. Boulder Communism and the Politics of Inequalities . Daniel N. Nelson, ed. The Los Angeles Metropolis . Howard J. Nelson. Dubuque An Historical Geography of Urban System Development: Tidewater Virginia in the 18th Century . James O'Mara. Procedures and Standards for a Multipurpose Cadastre . East Asia: Geographical and Historical Approaches to Foreign Area Studies . Clifton W. Pannell, ed. Dubuque Mackinder: Geography as an Aid to Statecraft . W. H. Parker. Beyond the Urban Fringe: Land Use Issues of Nonmetropolitan America . Rutherford H. Platt and George Macinko, eds. Recreation Geography of the USSR . V. S. Preobrazhensky and V. M. Krivosheyev, eds. Missouri: A Geography . Milton D. Rafferty The Invisible Farmers: Women in Agricultural Production . Carolyn E. Sachs. Cayman Islands Seashore Vegetation: A Study in Comparative Biogeography . Jonathan D. Sauer. Hillslope Materials and Processes . Michael J. Selby. Housing in Britain: The Post-War Experience . John R. Short The Study of Population: Elements, Patterns and Processes . George A. Schnell and Mark Stephen Monmonier. Columbus The Soviet Union: A Systematic Geography . Leslie Symons, ed. The Ottoman Slave Trade and Its Suppression . Ehud R. Toledano. The Impact of Recession on Industry, Employment and the Regions, 1976–1981 . Alan R. Townsend. Landslides and Their Control , 2nd ed. Quido Záruba and Vojtech Mencl. Translated from the Czech by H. Zárubová and V. Mencl.     

BOOK REVIEWS

Book Reviewed in this article: Unfairly Structured Cities . Blair Badcock Religion and Rural Revolt . Janos M. Bak and Gerhard Benecke The Industrial Geography of Canada . Anthony Blackbourn and Robert G. Putnam The Cuban-American Experience, Culture, Images, and Perspectives. Thomas D. Boswell and James R. Curtis Quaternary Paleoclimatology . R. S. Bradley Development and Crisis in Brazil, 1930–1983 . Luiz Bresser Pereiras Centres of Origin in Biogeography . John C. Briggs Analytical Urban Geography . Martin Cadwallader Geomorphology . Richard J. Chorley , Stanley A. Schumm, and David E. Sugden South Africa: The Impact of Past Geographies . A. J. Christopher The Geography of Underdevelopment. A Critical Survey . D. K. Forbes Health Care in Developing Countries . Wilbert M. Gesler Place to Grow Old: The Meaning of Environment in Old Age . Stephen M. Golant The Emerging Marine Economy of the Pacific . Chennat Gopalakrishnan An Introduction to Agricultural Geography . David B. Grigg The Soviet Union: A Geographical Study . G. Melvyn Howe Geographical Aspects of Health: Essays in Honour of Andrew Learmonth . N. D. Mc Glashan and J. R. Blunden Physical Geography: A Landscape Appreciation . Tom L. Mc Knight Mountain Experience. The Psychology and Sociology of Adventure. Richard G. Mitchell Jr . Systematic and Regional Biogeography. Stanley A. Morain The Economic Transformation of American Cities. T. J. Noyelle and T. M. Stanback , Jr . Normal Accidents: Living With High-Risk Technologies. Charles Perrow Vanishing Farmland: A Legal Solution for the States. Sarah E. Redfield Applied Methods of Regional Analysis: The Spatial Dimensions of Development Policy. Dennis A. Rondinelli Urbanization in Romania. A Geography of Social and Economic Change Since Independence. Per Ronnas Statistical Techniques in Geographical Analysis. Gareth Shaw and Dennis Wheeler The Granite Garden: Urban Nature and Human Design. Anne Whiston Spirn Political Geography: Recent Advances and Future Directions. Peter Taylor and John House Geographia y Medio Ambiente. Manuel Valenzuela -Rubío Nãgara and Commandery: Origins of the Southeast Asian Urban Traditions. Paul Wheatley The Common Fisheries Policy of the European Community. Mark Wise Geography and Gender. Women and Geography Study Group of the IBG Technological Hazards. D. J. Zeigler , J. H. Johnson , S. D. Brunn     

水环境中氮磷形态分析方法研究进展

归纳总结了近年来国内外水环境中氮、磷形态分析方法的研究新进展,并着重介绍了氮、磷在水环境中赋存形态的分类、分析测定方法,这对于深入揭示水环境中氮、磷的赋存形态及研究环境与生物地球化学循环有着重要的指导意义。     

