高压密闭消解-电感耦合等离子体光谱和质谱联合测定海洋地质样品中52种元素

An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method(HPCD), is studied by an inductively coupled plasma optical emission spectrometry(ICP-OES) and an inductively coupled plasma mass spectrometry(ICP-MS). The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error(RE) for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials(GBW07309, GBW07311, GBW07313), rock reference materials(GBW07103, GBW07104,GBW07105), and cobalt-rich crust reference materials(GBW07337, GBW07338, GBW07339), the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation(RSD) and the relative error(RE) are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples.     

Theoretical constraints to gully erosion research: time for a re‐evaluation of concepts and assumptions?

Gullies are conceptualized in the literature as essentially fluvial forms with dimensional boundaries arbitrarily defined between rills and river channels. This notion is incompatible with the existing variability of form and process, as mass movements frequently exert a fundamental control on gully initiation and expansion, to the point of features outgrowing their original contributing area. The inability of a conceptual framework to incorporate existing observations inevitably constrains methodologies and research results. In this commentary, several examples of published results are contrasted with the prevailing assumption of an essentially fluvial nature, with the purpose of encouraging discussion on the need for a revised conceptual framework in gully erosion research. Copyright © 2011 John Wiley & Sons, Ltd.     

岩体分级考虑因素的现状与趋势分析

在对国内外岩体分级方法深入研究的基础上,对岩体分级方法中所考虑的岩体分级因素及对各因素的处理方法进行了系统的归纳和总结。从岩体分级方法的现状来看,虽然目前尚无统一的岩体分级标准,但在岩体分级中应根据岩石的强度、岩体的完整性、地下水条件、地应力状况等多方面因素,进行岩体综合分级上达成了共识,并且国内规范中的岩体分级标准有趋于统一和向国际标准接轨的趋势。     

Lateral tidal mixing in the Antarctic marginal seas

Tidal mixing plays an important role in the modification of dense water masses around the Antarctic continent. In addition to the vertical (diapycnal) mixing in the near-bottom layers, lateral mixing can also be of relevance in some areas. A numerical tide simulation shows that lateral tidal mixing is not uniformly distributed along the shelf break. In particular, strong mixing occurs all along the Ross Sea and Southern Weddell Sea shelf breaks, while other regions (e.g., the western Weddell Sea) are relatively quiet. The latter regions correspond surprisingly well to areas where indications for cross-shelf exchange of dense water masses have been found. The results suggest that lateral tidal mixing may account for the relatively small contribution of Ross Sea dense water masses to Antarctic Bottom Water.     

碱熔沉淀-等离子体质谱法测定地质样品中的多元素

采用过氧化钠焙融或偏硼酸锂熔融分解样品，将提取液碱性沉淀，通过过滤分离掉大量熔剂，再将沉淀用酸复溶后用等离子体质谱测定26个元素。通过对比，偏硼酸锂熔融—酸提取—碱性沉淀的方案，空白低，易操作，成本低，大多数元素测定结果的相对误差＜10％，相对标准偏差＜5％(n＝10)，与标准值相吻合。     

澜沧江某电站右坝肩复杂岩体质量分类

笔者通过对澜沧江某电站右岸坝肩复杂岩体的成因进行分析,采用岩体质量指数Z并结合水利水电工程围岩分级和RMR分级等岩体分类方法对电站右岸坝肩的复杂岩体进行了综合分类。     

Holocene calcrete crust deposits on the moraine of Batura Glacier, northern Pakistan

Abstract   Calcretes can be observed on the surface of old moraines around Batura Glacier in the upper Hunza Valley, Karakoram Mountains, Pakistan. They develop as a calcareous crust cementing small gravels under boulders. In order to understand the genesis of the calcrete crust, a variety of methods were employed: (i) study of mineralogy and geochemistry of a calcrete crust precipitated on the lateral moraine using X-ray diffractometer and electron probe microanalysis; (ii) analysis of solute chemistry of surface water and ice bodies around the Batura Glacier; and (iii) accelerator mass spectrometry ¹⁴C dating of the crust itself. The results indicate that the calcrete crust has definite laminated layers composed of a fine-grain and compact calcite layer, and a mineral fragment layer. The chemical composition of the calcite layer is approximately 60% CaO and 1% MgO. The mineral fragment layer consists of rounded grain materials up to 0.2 mm in diameter. It shows a graded bedding structure with fine grains of quartz, albite and muscovite. Meanwhile, as the Paleozoic Pasu limestone is distributed around the terminal of Batura Glacier, Ca cations dissolve in the melt water of the glacier. Accordingly, the calcrete crust is precipitated by decreases in CO₂ partial pressure from glacier ice and evaporation of the melt water, including high concentration of Ca²⁺ at ephemeral streams and small ponds stagnating between the moraine and glacial ice. On the basis of the AMS ¹⁴C age, the calcrete is considered to have formed approximately 8200 calibrated years bp under the Batura glacial stage.     

MODIFIED MASS FLUX CUMULUS CONVECTIVE PARAMETERIZATION SCHEME AND ITS SIMULATION EXPERIMENT—PART Ⅰ:MASS FLUX SCHEME AND ITS SIMULATION OF THE 1991 FLOOD EVENT*

Based on the existing cumulus convective parameterization schemes,a mass flux scheme (MFS) for cumulus convective parameterization has been successfully developed by reference to the work of Chen et al. (1996).The MFS is a comprehensive scheme.In MFS,not only the importance of the large-scale moisture convergence is taken into account,but also it includes the cumulus updrafts and downdrafts,cumulus-induced subsidence in the environmental air.entrainment,detrainment and evaporation.The interaction between the cumulus and the environment is described by using a one-dimensional bulk model.At the same time the scheme includes the penetrative and shallow convections.The MFS has been successfully incorporated into the regional climate model RegCM2 developed by NCAR.The new model has been applied to simulate summer monsoon characteristics and their variations of heavy rainfall process in the Changjiang-Huaihe River Basins for three months from May to July 1991.The results show that the new model can successfully simulate this rainfall prolonged process.By comparising the model outputs of RegCM2.using the Kuo scheme and the MFS.it is found that the MFS is better in simulating the surface temperature,rainfall position and amount,and rainfall duration.     

A Combined Three-Dimensional Geological-Geostatistical-Numerical Model of Underground Excavations in Rock

Summary. This paper exploits geological and borehole geotechnical data obtained in the exploratory phase of a tunneling project to investigate in a first place if the kriging interpolation scheme may effectively reproduce the spatial variability of rock mass quality (Rock Mass Rating, RMR) in the vicinity of tunnels. For this purpose a quick solver in Fortran has been developed that performs variography analysis of 3D spatial data, fast kriging estimations of RMR between borehole sampling locations at the centroids of the elements of the numerical model, and model validation. For the purpose of an integrated underground excavation design, a step further is made by incorporating into the 3D mechanical numerical model of the rock mass, the three-dimensional (3D) solid geological model, thus coupling the geology with the ground (geotechnical) model (i.e. each element of the numerical model is assigned a geological material). The mechanical properties of each finite difference cell (or Representative Elementary Volume) of the ground model were then prescribed according to its geological type, the spatial heterogeneity of the rock mass expressed quantitatively with the kriging model, and the upscaling calculations of the mechanical properties of the intact rocks determined in the laboratory, based on the size-effect (strength dependence on size) and Damage Theory. Furthermore, a preliminary numerical simulation of the advance of unsupported tunnels in the model of the heterogeneous rock mass was performed for illustration purposes.