Evolution of the trophic state of Lake Annecy (eastern France) since the last glaciation as indicated by iron, manganese and phosphorus speciation

Lake Annecy sediments have been studied to provide an insight into the evolution of the lake trophic state in response to climate changes during the Holocene. Determination of the concentration of carbonate, Fe, Mn, and different forms of P in conjunction with total sediment fluxes derived from ¹⁴C ages allows an estimation of yearly fluxes of these sediment components. High fluxes of endogenic carbonate occur during the early to middle Holocene. Non apatitic inorganic phosphorus flux is variable but shows some higher-than-present values during this period. These observations are interpreted as being a result of enhanced productivity by favourable conditions for phytoplankton development. In addition, the low Mn/Fe ratio of the redox-sensitive forms of these elements recorded during this period suggests low oxygen concentrations in the bottom waters. Therefore it appears that the lake may have undergone oxygen depletion in the bottom water during the warmer-than-present periods, due to increased productivity and subsequent oxygen consumption from the decay of organic matter. With future climate changes, this suggests that lake water quality may likely degrade under global warming.     

Factors controlling the solubility of aerosol trace metals in the atmosphere and on mixing into seawater

Previous work has shown that the type and pH history of an aerosol governs trace metal solubility in rainwater. This study concentrates on the crustal elements Al, Fe and Mn and identifies additional processes which affect dissolution not only in the atmosphere but also on mixing into seawater. Aerosol dissolution experiments (at aerosol concentrations of about 30 mg 1^–1) show manganese exhibiting high solubility at the low pH values typical of clouds (54±2.5% at pH 2, with results expressed in mole percent units) with 85% of this increase occurring within 6 hours of acidification. The percentage dissolution decreases to 50% at pH values representative of rainwater (pH 5.5) and to 26±4% at pH 8, typical of seawater. No such dramatic solution phase removal occurs at pH 8 in the presence of inorganic anions (to a final solubility of 44±2%). Thus the extent of manganese dissolution depends strongly on whether aerosols are cycled through acidic environments and on subsequent inorganic complexation once rainwater mixes into sea. Aluminium shows highest dissolution (7.1±0.6%) at low pH with 78% of this increase occurring within 6 hours of acidification. Rapid solution phase removal occurs on increasing the pH to that representative of rainwater (to 0.9±0.4% with 87% of this decrease occurring within 15 min). As a consequence of acid cycling and aluminium's amphoteric nature, solubility is enhanced at seawater pH (2.3±0.3%) over that in rain. Iron shows a strong pH-solubility relationship with highest solubility at low pH (4.7±0.2%), 70% of this value being reached within 6 hours of acidification, and decreasing rapidly to 0.17% as pH is raised to 8. Addition of inorganic anions at pH 8 to simulate mixing into seawater causes a further decrease in solubility, perhaps due to anion induced colloid destabilisation. Photochemical reduction also effects solubility under low pH conditions with Fe(II) comprising 1% of the total iron in the Saharan Aerosol used and 8.4% in an Urban material at a pH of 2. This element shows rapid solution phase removal with increasing particulate load which is tentatively rationalised in terms of a simple Kd approach.     

Radioelement (U,Th, Rn) concentrations in Norwegian bedrock groundwaters

Twenty-eight samples of groundwater from bedrock boreholes in three distinct Norwegian geological provinces have been taken and analyzed for content of Rn, U, and Th, together with a wide variety of minor and major species. Median values of 290 Bq/1, 7.6 g/1, and 0.02 g/1 were obtained for Rn, U, and Th respectively, while maximum values were 8500 Bq/1, 170 g/1, and 2.2 g/1. Commonly suggested drinking water limits range from 8 to 1000 Bq/1 for radon and 14 to 160 g/1 for uranium. Radioelement content was closely related to lithology, the lowest concentrations being derived from the largely Caledonian rocks of the Trøndelag area, and the highest from the Precambrian Iddefjord Granite of southeast Norway (11 boreholes) where median values of 2500 Bq/1, 15 g/1 and 0.38 g/1, respectively, were obtained. The Iddefjord Granite is not believed to be unique in Norway in yielding high dissolved radionuclide contents in groundwaters, and several other granitic aquifers warrant further investigation in this respect.